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Free and Complexed R3M+ Cations (M = Ge, Sn, Pb)

Organic Germanium, Tin and Lead Compounds (2003)

  1. Ilya Zharov,
  2. Josef Michl

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0262

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Zharov, I. and Michl, J. 2009. Free and Complexed R3M+ Cations (M = Ge, Sn, Pb). Patai's Chemistry of Functional Groups. .

Author Information

  1. University of Colorado, Department of Chemistry and Biochemistry, Boulder, CO, USA

  1. Present address: Beckman Institute for Advanced Science and Technology, University of Illinois at Urbana-Champaign, 405 North Mathews Ave, Urbana, IL 61801.

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Preparation
  • 3
    Structure and Properties
  • 4
    Reactions
  • 5
    Related Species
  • 6
    Conclusions

Keywords:

  • heavier congeners of carbenium ions;
  • Sn NMR chemical shifts for cationic tin species;
  • germyl cations in sulfolane and dichloromethane;
  • B3LYP/SSD method and ion-pairing energies for optimized isomers;
  • intramolecular stabilization;
  • electron impact ionization;
  • crystal structure of free cyclotrigermenium cation;
  • free trimesitylgermyl and trimesitylstannyl cations