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The Chemistry of Acyllithium Derivatives

Organolithium Compounds (2006)

  1. Carmen Najera,
  2. Miguel Yus

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0340

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Najera, C. and Yus, M. 2009. The Chemistry of Acyllithium Derivatives. Patai's Chemistry of Functional Groups. .

Author Information

  1. Universidad de Alicante, Departamento de Química Orgánica, Facultad de Ciencias, and Instituto de Síntesis Orgánica (ISO), Alicante, Spain

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Unprotected Acyllithium Derivatives
  • 3
    Protected Acyllithium Equivalents
  • 4
    Other Acyllithium Equivalents
  • 5
    Conclusions
  • 6
    Acknowledgments

Keywords:

  • electrophilic substrate acylation reaction with acyllithium derivative;
  • unprotected acyllithium derivatives;
  • acyllithium dimerization mechanism;
  • dimethyl thiocarbamoyllithium;
  • sulfone bearing alkoxy or acyloxy functionality;
  • acyllithium derivative chemistry;
  • sulfone moiety - good acidifying group;
  • α-Heteroatom-substituted alkenyl-, dienyl- and allenyllithium derivatives