Standard Article

Asymmetric Deprotonation with Alkyllithium–(−)-Sparteine

Organolithium Compounds (2004)

  1. Dieter Hoppe,
  2. Guido Christoph

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0313

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Hoppe, D. and Christoph, G. 2009. Asymmetric Deprotonation with Alkyllithium–(−)-Sparteine. Patai's Chemistry of Functional Groups. .

Author Information

  1. Organisch-Chemisches Institut der Westfälischen Wilhelms-Universität Münster, Münster, Germany

Publication History

  1. Published Online: 15 DEC 2009

Chemistry Terms

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Abstract

  • 1
    Introduction
  • 2
    Non-Mesomerically Stabilized Organolithium Compounds
  • 3
    (−)-Sparteine-Induced Lithiation with Formation of Benzyl-Type Organolithiums
  • 4
    Allyllithium–(−)-Sparteine Complexes
  • 5
    Lithium–(−)-Sparteine Complexes of 2-Alkynyl Carbamates
  • 6
    Axial–Chiral and Planar–Chiral Lithium–(−)-Sparteine Complexes
  • 7
    Enantioselective Addition of Achiral Carbanionic Compounds in the Presence of (−)-Sparteine

Keywords:

  • chiral organolithium compounds;
  • deprotonation reaction;
  • non-mesomerically stabilized organolithium compounds;
  • dipole stabilization acidification;
  • asymmetric deprotonation with alkyllithium–(–)-sparteine;
  • mesomeric stabilization;
  • allyllithium–(–)-sparteine complexes;
  • axial–chiral and planar–chiral lithium–(–)-sparteine complexes

