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Ion–Molecule Reactions of Silicon Cations

Organic Silicon Compounds (2001)

  1. Simonetta Fornarini

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0252

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Fornarini, S. 2009. Ion–Molecule Reactions of Silicon Cations. Patai's Chemistry of Functional Groups. .

Author Information

  1. Università di Roma “La Sapienza”, Dipartimento di Studi di Chimica e Tecnologia delle Sostanze Biologicamente Attive, Roma, Italy

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Reactions of the Silicon Ion, Si+•
  • 3
    Reactions of Hydrogen-Containing Silacations, SixHy+•
  • 4
    Reactions of Halogen-Containing Silacations
  • 5
    Reactions of O- and S-Substituted Silacations
  • 6
    Reactions of SiCxHy+(•) Ions
  • 7
    Reactions of Transition Metal-Containing Silacations
  • 8
    Acknowledgments

Keywords:

  • silicon cation ion–molecule reaction;
  • understanding bimolecular reactivity of positively charged silicon ions;
  • atomic silicon cations with neutral molecule reactions;
  • halogen-containing silacation reactions;
  • O- and S-substituted silacation reaction;
  • EI or CI ionization of tetramethylsilane (TMS) - source of Me3SiC ions;
  • organosilane radical cation reaction;
  • transition metal-containing silacation reaction