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Chemistry on Silicon Surfaces

Organic Silicon Compounds (2001)

  1. Cheol Ho Choi,
  2. Mark S Gordon

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0249

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Cheol Ho, C. and Mark S, G. 2009. Chemistry on Silicon Surfaces. Patai's Chemistry of Functional Groups. .

Author Information

  1. Iowa State University, Department of Chemistry, Ames, Iowa, USA

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Theoretical Methods and Surface Models
  • 3
    2 × 1 Reconstruction of a Clean Silicon Surface
  • 4
    Chemical Reactions Involving Si[BOND]C Bond Formation
  • 5
    Hydration of the Reconstructed Si(100) Surface
  • 6
    Hydrogenation of the Reconstructed Si(100) Surface
  • 7
    Oxidation Reactions on the Si(100) Surface
  • 8
    Etching of Si(100) with Halogen
  • 9
    Summary and Outlook
  • 10
    Acknowledgment

Keywords:

  • chemistry on silicon surfaces;
  • Hückel theory and tight binding method (or Extended Hückel Theory);
  • hybrid quantum mechanics/molecular mechanics (QM/MM) techniques;
  • SIMOMM (Surface Integrated Molecular Orbital/Molecular Mechanics);
  • reconstruction and ‘dimerization’ of adjacent surface Si atoms;
  • chemical reactions involving Si–C bond formation;
  • backbond and dimer-bridge configurations;
  • etching of SI(100) with halogen