Featured Compounds

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  1. 1 - 250
Compound 1
Molecular Weight:469.29
Molecular Formula:C23H42O2Sn
InChIKey:ZXVKFBJRDYFGGC-UHFFFAOYSA-N
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Compound 2
Molecular Weight:186.177
Molecular Formula:C11H15LiO2
InChIKey:INTPMRIJKCMTJA-UHFFFAOYSA-N
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Compound 3
Molecular Weight:194.2701
Molecular Formula:C12H18O2
InChIKey:RWVBUZUTPBMJHZ-LLVKDONJSA-N
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Compound 4
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 6
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound epi-6
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 7
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 11
Molecular Weight:234.3803
Molecular Formula:C15H26N2
InChIKey:SLRCCWJSBJZJBV-JKXDFHQYSA-N
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Compound 8
Molecular Weight:106.165
Molecular Formula:C8H10
InChIKey:YNQLUTRBYVCPMQ-UHFFFAOYSA-N
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Compound ent-7
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 9
Molecular Weight:346.478
Molecular Formula:C23H35LiN2
InChIKey:LUTVVEOGUDHWHX-OOOKPSEVSA-N
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Compound 10
Molecular Weight:150.1745
Molecular Formula:C9H10O2
InChIKey:YPGCWEMNNLXISK-SSDOTTSWSA-N
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Compound 149
Molecular Weight:171.2368
Molecular Formula:C9H17NO2
InChIKey:LPQZERIRKRYGGM-UHFFFAOYSA-N
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Compound 13
Molecular Weight:190.2417
Molecular Formula:C11H14N2O
InChIKey:ANJTVLIZGCUXLD-DTWKUNHWSA-N
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Compound 12
Molecular Weight:194.3165
Molecular Formula:C12H22N2
InChIKey:JHVZGAIDVLLSEV-TUAOUCFPSA-N
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Compound 14
Molecular Weight:234.3803
Molecular Formula:C15H26N2
InChIKey:SLRCCWJSBJZJBV-TUVASFSCSA-N
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Compound ent-11
Molecular Weight:234.3803
Molecular Formula:C15H26N2
InChIKey:SLRCCWJSBJZJBV-ZQDZILKHSA-N
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Compound 15
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 18
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 17
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 20
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 21
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 23
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound epi-23
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 24
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound ent-24
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 25
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 26
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 27
Molecular Weight:369.5817
Molecular Formula:C22H43NO3
InChIKey:XQADZNQIOHYFRL-IBGZPJMESA-N
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Compound 28
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 29
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 30
Molecular Weight:283.4064
Molecular Formula:C16H29NO3
InChIKey:VNUJEYFJJQYNQK-ZDUSSCGKSA-N
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Compound 31a
Molecular Weight:281.3905
Molecular Formula:C16H27NO3
InChIKey:BBLLSMNJXGMTQD-UHFFFAOYSA-N
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Compound 32a
Molecular Weight:263.3752
Molecular Formula:C16H25NO2
InChIKey:YQOFKFALLMRYLE-UHFFFAOYSA-N
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Compound 33a
Molecular Weight:321.4113
Molecular Formula:C18H27NO4
InChIKey:BSTJSSQVVRHFMG-UHFFFAOYSA-N
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Compound 35a
Molecular Weight:396.5225
Molecular Formula:C24H32N2O3
InChIKey:OHDKXQVKERTSLT-UHFFFAOYSA-N
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Compound 36a
Molecular Weight:410.5491
Molecular Formula:C25H34N2O3
InChIKey:FPVBDHXCFUAVRA-UHFFFAOYSA-N
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Compound 37a
Molecular Weight:386.4831
Molecular Formula:C19H34N2O6
InChIKey:MSLSEUDBMTXCOP-UHFFFAOYSA-N
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Compound 38a
Molecular Weight:414.5362
Molecular Formula:C21H38N2O6
InChIKey:LFGFKNOSQPHTSE-UHFFFAOYSA-N
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Compound 40a
Molecular Weight:609.7959
Molecular Formula:C35H51N3O6
InChIKey:SIAOKPAVIMFLIQ-LJAQVGFWSA-N
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Compound 39a
Molecular Weight:373.6028
Molecular Formula:C19H39NO4Si
InChIKey:AEKYISRLDSZXMA-UHFFFAOYSA-N
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Compound 25a
