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α-Amino-Organolithium Compounds

Organolithium Compounds (2004)

  1. Robert E. Gawley1,*,
  2. Iain Coldham2

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0312

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Gawley, R. E. and Coldham, I. 2009. α-Amino-Organolithium Compounds. Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    University of Miami, Department of Chemistry, Coral Gables, FL, USA

  2. 2

    University of Exeter, School of Chemistry, Exeter, UK

  1. *

    Current address: Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, AR 72701, USA.

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction to α-Amino-Organolithium Compounds
  • 2
    Unstabilized α-Amino-Organolithium Compounds
  • 3
    Dipole-Stabilized α-Amino-Organolithium Compounds
  • 4
    Dipole- and Heteroatom-Stabilized α-Amino-Organolithium Compounds
  • 5
    Mesomerically Stabilized α-Amino-Organolithium Compounds
  • 6
    Dipole- and Mesomerically Stabilized α-Amino-Organolithium Compounds
  • 7
    Acknowledgments

Keywords:

  • α-amino-organolithium compounds;
  • proton abstraction and metal preparation exchange;
  • unstabilized α-amino-organolithium compounds;
  • tin–lithium exchange;
  • allylic ethers and [2,3]-sigmatropic (Wittig) rearrangement ;
  • unsaturated organolithium compound anionic cyclization;
  • α-Amino-organolithium compounds;
  • mesomerically stabilized α-amino-organolithium compounds

Featured Compounds

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Compound 1
Molecular Weight:190.2417
Molecular Formula:C11H14N2O
InChIKey:PLERIDASECPNCJ-UHFFFAOYSA-N
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Compound 2
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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