Standard Article

Acidity and Basicity of Cyclobutanes

Cyclobutanes (2005)

  1. Esther Quintanilla1,
  2. Juan Z. Dávalos1,
  3. José Luis M. Abboud1,
  4. Ibon Alkorta2

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0319

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Quintanilla, E., Dávalos, J. Z., Abboud, J. L. M. and Alkorta, I. 2009. Acidity and Basicity of Cyclobutanes. Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    Instituto de Química Física ‘Rocasolano’, CSIC, Madrid, Spain

  2. 2

    Instituto de Química Médica, CSIC, Madrid, Spain

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Geometrical Structures
  • 3
    Some Consequences of the Geometrical Structures
  • 4
    Selected Reactions
  • 5
    CB and CUB as Bases
  • 6
    Hydrogen Bonding (HB)
  • 7
    CB and CUB as Substituents
  • 8
    Acknowledgments

Keywords:

  • chemistry of cyclobutanes;
  • acid–base properties of cyclobutane (CB) and cubane (CUB);
  • gas-phase diffraction data and rg values of bond lengths;
  • CB geometry - ring puckering and methylene group inward rocking;
  • CUB geometric structure;
  • negative charge stabilization;
  • infrared multiple photon (IRM) photochemical activation;
  • anionic hyperconjugation - carbanion stabilizing role

Featured Compounds

VIEW

  1. 1 - 3
Compound 3+
Molecular Weight:103.1406
Molecular Formula:C8H7
InChIKey:NKDFVYJXVLTFJA-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound A
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound B
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound

VIEW

  1. 1 - 3