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Alkaline and Alkaline Earth Metal-14 Compounds: Preparation, Spectroscopy, Structure and Reactivity

Organic Germanium, Tin and Lead Compounds (2003)

  1. Pierre Riviere,
  2. Annie Castel,
  3. Monique Riviere-Baudet

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0263

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Riviere, P., Castel, A. and Riviere-Baudet, M. 2009. Alkaline and Alkaline Earth Metal-14 Compounds: Preparation, Spectroscopy, Structure and Reactivity. Patai's Chemistry of Functional Groups. .

Author Information

  1. Université Paul Sabatier, Laboratoire d'Hétérochimie Fondamentale et Appliquée, Toulouse cedex, France

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Preparations
  • 3
    Spectroscopic and Structural Studies
  • 4
    Reactivities

Keywords:

  • M14 –alkali metal compounds*;
  • Chemical Vapor Deposition (CVD);
  • lithium diisopropylamide (LDA) and tin hydrides;
  • nucleophilic cleavage by potassium t-butoxide of digermanes, distannanes;
  • cyclic pentacoordinate plumbyl anions;
  • bis(trimethylgermyl)magnesium - first symmetrical bis(organogermyl) magnesium isolated;
  • dimesitylgermyllithium etherate and diethylchloroaluminium reaction;
  • alkaline and alkaline earth metal-14 compounds