Molecular Weight:201.2628
Molecular Formula:C10H19NO3
InChIKey:WOCMGZWJJQPFGY-UHFFFAOYSA-N
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Compound 25b
Molecular Weight:202.2689
Molecular Formula:C10H19NO3
InChIKey:Not Available
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Compound 25c
Molecular Weight:259.2988
Molecular Formula:C12H21NO5
InChIKey:KUPWLJNQUZPQDK-MRVPVSSYSA-N
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Compound 25d
Molecular Weight:273.4439
Molecular Formula:C13H27NO3Si
InChIKey:YHGFMVRGZHGLFU-JTQLQIEISA-N
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Compound 25e
Molecular Weight:364.07
Molecular Formula:C13H27NO3Sn
InChIKey:XZXYFGOGRWHVOQ-UHFFFAOYSA-N
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Compound 25f
Molecular Weight:452.6
Molecular Formula:C13H27NO3Pb
InChIKey:VHHBKIONBZVKLZ-UHFFFAOYSA-N
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Compound 25g
Molecular Weight:241.3266
Molecular Formula:C13H23NO3
InChIKey:RPKUKTGPFOKMJK-SNVBAGLBSA-N
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Compound 26a
Molecular Weight:285.4222
Molecular Formula:C16H31NO3
InChIKey:OQOXHBVUBUVWQZ-UHFFFAOYSA-N
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Compound 26b
Molecular Weight:343.4583
Molecular Formula:C18H33NO5
InChIKey:RBJJMMCFYUWGDL-CQSZACIVSA-N
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Compound 28a
Molecular Weight:229.3159
Molecular Formula:C12H23NO3
InChIKey:NKMRNEAMIDPLQV-UHFFFAOYSA-N
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Compound 28b
Molecular Weight:287.352
Molecular Formula:C14H25NO5
InChIKey:RGFRYKLSRKWBRU-SNVBAGLBSA-N
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Compound 29a
Molecular Weight:243.3425
Molecular Formula:C13H25NO3
InChIKey:JNKPAYMFDZSBOI-UHFFFAOYSA-N
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Compound 29b
Molecular Weight:301.3786
Molecular Formula:C15H27NO5
InChIKey:KPSJXQPPTPQQJV-JTQLQIEISA-N
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Compound 31
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 31b
Molecular Weight:309.4006
Molecular Formula:C17H27NO4
InChIKey:YIUBIHPNMBUNGZ-CQSZACIVSA-N
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Compound 32
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 32b
Molecular Weight:349.4214
Molecular Formula:C19H27NO5
InChIKey:LFYNNJRZSCYKSR-OAHLLOKOSA-N
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Compound 33
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 33b
Molecular Weight:425.5173
Molecular Formula:C25H31NO5
InChIKey:VRDPBKZXUDFTIH-OAQYLSRUSA-N
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Compound 34
Molecular Weight:569.452
Molecular Formula:C32H36FeNO3P
InChIKey:OHLJFHIRIAKQCU-ASMAMLKCSA-N
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Compound 35
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 35b
Molecular Weight:454.5586
Molecular Formula:C26H34N2O5
InChIKey:YGYJRYGRTDVQFO-JOCHJYFZSA-N
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Compound 35c
Molecular Weight:468.7036
Molecular Formula:C27H40N2O3Si
InChIKey:XONULHZRKPHWEZ-DEOSSOPVSA-N
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Compound 35d
Molecular Weight:685.57
Molecular Formula:C36H58N2O3Sn
InChIKey:TYFOVUUJHOVZMS-UHFFFAOYSA-N
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Compound 35e
Molecular Weight:410.5491
Molecular Formula:C25H34N2O3
InChIKey:BFMBGDYNOCAPSU-FQEVSTJZSA-N
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Compound 36
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 36b
Molecular Weight:468.5851
Molecular Formula:C27H36N2O5
InChIKey:YZLKQXHVNOAMPM-HSZRJFAPSA-N
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Compound 36c
Molecular Weight:482.7302
Molecular Formula:C28H42N2O3Si
InChIKey:RJTZWQQFPDRARF-VWLOTQADSA-N
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Compound 36d
Molecular Weight:573.35
Molecular Formula:C28H42N2O3Sn
InChIKey:VOXCVLAUDFBVLZ-UHFFFAOYSA-N
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Compound 36e
Molecular Weight:424.5756
Molecular Formula:C26H36N2O3
InChIKey:LBSPKEIDPMROCG-NRFANRHFSA-N
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Compound 37
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 37b
Molecular Weight:400.5096
Molecular Formula:C20H36N2O6
InChIKey:NCKZYFSOBNTTCN-AWEZNQCLSA-N
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Compound 38b
Molecular Weight:472.5723
Molecular Formula:C23H40N2O8
InChIKey:AZVSNWPNSYOERO-HNNXBMFYSA-N
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Compound 39
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 39b
Molecular Weight:662.65
Molecular Formula:C31H65NO4SiSn
InChIKey:VWZAPWLMOUVLEL-UHFFFAOYSA-N
