Standard Article

The Structural Chemistry of Acyclic Organic Peroxides

Peroxides (2006)

  1. Jens Hartung1,
  2. Ingrid Svoboda2

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0348

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Hartung, J. and Svoboda, I. 2009. The Structural Chemistry of Acyclic Organic Peroxides. Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    Technische Universität Kaiserslautern, Fachbereich Chemie, Organische Chemie, Kaiserslautern, Germany

  2. 2

    Technische Universität Darmstadt, Fachgebiet Strukturforschung, FB 11, Material-und Geowissenschaften, Darmstadt, Germany

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Basic Principles
  • 3
    Organic Peroxy Compounds
  • 4
    Polyoxo Compounds
  • 5
    Natural Products
  • 6
    Concluding Remarks

Keywords:

  • acyclic organic peroxide structural chemistry;
  • acyclic organic peroxides - structure and bonding;
  • lone pair repulsion;
  • organic peroxy compound;
  • hydrocarbon autoxidations with molecular oxygen;
  • neutral organic peroxides;
  • alkyl hydroperoxide anion as ligand;
  • peroxide functionality as antimalarial qinghaosu (artemisinin) pharmacophore

Featured Compounds

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  1. 1 - 78
Compound 1
Molecular Weight:90.121
Molecular Formula:C4H10O2
InChIKey:CIHOLLKRGTVIJN-UHFFFAOYSA-N
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Compound 3
Molecular Weight:102.0126
Molecular Formula:CHF3O2
InChIKey:UANXSGVNVXTETO-UHFFFAOYSA-N
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Compound 4
Molecular Weight:238.2359
Molecular Formula:C8H7KO6
InChIKey:RWHDSCGHPUUIGA-UHFFFAOYSA-M
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Compound 5
Molecular Weight:62.0678
Molecular Formula:C2H6O2
InChIKey:SRXOCFMDUSFFAK-UHFFFAOYSA-N
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Compound 6
Molecular Weight:146.2273
Molecular Formula:C8H18O2
InChIKey:Not Available
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Compound 7
Molecular Weight:170.2487
Molecular Formula:C10H18O2
InChIKey:VKCPPMKRNVBDOD-UHFFFAOYSA-N
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Compound 8
Molecular Weight:276.3291
Molecular Formula:C19H16O2
InChIKey:Not Available
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Compound 9
Molecular Weight:518.6436
Molecular Formula:C38H30O2
InChIKey:CGQJDFJVDYLLLN-UHFFFAOYSA-N
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Compound 12
Molecular Weight:170.0106
Molecular Formula:C2F6O2
InChIKey:BPXRXDJNYFWRDI-UHFFFAOYSA-N
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Compound 10
Molecular Weight:120.0031
Molecular Formula:CF4O2
InChIKey:AIKCCGFRZVLPIC-UHFFFAOYSA-N
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Compound 11
Molecular Weight:136.458
Molecular Formula:CClF3O2
InChIKey:MBHVCOIELKGWNR-UHFFFAOYSA-N
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Compound 13
Molecular Weight:147.0102
Molecular Formula:CF3NO4
InChIKey:IRCOOTKZKSUTLW-UHFFFAOYSA-N
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Compound 15
Molecular Weight:60.052
Molecular Formula:C2H4O2
InChIKey:IEZWOVIWXFLQTP-UHFFFAOYSA-N
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Compound 17
Molecular Weight:110.1106
Molecular Formula:C6H6O2
InChIKey:JYINMLPNDRBKKZ-UHFFFAOYSA-N
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Compound 16
Molecular Weight:74.0785
Molecular Formula:C3H6O2
InChIKey:LYPJURWUGVQBTD-UHFFFAOYSA-N
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Compound 18
Molecular Weight:121.0489
Molecular Formula:C2H3NO5
InChIKey:VGQXTTSVLMQFHM-UHFFFAOYSA-N
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Compound 19
Molecular Weight:175.0203
Molecular Formula:C2F3NO5
InChIKey:RVINLGAKTAPHME-UHFFFAOYSA-N
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Compound 20
Molecular Weight:219.2365
Molecular Formula:C12H13NO3
InChIKey:TUCGTODTVORMIS-UHFFFAOYSA-N
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Compound 21
Molecular Weight:252.3095
Molecular Formula:C13H20N2O3
InChIKey:MCCDUXYKOGRQQX-CYBMUJFWSA-N
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Compound 22
Molecular Weight:211.2609
Molecular Formula:C10H17N3O2
InChIKey:BFOLXQNZYGKCCQ-UHFFFAOYSA-N
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Compound 23
Molecular Weight:178.2261
Molecular Formula:C8H18O4
InChIKey:JGBAASVQPMTVHO-UHFFFAOYSA-N
