Standard Article

Thermochemistry of Organolithium Compounds

Organolithium Compounds (2004)

  1. Suzanne W. Slayden1,
  2. Joel F. Liebman2

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0299

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Slayden, S. W. and Liebman, J. F. 2009. Thermochemistry of Organolithium Compounds. Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    George Mason University, Department of Chemistry, Fairfax, Virginia, USA

  2. 2

    University of Maryland, Department of Chemistry and Biochemistry, Baltimore, Maryland, USA

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction: Scope and Definitions
  • 2
    Isomeric and Homologous Alkyl Lithium Series
  • 3
    Comparison of Organolithiums and Grignard Reagents
  • 4
    Protodelithiation Reactions
  • 5
    Aryl Halogen–Lithium Exchange Reactions
  • 6
    Oxygenated Organolithiums: Intramolecular Complexation and Enthalpies of Formation
  • 7
    Perlithiocarbons and Lithiated Aromatic Anions
  • 8
    Acknowledgment

Keywords:

  • molar standard enthalpy of formation;
  • organolithium compound thermochemistry;
  • isomeric and homologous alkyl lithium series;
  • organolithiums and Grignard reagents;
  • protodelithiation reactions;
  • protodelithiation with 2-butanol;
  • aryl halogen–lithium exchange reactions;
  • oxygenated organolithiums and enthalpies of formation