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Selective Formation of Allylic Hydroperoxides via Singlet Oxygen ene Reaction

Peroxides (2006)

  1. Michael Orfanopoulos,
  2. Georgios C. Vougioukalakis,
  3. Manolis Stratakis

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0355

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Orfanopoulos, M., Vougioukalakis, G. C. and Stratakis, M. 2009. Selective Formation of Allylic Hydroperoxides via Singlet Oxygen ene Reaction. Patai's Chemistry of Functional Groups. .

Author Information

  1. University of Crete, Department of Chemistry, Iraklion, Greece

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Regioselective Formation of Allylic Hydroperoxides
  • 3
    Diastereoselective Formation of Allylic Hydroperoxides
  • 4
    Selective Formation of Allylic Hydroperoxides by Dye-Sensitized Intrazeolite Photooxygenation
  • 5
    Synthetic Applications
  • 6
    Perspectives
  • 7
    Acknowledgements

Keywords:

  • allylic hydroperoxide regioselective formation;
  • trisubstituted enol ether photooxygenation and transition states;
  • geminal regioselectivity;
  • geminal selectivity in alkene photooxygenation;
  • methyl tiglate photooxygenation reaction;
  • allylic hydroperoxide diastereoselective formation;
  • dye-sensitized intrazeolite photooxygenation;
  • synthetic applications