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Compound 40b
Molecular Weight:667.832
Molecular Formula:C37H53N3O8
InChIKey:JZDXLEZWTCWADI-BDCODIICSA-N
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Compound 42
Molecular Weight:469.629
Molecular Formula:C27H48LiN3O3
InChIKey:CEGMXZPRWAVIQP-OOOKPSEVSA-N
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Compound 43
Molecular Weight:269.3798
Molecular Formula:C15H27NO3
InChIKey:HLXBAXQNDYDTHS-LBPRGKRZSA-N
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Compound 41
Molecular Weight:229.3159
Molecular Formula:C12H23NO3
InChIKey:WVIXZRMFGYBCDT-UHFFFAOYSA-N
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Compound 44
Molecular Weight:503.689
Molecular Formula:C31H50LiN3O2
InChIKey:ZGXKULPELIEZKR-FLOVRWNLSA-N
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Compound 45
Molecular Weight:263.3752
Molecular Formula:C16H25NO2
InChIKey:SXEDYGJCDDYPRH-OAHLLOKOSA-N
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Compound 46
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 47
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 48
Molecular Weight:202.2689
Molecular Formula:C10H19NO3
InChIKey:Not Available
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Compound 49
Molecular Weight:274.45
Molecular Formula:C13H27NO3Si
InChIKey:Not Available
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Compound ent-25c
Molecular Weight:259.2988
Molecular Formula:C12H21NO5
InChIKey:KUPWLJNQUZPQDK-QMMMGPOBSA-N
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Compound ent-28b
Molecular Weight:287.352
Molecular Formula:C14H25NO5
InChIKey:RGFRYKLSRKWBRU-JTQLQIEISA-N
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Compound ent-29b
Molecular Weight:301.3786
Molecular Formula:C15H27NO5
InChIKey:KPSJXQPPTPQQJV-SNVBAGLBSA-N
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Compound 50
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound epi-50
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 50a
Molecular Weight:377.491
Molecular Formula:C20H40LiN3O3
InChIKey:WIOGDOSHHLCJBY-HSTMFJOWSA-N
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Compound 50b
Molecular Weight:405.544
Molecular Formula:C22H44LiN3O3
InChIKey:OKOVFOSBJCCSOD-XCONSJKQSA-N
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Compound 50c
Molecular Weight:419.571
Molecular Formula:C23H46LiN3O3
InChIKey:INUSSIXKOAKEJF-XCONSJKQSA-N
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Compound epi-50a
Molecular Weight:377.491
Molecular Formula:C20H40LiN3O3
InChIKey:WIOGDOSHHLCJBY-HSTMFJOWSA-N
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Compound epi-50b
Molecular Weight:405.544
Molecular Formula:C22H44LiN3O3
InChIKey:OKOVFOSBJCCSOD-XCONSJKQSA-N
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Compound epi-50c
Molecular Weight:419.571
Molecular Formula:C23H46LiN3O3
InChIKey:INUSSIXKOAKEJF-XCONSJKQSA-N
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Compound 51
Molecular Weight:654.85
Molecular Formula:C36H63LiN4O6
InChIKey:FEYWFURWZNHNLN-FLOVRWNLSA-N
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Compound 52
Molecular Weight:241.3266
Molecular Formula:C13H23NO3
InChIKey:IJLUVCRDVPHLSE-VIFPVBQESA-N
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Compound 53
Molecular Weight:299.3627
Molecular Formula:C15H25NO5
InChIKey:BIKQVRIBRFUBIT-OAHLLOKOSA-N
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Compound 54
Molecular Weight:492.6496
Molecular Formula:C30H40N2O4
InChIKey:MBZLGLFFGHXRAE-SMSORMJASA-N
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Compound ent-51
Molecular Weight:654.85
Molecular Formula:C36H63LiN4O6
InChIKey:FEYWFURWZNHNLN-FLOVRWNLSA-N
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Compound ent-52
Molecular Weight:241.3266
Molecular Formula:C13H23NO3
InChIKey:IJLUVCRDVPHLSE-SECBINFHSA-N
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Compound ent-53
Molecular Weight:299.3627
Molecular Formula:C15H25NO5
InChIKey:BIKQVRIBRFUBIT-HNNXBMFYSA-N
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Compound 55a
Molecular Weight:331.4492
Molecular Formula:C20H29NO3
InChIKey:FJPJWACXNRINGT-XYOKQWHBSA-N
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Compound 55b
Molecular Weight:359.5023
Molecular Formula:C22H33NO3
InChIKey:OIZDZVLXTRXHKM-JLHYYAGUSA-N
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Compound 58a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 58b
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 59
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 60
Molecular Weight:303.4391
Molecular Formula:C19H29NO2
InChIKey:YYVSZIKLPREVQV-XYOKQWHBSA-N
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Compound 63
Molecular Weight:433.6993
Molecular Formula:C25H43NO3Si
