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Silyl Migrations

Organic Silicon Compounds (2001)

  1. Mitsuo Kira,
  2. Takeaki Iwamoto

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0250

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Kira, M. and Iwamoto, T. 2009. Silyl Migrations. Patai's Chemistry of Functional Groups. .

Author Information

  1. Tohoku University, Graduate School of Science, Department of Chemistry, Sendai, Japan

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    1,2-Silyl Migrations
  • 3
    1,3-Silyl Migrations
  • 4
    1,N-Silyl Migrations (n ≥ 4)

Keywords:

  • silyl migrations;
  • dyotropic and related rearrangements;
  • 1,2-silyl migrations in unsaturated silicon compounds;
  • synthetic applications;
  • silyl group high migratory aptitudes;
  • 1,2-Silyl migrations in unsaturated silicon compounds;
  • lithium di-t-butylbiphenylide (LDBB);
  • 1,5-Silyl migrations between oxygen atoms in silyl diketonates