Standard Article

Transition Metal Peroxides. Synthesis and Role in Oxidation Reactions

Peroxides (2006)

  1. Valeria Conte1,
  2. Olga Bortolini2

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0359

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Conte, V. and Bortolini, O. 2009. Transition Metal Peroxides. Synthesis and Role in Oxidation Reactions . Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    Università di Roma “Tor Vergata”, Dipartimento di Scienze e Tecnologie Chimiche, Roma, Italy

  2. 2

    Università della Calabria, Dipartimento di Chimica, Rende (CS), Italy

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Limitations and Scope
  • 3
    Synthesis and Structural Characterization
  • 4
    Reactivity
  • 5
    Conclusions
  • 6
    Acknowledgments

Keywords:

  • organic and inorganic substrate functionalization;
  • metal catalyzed oxidations with peroxides;
  • transition metal peroxides and peroxo species identification;
  • transition metal substituted polyoxometallates (POM);
  • peroxo metal complex synthesis;
  • transition metal based catalytic species;
  • ketone oxidation;
  • metal-catalyzed oxidation with peroxides

Featured Compounds

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  1. 1 - 120
Compound 1
Molecular Weight:299.254
Molecular Formula:CH5O6Re
InChIKey:CIZQZBNYUOWSQB-UHFFFAOYSA-N
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Compound 2
Molecular Weight:926.79
Molecular Formula:C52H40MoN4O3P2
InChIKey:QPNPOXUGIRDWPM-UHFFFAOYSA-N
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Compound 3
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 4
Molecular Weight:996.759
Molecular Formula:C46H48O4P2Rh2S2
InChIKey:JBMXPVCCZDGEKO-UHFFFAOYSA-L
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Compound 5
Molecular Weight:1495.041
Molecular Formula:C52H44I2Ir2O4P4
InChIKey:XKEHKWMMOGTYMD-UHFFFAOYSA-L
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Compound 6
Molecular Weight:1264.433
Molecular Formula:C68H64Cu2N16O2
InChIKey:RZNXPVQNEIJGSP-UHFFFAOYSA-N
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Compound 7
Molecular Weight:1569
Molecular Formula:C98H87BCuFeN9O3
InChIKey:JFBOPXFGEYRJKK-WPLIICQTSA-M
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Compound 8
Molecular Weight:339.1723
Molecular Formula:C11H14NO8V
InChIKey:RUKDVXRTYSSWHK-UHFFFAOYSA-K
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Compound 9
Molecular Weight:566.289
Molecular Formula:C20H42N2O10Ti2
InChIKey:GBCNMDJWVGWOJG-UHFFFAOYSA-L
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Compound 10
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 11
Molecular Weight:433.427
Molecular Formula:C7H19O9Re
InChIKey:PSCKYLBQOABWKJ-UHFFFAOYSA-N
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Compound 12
Molecular Weight:460.439
Molecular Formula:C7H21N3O6PRe
InChIKey:GVTQNJUTHXYOCW-UHFFFAOYSA-N
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Compound 13
Molecular Weight:268.101
Molecular Formula:C6H8N4O5V
InChIKey:ZSYUXNDJXGZBKG-UHFFFAOYSA-O
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Compound 14
Molecular Weight:435.33
Molecular Formula:C18H15MoO5Si
InChIKey:FFWZKLGSMICHET-UHFFFAOYSA-N
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Compound 15
Molecular Weight:523.23
Molecular Formula:C18H15O5SiW
InChIKey:ATHVESLCSGRIAA-UHFFFAOYSA-N
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Compound 16
Molecular Weight:732.46
Molecular Formula:C24H20Mo2O11Si2
InChIKey:NPXLWOVREXEPKK-UHFFFAOYSA-N
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Compound 17
Molecular Weight:908.26
Molecular Formula:C24H20O11Si2W2
InChIKey:VZRAKWQXOAJHSV-UHFFFAOYSA-N
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Compound 18
Molecular Weight:477.1153
Molecular Formula:C10H12N2NbO14
InChIKey:YNAWJGQFLHEHTP-UHFFFAOYSA-J
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Compound 19
Molecular Weight:1149.784
Molecular Formula:C45H49BF4IrN6O2P2Rh
InChIKey:VKWWZSJOTKXMAB-UHFFFAOYSA-M
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Compound 20
Molecular Weight:585.177
Molecular Formula:C28H37CuN6O4
InChIKey:WEYGBWISSGCRLP-UHFFFAOYSA-M
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Compound 21
Molecular Weight:555.346
Molecular Formula:C17H29BN6O2Pt
InChIKey:YWKPSSVTHRJHKP-UHFFFAOYSA-M
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Compound 22
Molecular Weight:514.91
Molecular Formula:C18H38ClCoN5O6
InChIKey:Not Available
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Compound 23
Molecular Weight:867.22
Molecular Formula:C45H62BN6O2PPd
InChIKey:QUSLNPVNNWBULU-UHFFFAOYSA-M
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Compound 24
Molecular Weight:736.564
Molecular Formula:C33H54BN10O2Rh
InChIKey:PHUHHAKZXDZEIW-UHFFFAOYSA-M
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Compound 25
Molecular Weight:1523.051
Molecular Formula:C53H44I2Ir2O5P4
InChIKey:BBRWQDHTXQEVGR-UHFFFAOYSA-L
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Compound 26
Molecular Weight:1429.266
Molecular Formula:C85H76Fe2N10O5
InChIKey:YXVOGIDPFLDCCZ-UHFFFAOYSA-L
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Compound 27
Molecular Weight:1344.979
Molecular Formula:C70H106B2Fe2N12O6
InChIKey:SNUOYEFEMSTKQE-UHFFFAOYSA-L
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Compound 28
Molecular Weight:1366.066
Molecular Formula:C75H71Fe2N10O5P2
InChIKey:DJXKMHOFQWCCLF-UHFFFAOYSA-N
