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Arene-Catalyzed Lithiation

Organolithium Compounds (2004)

  1. Miguel Yus

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0307

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Yus, M. 2009. Arene-Catalyzed Lithiation. Patai's Chemistry of Functional Groups. .

Author Information

  1. Universidad de Alicante, Departamento de Química Orgánica, Facultad de Ciencias, Alicante, Spain

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Mechanistic Aspects
  • 3
    Organolithiums by Halogen–Lithium Exchange
  • 4
    Organolithiums from Acyclic Nonhalogenated Materials
  • 5
    Functionalized Organolithium Compounds by Halogen–Lithium or Sulfur–Lithium Exchange
  • 6
    Ring Opening of Heterocycles
  • 7
    Polylithium Synthons
  • 8
    Activation of other Metals
  • 9
    Other Methodologies
  • 10
    The Polymer-Supported Version
  • 11
    Conclusions
  • 12
    Acknowledgments

Keywords:

  • organolithiums by halogen–lithium exchange;
  • arene-catalyzed lithiation;
  • organolithiums from acyclic nonhalogenated materials;
  • carbon–fluorine bond cleavage;
  • functionalized organolithium compounds;
  • heterocycle ring opening;
  • polylithium synthons;
  • arene-catalyzed lithiation in synthetic organic chemistry