InChIKey:VMNFCCSKAMSQSW-ZRBLBEILSA-N
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Compound 64
Molecular Weight:288.4998
Molecular Formula:C18H28OSi
InChIKey:SKBOHWLXUKGBCJ-VQHPVUNQSA-N
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Compound rac-61
Molecular Weight:433.6993
Molecular Formula:C25H43NO3Si
InChIKey:SYWVNMWVEHPWFG-ISLYRVAYSA-N
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Compound 65
Molecular Weight:481.6991
Molecular Formula:C28H39NO4Si
InChIKey:GFKGTFPTWUAZTE-MHWRWJLKSA-N
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Compound 66
Molecular Weight:481.6991
Molecular Formula:C28H39NO4Si
InChIKey:TUWSJJQLVRPRKD-GPXOXTDOSA-N
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Compound 67
Molecular Weight:174.239
Molecular Formula:C12H14O
InChIKey:DPAZULIIEZCTIE-GDGBQDQQSA-N
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Compound 68
Molecular Weight:208.2536
Molecular Formula:C12H16O3
InChIKey:CRUPQWXFXICCEV-JLLWLGSASA-N
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Compound 69
Molecular Weight:526.7089
Molecular Formula:C34H42N2O3
InChIKey:JLRCDNBLSACYNR-DTERZYDESA-N
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Compound 70
Molecular Weight:526.7089
Molecular Formula:C34H42N2O3
InChIKey:YOCXPIGDEPCSSY-MJSOWUPRSA-N
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Compound rac-71
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 72
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 73
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 74
Molecular Weight:552.7462
Molecular Formula:C36H44N2O3
InChIKey:YZBOGCRNYCKUAM-PTRFHKNWSA-N
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Compound 75
Molecular Weight:558.679
Molecular Formula:C36H43LiN2O3
InChIKey:CWLPZMWEIZGIDD-NXAKACHASA-N
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Compound 76
Molecular Weight:552.7462
Molecular Formula:C36H44N2O3
InChIKey:NQNQCHKMWPKSGF-MQEUCWLYSA-N
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Compound 77
Molecular Weight:552.7462
Molecular Formula:C36H44N2O3
InChIKey:QMVHAQICRYTHOL-IFHZMTQUSA-N
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Compound 78
Molecular Weight:546.37
Molecular Formula:C25H49NO4Sn
InChIKey:KKDIBJQPLGQRLY-UHFFFAOYSA-N
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Compound 79
Molecular Weight:592.87
Molecular Formula:C27H52ClNO3Sn
InChIKey:ZKLOWKUSVVZKIV-UFCFYSFLSA-N
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Compound 81
Molecular Weight:267.3639
Molecular Formula:C15H25NO3
InChIKey:SLPFKVYVXJISJN-VXGBXAGGSA-N
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Compound 82
Molecular Weight:175.154
Molecular Formula:C9H14LiNO2
InChIKey:MNIQYMVPZRIRER-UHFFFAOYSA-N
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Compound 83
Molecular Weight:504.33
Molecular Formula:C23H47NO3Sn
InChIKey:WQRFXHUKJBILDQ-UHFFFAOYSA-N
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Compound 84
Molecular Weight:787.82
Molecular Formula:C38H76N2O5SiSn
InChIKey:SHGMULWRXJCMFP-UHFFFAOYSA-N
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Compound 86
Molecular Weight:504.704
Molecular Formula:C26H49LiN2O5Si
InChIKey:LAZSWXJJFLYBEG-GCUSPBPKSA-N
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Compound 87
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 87a
Molecular Weight:498.7711
Molecular Formula:C26H50N2O5Si
InChIKey:IBKSCXIUAJAWPW-SWXNLADBSA-N
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Compound 87b
Molecular Weight:570.9522
Molecular Formula:C29H58N2O5Si2
InChIKey:YLUWUITUFQRECL-WJACPXSLSA-N
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Compound 87c
Molecular Weight:512.7977
Molecular Formula:C27H52N2O5Si
InChIKey:UVNGUSGPCZDJJM-SWNFIOEFSA-N
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Compound 88
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 88a
Molecular Weight:498.7711
Molecular Formula:C26H50N2O5Si
InChIKey:IBKSCXIUAJAWPW-PWECSXFSSA-N
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Compound 88b
Molecular Weight:570.9522
Molecular Formula:C29H58N2O5Si2
InChIKey:YLUWUITUFQRECL-GWAYXRLQSA-N
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Compound 88c
Molecular Weight:512.7977
Molecular Formula:C27H52N2O5Si
InChIKey:UVNGUSGPCZDJJM-JTTVLKEHSA-N
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Compound 89
Molecular Weight:486.645
Molecular Formula:C31H38N2O3
InChIKey:KTFBGFLNDOWDLK-NDEPHWFRSA-N
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Compound 90a
Molecular Weight:608.783
Molecular Formula:C37H53LiN4O3
InChIKey:OAAWIFYWVJIJPC-ZXVJYWQYSA-N
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Compound 91a
Molecular Weight:608.783
Molecular Formula:C37H53LiN4O3
InChIKey:OAAWIFYWVJIJPC-ZXVJYWQYSA-N