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Compound 24
Molecular Weight:312.3166
Molecular Formula:C18H16O5
InChIKey:XWRQAHNHDYRDLZ-SQNIBIBYSA-N
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Compound 25
Molecular Weight:268.3056
Molecular Formula:C14H20O5
InChIKey:BGKVVYGMFLVOAJ-UONOGXRCSA-N
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Compound 26
Molecular Weight:289.393
Molecular Formula:C16H19NO2S
InChIKey:GTABYMUTULMIIF-UHFFFAOYSA-N
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Compound 27
Molecular Weight:333.23
Molecular Formula:C14H14Cl2O3S
InChIKey:CBBSCLLQRCQLFP-UHFFFAOYSA-N
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Compound 28
Molecular Weight:211.054
Molecular Formula:C6H11BrO3
InChIKey:PUDYZEPVMLYVET-UHFFFAOYSA-N
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Compound 29
Molecular Weight:329.3472
Molecular Formula:C18H19NO5
InChIKey:PYMABTFSARRFGA-VWMHFEHESA-N
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Compound 30
Molecular Weight:252.3062
Molecular Formula:C14H20O4
InChIKey:NYPDVVIDZMGSIH-UHFFFAOYSA-N
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Compound 31
Molecular Weight:320.3042
Molecular Formula:C15H19F3O4
InChIKey:NXJAGKFCNBYIKE-JHJVBQTASA-N
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Compound 32
Molecular Weight:566.5615
Molecular Formula:C31H36O6P2
InChIKey:BOUVCVMIIRRMPL-UHFFFAOYSA-N
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Compound 33
Molecular Weight:242.2683
Molecular Formula:C12H18O5
InChIKey:JGBJRTWILYHUCV-UHFFFAOYSA-N
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Compound 34
Molecular Weight:1152.649
Molecular Formula:C48H108Li12O24
InChIKey:MRWDJDDIKNMBCI-UHFFFAOYSA-B
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Compound 35
Molecular Weight:302.619
Molecular Formula:C14H19ClO2Ti
InChIKey:PMSPSHSZQCQHMZ-UHFFFAOYSA-L
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Compound 36
Molecular Weight:566.289
Molecular Formula:C20H42N2O10Ti2
InChIKey:GBCNMDJWVGWOJG-UHFFFAOYSA-L
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Compound 37
Molecular Weight:426.85
Molecular Formula:C16H24HfO2
InChIKey:WJIAGHDYURYMQF-UHFFFAOYSA-M
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Compound 38
Molecular Weight:428.3659
Molecular Formula:C18H29CoN2O6
InChIKey:KQMNQEJFGIPMQP-VGKOASNMSA-K
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Compound 39
Molecular Weight:740.14
Molecular Formula:C36H60BN7O2Pd
InChIKey:IXFKBVBERZSYKT-UHFFFAOYSA-M
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Compound 40
Molecular Weight:546.129
Molecular Formula:C24H54Ga2O4
InChIKey:RLJCZTVAAAXKHE-UHFFFAOYSA-L
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Compound 41
Molecular Weight:636.319
Molecular Formula:C24H54In2O4
InChIKey:GAXRERAJVIRQIZ-UHFFFAOYSA-L
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Compound 42
Molecular Weight:519.29
Molecular Formula:C28H29O2Sb
InChIKey:IBRYNGGLAKAWLY-UHFFFAOYSA-M
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Compound 43
Molecular Weight:418.2989
Molecular Formula:C15H19IO4Si
InChIKey:OADOIUOVVREYIJ-UHFFFAOYSA-N
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Compound 44
Molecular Weight:648.448
Molecular Formula:C10Cl14O2
InChIKey:DYJKZYHSEYGFBT-UHFFFAOYSA-N
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Compound 45
Molecular Weight:694.962
Molecular Formula:C36H28ClO6Rh
InChIKey:ADFPUXWSCIXPSE-UHFFFAOYSA-M
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Compound 46
Molecular Weight:278.3435
Molecular Formula:C16H22O4
InChIKey:USKBVFMTCVCBIH-RRCSTGOVSA-N
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Compound 47
Molecular Weight:416.4706
Molecular Formula:C28H20N2O2
InChIKey:IVCJQTNLTTZOQO-UHFFFAOYSA-N
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Compound 48
Molecular Weight:470.5977
Molecular Formula:C28H38O6
InChIKey:QVMSUOURBBDAIL-VSGBNLITSA-N
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Compound 49
Molecular Weight:470.5977
Molecular Formula:C28H38O6
InChIKey:QVMSUOURBBDAIL-HNRBIFIRSA-N
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Compound 50
Molecular Weight:277.2726
Molecular Formula:C14H15NO5
InChIKey:UZJGVXSQDRSSHU-UHFFFAOYSA-N
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Compound 51
Molecular Weight:271.247
Molecular Formula:C10H9NO6S
InChIKey:IEHDOZDPERAHPH-UHFFFAOYSA-N
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Compound 52
Molecular Weight:195.1721
