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Aspects of the Synthesis, Structure and Reactivity of Lithium Enolates

Organolithium Compounds (2006)

  1. Jean-Yves Valnot,
  2. Jacques Maddaluno

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0345

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Valnot, J.-Y. and Maddaluno, J. 2009. Aspects of the Synthesis, Structure and Reactivity of Lithium Enolates. Patai's Chemistry of Functional Groups. .

Author Information

  1. Université de Rouen, Laboratoire des Fonctions Azotées & Oxygénées Complexes de l'IRCOF, Mont St Aignan Cedex, France

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Synthesis of Lithium Enolates
  • 3
    Structure of Lithium Enolates
  • 4
    Reactivity of Lithium Enolates

Keywords:

  • lithium enolate synthesis;
  • enolate synthesis from enol ethers and esters;
  • carbon nucleophile addition;
  • enolate synthesis by miscellaneous methods;
  • lithium enolate reactivity;
  • preformed lithium enolates and alkylation and acylation;
  • directed aldol reaction;
  • enantioselective aldol reaction

Featured Compounds

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Compound 2
Molecular Weight:981.297
Molecular Formula:C66H86Li2N4O2
InChIKey:GQQODKLFKCNOSU-CWLRCDKUSA-N
View compound in article | Full details | Search for this compound

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  1. 1