Standard Article

Synthesis of Multiply Bonded Phosphorus Compounds Using Silylphosphines and Silylphosphides

Organic Silicon Compounds (2001)

  1. Masaaki Yoshifuji,
  2. Kozo Toyota

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0242

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Yoshifuji, M. and Toyota, K. 2009. Synthesis of Multiply Bonded Phosphorus Compounds Using Silylphosphines and Silylphosphides. Patai's Chemistry of Functional Groups. .

Author Information

  1. Tohoku University, Department of Chemistry, Graduate School of Science, Sendai, Japan

Publication History

  1. Published Online: 15 DEC 2009

Chemistry Terms

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Abstract

  • 1
    Introduction
  • 2
    Survey of Silylphosphines and Alkali Metal Silylphosphides
  • 3
    Disilyl(2,4,6-tri-t-Butylphenyl)Phosphines
  • 4
    Monosilyl(2,4,6-tri-t-Butylphenyl)Phosphines
  • 5
    Alkali Metal Monosilyl(2,4,6-tri-t-Butylphenyl) Phosphides
  • 6
    Phosphasilenes

Keywords:

  • silylphosphines and alkali metal silylphosphides;
  • multiply bonded phosphorus compounds;
  • multiply bonded phosphorus compound synthesis;
  • disilylphosphines and alkali metal disilylphosphides;
  • lithium bis(trimethylsilyl)phosphide reactions;
  • metal mono(trialkylsilyl)phosphides and related compounds;
  • disilyl(2,4,6-tri-t-butylphenyl)phosphines;
  • synthetic applications of silylphosphides

Featured Compounds

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  1. 1 - 20
Compound 1
Molecular Weight:250.5409
Molecular Formula:C9H27PSi3
InChIKey:OUMZKMRZMVDEOF-UHFFFAOYSA-N
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Compound 5
Molecular Weight:184.293
Molecular Formula:C6H18LiPSi2
InChIKey:YBKNUOBTYUGFPN-UHFFFAOYSA-N
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Compound 2
Molecular Weight:234.4661
Molecular Formula:C10H27PSi2
InChIKey:ZRCWXWUJAZXNPP-UHFFFAOYSA-N
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Compound 3
Molecular Weight:254.4558
Molecular Formula:C12H23PSi2
InChIKey:GVEYKVGCJIJGIW-UHFFFAOYSA-N
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Compound 4
Molecular Weight:296.5355
Molecular Formula:C15H29PSi2
InChIKey:CPBAZPIZODLYPA-UHFFFAOYSA-N
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Compound 6
Molecular Weight:188.208
Molecular Formula:C9H14LiPSi
InChIKey:DFHMLUVFMAADFR-UHFFFAOYSA-N
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Compound 11a
Molecular Weight:356.527
Molecular Formula:C21H38LiPSi
InChIKey:GIQXZKYEDAGBNL-UHFFFAOYSA-N
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Compound 11b
Molecular Weight:398.606
Molecular Formula:C24H44LiPSi
InChIKey:LGBQHPKIVIBHRF-UHFFFAOYSA-N
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Compound 7a
Molecular Weight:262.4762
Molecular Formula:C11H27OPSi2
InChIKey:VYQYZRNRDVUILQ-UHFFFAOYSA-N
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Compound 8
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 7b
Molecular Weight:340.5881
Molecular Formula:C17H33OPSi2
InChIKey:CBQPVKQLKXYNGD-UHFFFAOYSA-N
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Compound 9
Molecular Weight:422.7747
Molecular Formula:C24H47PSi2
InChIKey:WQDHMKQIGYJTQV-UHFFFAOYSA-N
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Compound 10a
Molecular Weight:350.5936
Molecular Formula:C21H39PSi
InChIKey:FZWHVJADXXDNOZ-UHFFFAOYSA-N
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Compound 10b
Molecular Weight:392.6734
Molecular Formula:C24H45PSi
InChIKey:HAPSRSCHDZAKJV-UHFFFAOYSA-N
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Compound 12
Molecular Weight:655.0003
Molecular Formula:C40H68OP2Si
InChIKey:PANFANJRKFEOMH-UHFFFAOYSA-N
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Compound 13
Molecular Weight:697.0801
Molecular Formula:C43H74OP2Si
InChIKey:ZQLXKNUHSWHSJU-UHFFFAOYSA-N
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Compound 10c
Molecular Weight:537.231
Molecular Formula:C33H46ClPSi
InChIKey:MFFRJTVQGVGLNE-UHFFFAOYSA-N
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Compound 10d
Molecular Weight:675.462
Molecular Formula:C40H69ClP2Si
InChIKey:SMQRABLWZOVBPL-UHFFFAOYSA-N
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Compound 14
Molecular Weight:618.48
Molecular Formula:C30H43PW
InChIKey:OYLHNWXEDGIZMS-UHFFFAOYSA-N
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Compound 15
Molecular Weight:618.48
Molecular Formula:C30H43PW
InChIKey:ZXZQSZKFMXXZKE-UHFFFAOYSA-N
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VIEW

  1. 1 - 20