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Compound 90b
Molecular Weight:726.958
Molecular Formula:C46H63LiN4O3
InChIKey:FXKIXPGSJRMFLE-JUQFKADYSA-N
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Compound 91b
Molecular Weight:757.027
Molecular Formula:C48H69LiN4O3
InChIKey:VRVZNPKFPSYVMN-UBXFXIQCSA-N
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Compound 90
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 91
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound R-92
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 94
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 96
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 95
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound S-92
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 93
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound rac-97
Molecular Weight:291.3853
Molecular Formula:C17H25NO3
InChIKey:WJCNQLPKWWXZLZ-UHFFFAOYSA-N
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Compound rac-100
Molecular Weight:317.4226
Molecular Formula:C19H27NO3
InChIKey:UXJCUJWTIZUWPG-UHFFFAOYSA-N
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Compound S-97
Molecular Weight:291.3853
Molecular Formula:C17H25NO3
InChIKey:WJCNQLPKWWXZLZ-CYBMUJFWSA-N
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Compound 102
Molecular Weight:462.579
Molecular Formula:C25H38N2O6
InChIKey:CTBLEWNYQUEQQU-UHFFFAOYSA-N
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Compound 103
Molecular Weight:468.512
Molecular Formula:C25H37LiN2O6
InChIKey:WMZCOPLEYPAVSY-FSRHSHDFSA-N
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Compound 104
Molecular Weight:468.512
Molecular Formula:C25H37LiN2O6
InChIKey:WMZCOPLEYPAVSY-FYZYNONXSA-N
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Compound 93a
Molecular Weight:456.546
Molecular Formula:C28H37LiN2O3
InChIKey:LPNDKINYYZDXMV-VQIWEWKSSA-N
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Compound 94a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound ent-94
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound ent-96
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound epi-93
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound epi-95
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound R-92a
Molecular Weight:450.6129
Molecular Formula:C28H38N2O3
InChIKey:IIEMVWPOACXOIY-RUZDIDTESA-N
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Compound S-92a
Molecular Weight:450.6129
Molecular Formula:C28H38N2O3
InChIKey:IIEMVWPOACXOIY-VWLOTQADSA-N
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Compound 98
Molecular Weight:454.19
Molecular Formula:C20H33NO3Sn
InChIKey:VQILNNKNHPRGCM-AHJYMZSGSA-N
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Compound 99
Molecular Weight:454.19
Molecular Formula:C20H33NO3Sn
InChIKey:VQILNNKNHPRGCM-SVZPRBGCSA-N
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Compound 101
Molecular Weight:375.4587
Molecular Formula:C21H29NO5
InChIKey:FFEFGSLUFWUXMQ-DLBZAZTESA-N
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Compound R-100
Molecular Weight:317.4226
Molecular Formula:C19H27NO3
InChIKey:UXJCUJWTIZUWPG-HNNXBMFYSA-N
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Compound 105
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 105a
Molecular Weight:625.38
Molecular Formula:C28H46N2O6Sn
InChIKey:DQAVAKYESYVUSO-MXFMKSRJSA-N
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Compound 105b
Molecular Weight:546.6954
Molecular Formula:C30H46N2O7
InChIKey:AIYFULPSVLFSLN-FGZHOGPDSA-N
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Compound 106
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 106a
Molecular Weight:625.38
Molecular Formula:C28H46N2O6Sn
InChIKey:DQAVAKYESYVUSO-QMKYUQMLSA-N
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Compound 106b
Molecular Weight:546.6954
Molecular Formula:C30H46N2O7
InChIKey:AIYFULPSVLFSLN-FCHUYYIVSA-N
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Compound 107
Molecular Weight:454.6001
Molecular Formula:C24H42N2O6
InChIKey:RRNLCHMSIIFVTL-HDICACEKSA-N
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Compound 108
Molecular Weight:694.913
Molecular Formula:C39H67LiN4O6
InChIKey:TVAJCFIFBWASSD-GPZSEVJZSA-N
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Compound 110
Molecular Weight:694.913
Molecular Formula:C39H67LiN4O6
InChIKey:TVAJCFIFBWASSD-MPFOOVNDSA-N
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Compound 111
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 109
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 109a
Molecular Weight:617.41
Molecular Formula:C27H50N2O6Sn
InChIKey:HQIHWJJKLKQGGJ-IGEOGUOMSA-N
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Compound 109c