Molecular Formula:C9H9NO4
InChIKey:KUIMAGXDVDAQEA-UHFFFAOYSA-N
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Compound 53
Molecular Weight:1069.286
Molecular Formula:C43H43Cl3Cu2N6O12
InChIKey:XJWYJQMKSQPBMD-UHFFFAOYSA-J
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Compound 54
Molecular Weight:464.4178
Molecular Formula:C19H28O13
InChIKey:DDZWSIJLYIEIJG-OAGGEKHMSA-N
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Compound 55
Molecular Weight:362.546
Molecular Formula:C23H38O3
InChIKey:QUXLEQCBMLJJDB-UHFFFAOYSA-N
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Compound 56
Molecular Weight:478.4444
Molecular Formula:C20H30O13
InChIKey:LHQKFHSNAUGBQN-XDCWJTEKSA-N
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Compound 57
Molecular Weight:294.3014
Molecular Formula:C18H14O4
InChIKey:YPWDLNYZZVNNKN-PHEQNACWSA-N
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Compound 58
Molecular Weight:274.2256
Molecular Formula:C14H10O6
InChIKey:SQHSUOBKWACYNG-UHFFFAOYSA-N
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Compound 59
Molecular Weight:184.2371
Molecular Formula:C12H12N2
InChIKey:YBQZXXMEJHZYMB-UHFFFAOYSA-N
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Compound 60
Molecular Weight:206.2824
Molecular Formula:C16H14
InChIKey:JTGMTYWYUZDRBK-UHFFFAOYSA-N
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Compound 61
Molecular Weight:238.2812
Molecular Formula:C16H14O2
InChIKey:PSLFJTHFYQXBSA-UHFFFAOYSA-N
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Compound 62
Molecular Weight:186.01
Molecular Formula:C2F6O3
InChIKey:JGFHBZWYOYWBRG-UHFFFAOYSA-N
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Compound 63
Molecular Weight:236.3499
Molecular Formula:C15H24O2
InChIKey:JYGAZEJXUVDYHI-DGTMBMJNSA-N
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Compound 64
Molecular Weight:268.3487
Molecular Formula:C15H24O4
InChIKey:WCRHLQJCUOBAKM-VUABOHJTSA-N
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Compound 65
Molecular Weight:266.3328
Molecular Formula:C15H22O4
InChIKey:UKXCIQFCSITOCY-VLDCTWHGSA-N
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Compound 66
Molecular Weight:298.3316
Molecular Formula:C15H22O6
InChIKey:ZIXBIPFUJKVHBO-JALVAONISA-N
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Compound 67
Molecular Weight:280.3163
Molecular Formula:C15H20O5
InChIKey:IGEBZMMCKFUABB-KPHNHPKPSA-N
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Compound 68
Molecular Weight:364.4327
Molecular Formula:C20H28O6
InChIKey:QYBOEYZNFHEAHE-IUHOTWCESA-N
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Compound 69
Molecular Weight:236.3068
Molecular Formula:C14H20O3
InChIKey:HEALTGFGXVSAOJ-KDRYVUTISA-N
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Compound 70
Molecular Weight:280.3594
Molecular Formula:C16H24O4
InChIKey:FCCCJMLXLSDJCZ-HLSYRSCKSA-N
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Compound 71
Molecular Weight:232.275
Molecular Formula:C14H16O3
InChIKey:VVRAEGICVWTGJK-RBOJZIDYSA-N
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Compound 72
Molecular Weight:248.3175
Molecular Formula:C15H20O3
InChIKey:CEBGUTYGDPPDGN-RLLAQXBXSA-N
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Compound 74
Molecular Weight:128.1259
Molecular Formula:C6H8O3
InChIKey:HDRUBHQNIALXHQ-UHFFFAOYSA-N
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Compound 73
Molecular Weight:96.1271
Molecular Formula:C6H8O
InChIKey:GSNUFIFRDBKVIE-UHFFFAOYSA-N
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Compound 75
Molecular Weight:160.1678
Molecular Formula:C7H12O4
InChIKey:HLEZYIOUMWDABO-BQBZGAKWSA-N
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Compound 76
Molecular Weight:280.3594
Molecular Formula:C16H24O4
InChIKey:VZINIQPADMOWHP-XEQQAGFISA-N
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Compound 77
Molecular Weight:568.7822
Molecular Formula:C32H56O8
InChIKey:VZCTWFZHGAUQIW-JMVUUIBUSA-N
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Compound 78
Molecular Weight:444.6896
Molecular Formula:C29H48O3
InChIKey:WSVAJLWNDHCMEJ-XPBNMDRNSA-N
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Compound 79
Molecular Weight:654.6162
Molecular Formula:C36H30O12
InChIKey:IEVJARSTOGQGJT-LQFQNGICSA-N
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Compound 80
Molecular Weight:710.7225
Molecular Formula:C40H38O12
InChIKey:QKNQMJLFKVGEEI-XRSDMRJBSA-N
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