Molecular Weight:468.6267
Molecular Formula:C25H44N2O6
InChIKey:VXGDLLOZRYQUIW-OTWHNJEPSA-N
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Compound 109b
Molecular Weight:512.6362
Molecular Formula:C26H44N2O8
InChIKey:YERXOILALQCMKO-GUDVDZBRSA-N
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Compound ent-109d
Molecular Weight:743.64
Molecular Formula:C36H68N2O6Sn
InChIKey:ZHEKIQSKTGBBIN-PRCPTQGPSA-N
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Compound 109d
Molecular Weight:743.64
Molecular Formula:C36H68N2O6Sn
InChIKey:ZHEKIQSKTGBBIN-IGEOGUOMSA-N
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Compound R-112
Molecular Weight:386.5277
Molecular Formula:C23H34N2O3
InChIKey:YJXPGUVNICHULY-XEDBTPMOSA-N
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Compound 114
Molecular Weight:392.461
Molecular Formula:C23H33LiN2O3
InChIKey:RIHPHJXCIHZUHR-OACSPZGTSA-N
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Compound S-112
Molecular Weight:386.5277
Molecular Formula:C23H34N2O3
InChIKey:YJXPGUVNICHULY-YPNIWSFNSA-N
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Compound 115
Molecular Weight:385.5429
Molecular Formula:C23H35N3O2
InChIKey:FVRGODSXRFBNND-AQNXPRMDSA-N
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Compound R-116
Molecular Weight:343.4599
Molecular Formula:C21H29NO3
InChIKey:JIBJFBANEAERMI-OAQYLSRUSA-N
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Compound S-116
Molecular Weight:343.4599
Molecular Formula:C21H29NO3
InChIKey:JIBJFBANEAERMI-NRFANRHFSA-N
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Compound S,S-117
Molecular Weight:583.773
Molecular Formula:C36H54LiN3O3
InChIKey:IGACIIBSHUBSFK-ARQSFEELSA-N
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Compound R,S-117
Molecular Weight:583.773
Molecular Formula:C36H54LiN3O3
InChIKey:IGACIIBSHUBSFK-BESJKQNHSA-N
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Compound 118
Molecular Weight:583.773
Molecular Formula:C36H54LiN3O3
InChIKey:HPVCQBTZPSOFLD-LKDIDBNNSA-N
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Compound 119
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 120
Molecular Weight:170.2503
Molecular Formula:C13H14
InChIKey:QPXIMLXGKPIFOC-CTEVKTCYSA-N
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Compound 121
Molecular Weight:360.4904
Molecular Formula:C21H32N2O3
InChIKey:KFPWCTAFPFJHCS-GOSISDBHSA-N
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Compound 122
Molecular Weight:346.4638
Molecular Formula:C20H30N2O3
InChIKey:RNWSLBBURYJUJD-KRWDZBQOSA-N
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Compound 123
Molecular Weight:595.7694
Molecular Formula:C34H49N3O6
InChIKey:AYBNHPKDEQTOLA-NDEPHWFRSA-N
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Compound 124
Molecular Weight:126.1962
Molecular Formula:C8H14O
InChIKey:MELPJGOMEMRMPL-OCAPTIKFSA-N
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Compound 125
Molecular Weight:132.129
Molecular Formula:C8H13LiO
InChIKey:HCDMMVKORIGHBU-XRUQTVKYSA-N
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Compound 126
Molecular Weight:132.129
Molecular Formula:C8H13LiO
InChIKey:UMDUKXOCLLJGRQ-FJXQXJEOSA-N
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Compound 128
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 127
Molecular Weight:132.129
Molecular Formula:C8H13LiO
InChIKey:HKABHADDWHLREU-LRACWOHVSA-N
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Compound 129
Molecular Weight:126.1962
Molecular Formula:C8H14O
InChIKey:AOONMBCPMGBOBG-BIIVOSGPSA-N
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Compound ent-129
Molecular Weight:126.1962
Molecular Formula:C8H14O
InChIKey:AOONMBCPMGBOBG-PRJMDXOYSA-N
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Compound 130
Molecular Weight:110.1537
Molecular Formula:C7H10O
InChIKey:OHNNZOOGWXZCPZ-CYDAGYADSA-N
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Compound 132
Molecular Weight:386.7167
Molecular Formula:C20H42O3Si2
InChIKey:YRRHHDQREIQMSV-FZDBZEDMSA-N
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Compound 134
Molecular Weight:386.7167
Molecular Formula:C20H42O3Si2
InChIKey:BLAWJFOREIWNQS-USTZCAOPSA-N
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Compound 131
Molecular Weight:110.1537
Molecular Formula:C7H10O
InChIKey:OZMQKGXJENMAHL-VICYTKJSSA-N
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Compound 133
Molecular Weight:386.7167
Molecular Formula:C20H42O3Si2
InChIKey:FYSAPCUEYABLSV-BOSXTWCSSA-N
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Compound 135
Molecular Weight:386.7167
Molecular Formula:C20H42O3Si2
InChIKey:NTQWFRZQFJXUTM-FLXSYLCISA-N
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Compound 136
Molecular Weight:386.7167
Molecular Formula:C20H42O3Si2
InChIKey:BLAWJFOREIWNQS-FZDBZEDMSA-N
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Compound 138
Molecular Weight:386.7167
Molecular Formula:C20H42O3Si2
InChIKey:HGTXLVFMCDMVLP-GCNJGVOGSA-N
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Compound 137
Molecular Weight:386.7167
Molecular Formula:C20H42O3Si2
InChIKey:NTQWFRZQFJXUTM-ADHGMGHFSA-N
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Compound 139
Molecular Weight:124.1803
Molecular Formula:C8H12O
InChIKey:YWFPXWMSGJXUFS-VMPVEFHESA-N
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Compound 140
Molecular Weight:124.1803
Molecular Formula:C8H12O
InChIKey:GAJWLWOIFZSYOW-BFZCNVHISA-N
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Compound 141
Molecular Weight:124.1803
Molecular Formula:C8H12O
InChIKey:NWSDLEBQGQVEKA-RNJXMRFFSA-N
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Compound 142
Molecular Weight:132.129
Molecular Formula:C8H13LiO
InChIKey:UMDUKXOCLLJGRQ-FJXQXJEOSA-N
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Compound 143
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 143a
Molecular Weight:198.3773
Molecular Formula:C11H22OSi
InChIKey:LIPUKTMIRZWFLA-QWRGUYRKSA-N
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Compound 143b
Molecular Weight:415.24
Molecular Formula:C20H40OSn
InChIKey:GYEUNSAEHZAOSD-HEDVWWMMSA-N
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Compound 143c
Molecular Weight:184.2753
Molecular Formula:C11H20O2
InChIKey:ISPDLWYPWOVBDS-DVRYWGNFSA-N
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Compound 143d
Molecular Weight:198.2588
Molecular Formula:C11H18O3
InChIKey:ICLKAODPTSGAJM-ONGXEEELSA-N
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Compound 144
Molecular Weight:268.4671
Molecular Formula:C15H28O2Si
InChIKey:YOIRMNMIZWNKBW-SIMOQEFBSA-N
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Compound 147
Molecular Weight:301.3786
Molecular Formula:C15H27NO5
InChIKey:PMQHRWHOZGXQHR-UHFFFAOYSA-N
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Compound 146
Molecular Weight:270.483
Molecular Formula:C15H30O2Si
InChIKey:AFKJNOLSEMNDRK-RQJABVFESA-N
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Compound 148
Molecular Weight:301.3786
Molecular Formula:C15H27NO5
InChIKey:IBLMLPOAOYWZQR-FRRDWIJNSA-N
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Compound 150
Molecular Weight:411.55
Molecular Formula:C24H42LiN3O2
InChIKey:QMSIXWZNCHKGIM-NFFOJHPUSA-N
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Compound 151
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 151d
Molecular Weight:353.4547
Molecular Formula:C22H27NO3
InChIKey:IRUWVJPUDXOJLJ-LJQANCHMSA-N
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Compound 151a
Molecular Weight:243.4179
Molecular Formula:C12H25NO2Si
InChIKey:HJGAXMDEXCEYGL-JTQLQIEISA-N
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Compound 151b
Molecular Weight:185.2634
Molecular Formula:C10H19NO2
InChIKey:PPUYUEPZGGATCN-QMMMGPOBSA-N
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Compound 151c
Molecular Weight:460.28
Molecular Formula:C21H43NO2Sn
InChIKey:PZUXJSXENZTXMP-UHFFFAOYSA-N
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Compound ent-151
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound E-152
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Z-152
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 153
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 154
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 155
Molecular Weight:91.081
Molecular Formula:C5H10LiN
InChIKey:WJGZBPOAGDFKJX-UHFFFAOYSA-N
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Compound 156
Molecular Weight:239.305
Molecular Formula:C14H18LiNS
InChIKey:ZBLGENJFXOAGDU-FTPOTTDRSA-N
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Compound 157
Molecular Weight:207.24
Molecular Formula:C14H18LiN
InChIKey:GYIIZVLUISNUCH-UHFFFAOYSA-N
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Compound 158
Molecular Weight:160.186
Molecular Formula:C9H17LiN2
InChIKey:XEVPFIXALFXIBO-VRTOBVRTSA-N
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Compound 159
Molecular Weight:185.2634
Molecular Formula:C10H19NO2
InChIKey:RQCNHUCCQJMSRG-UHFFFAOYSA-N
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Compound 160
Molecular Weight:257.4445
Molecular Formula:C13H27NO2Si
InChIKey:BSZHRPQJZZLGMD-NSHDSACASA-N
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Compound 161
Molecular Weight:355.449
Molecular Formula:C17H25NO5S
InChIKey:IKOMRHLHPZAEMV-UHFFFAOYSA-N
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Compound 162
Molecular Weight:595.763
Molecular Formula:C32H50LiN3O5S
InChIKey:YOYDPRTZSFCWMG-HQQPDLTJSA-N
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