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Compound 29
Molecular Weight:880.094
Molecular Formula:C38H42ClCo2N6O9
InChIKey:PPIQVQSCIDORFK-UHFFFAOYSA-K
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Compound 31
Molecular Weight:861.6131
Molecular Formula:C38H35Co2N10O7
InChIKey:IIQLVAZYHVXPSB-UHFFFAOYSA-L
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Compound 30
Molecular Weight:815.6082
Molecular Formula:C38H35Co2N9O5
InChIKey:DOMHVNGLCHQKNQ-UHFFFAOYSA-L
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Compound 32
Molecular Weight:1093.938
Molecular Formula:C36H56Cl2Cu4N4O14
InChIKey:FICYDZUDRNXDHR-UHFFFAOYSA-J
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Compound 33
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 34
Molecular Weight:573.502
Molecular Formula:C33H35NO5Ti
InChIKey:ZLQIWYSDVUMXKR-YZYZGRISSA-M
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Compound 76
Molecular Weight:232.321
Molecular Formula:C12H8OS2
InChIKey:NYVGTLXTOJKHJN-UHFFFAOYSA-N
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Compound 35
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 36
Molecular Weight:257.0717
Molecular Formula:C6H8NO7V
InChIKey:YLTIQCYEUSVXAM-UHFFFAOYSA-M
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Compound 37
Molecular Weight:1150.32
Molecular Formula:H3O24PW4
InChIKey:SZGUVCWDYMROCC-UHFFFAOYSA-K
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Compound 38
Molecular Weight:3790.63
Molecular Formula:C63H114N3O40PW12
InChIKey:WMSXDIOSDYATTH-UHFFFAOYSA-K
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Compound 39
Molecular Weight:2735.83
Molecular Formula:C63H114Mo12N3O40P
InChIKey:BDMWIWBQVWGUDU-UHFFFAOYSA-K
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Compound 40
Molecular Weight:2063.92
Molecular Formula:C63H114N3O24PW4
InChIKey:WNMIPENSENYJEN-UHFFFAOYSA-K
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Compound 41
Molecular Weight:249.24
Molecular Formula:CH3O3Re
InChIKey:PQTLALPZRPFYIT-UHFFFAOYSA-N
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Compound 42
Molecular Weight:283.254
Molecular Formula:CH5O5Re
InChIKey:YXWYZDWSWZABLJ-UHFFFAOYSA-N
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Compound 43
Molecular Weight:94.0699
Molecular Formula:CH6N2O3
InChIKey:AQLJVWUFPCUVLO-UHFFFAOYSA-N
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Compound 44
Molecular Weight:265.03
Molecular Formula:C3H7MoNO7
InChIKey:NTDOQXOZSHVFBH-AIDJSRAFSA-N
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Compound 45
Molecular Weight:333.15
Molecular Formula:C8H15MoNO7
InChIKey:FFHFSWMOZKUKNB-HEDVWWMMSA-N
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Compound 46
Molecular Weight:121.1796
Molecular Formula:C8H11N
InChIKey:RQEUFEKYXDPUSK-SSDOTTSWSA-N
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Compound 47
Molecular Weight:426.4694
Molecular Formula:C28H28P2
InChIKey:Not Available
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Compound 48
Molecular Weight:658.7493
Molecular Formula:C44H40N2P2
InChIKey:GCUKRENTSKVSIL-DYDPWSPUSA-N
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Compound 49
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 50
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 51
Molecular Weight:426.7174
Molecular Formula:C30H50O
InChIKey:QYIMSPSDBYKPPY-RSKUXYSASA-N
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Compound 52
Molecular Weight:442.4
Molecular Formula:C18H34MoO6
InChIKey:YNTIUWONYUPLAB-ACOZVLFJSA-N
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Compound 53
Molecular Weight:979.401
Molecular Formula:C37H33BCl2F7NOP2Pt
InChIKey:NFVZKNYHSQLMQN-IIDSZDJSSA-N
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Compound 54
Molecular Weight:179.2588
Molecular Formula:C11H17NO
InChIKey:FMCGSUUBYTWNDP-KOLCDFICSA-N
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Compound 55
Molecular Weight:837.1355
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 56
Molecular Weight:304.72
Molecular Formula:C13H21NO3Zn
InChIKey:RJDQTHAQNFTXGX-SFGLUTOSSA-M
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Compound 57
Molecular Weight:208.2552
Molecular Formula:C15H12O
InChIKey:DQFBYFPFKXHELB-VAWYXSNFSA-N
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Compound 58
Molecular Weight:154.2493
Molecular Formula:C10H18O
InChIKey:GLZPCOQZEFWAFX-JXMROGBWSA-N
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Compound 59
Molecular Weight:100.1589
Molecular Formula:C6H12O
InChIKey:SAOXPNBHKSWHGW-UHFFFAOYSA-N
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Compound 60
Molecular Weight:3921.74
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 61
Molecular Weight:222.3663
Molecular Formula:C15H26O
InChIKey:Not Available
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Compound 62
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 63
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 64
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 65
Molecular Weight:152.2334
Molecular Formula:C10H16O
InChIKey:BAVONGHXFVOKBV-UHFFFAOYSA-N
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Compound 66
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 67
Molecular Weight:261.3593
Molecular Formula:C16H23NO2
InChIKey:WTYUECSGNWPTRO-LRDDRELGSA-N
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Compound 68
Molecular Weight:509.5938
Molecular Formula:C35H27NO3
InChIKey:SSVNVLVJDXLHAY-UHFFFAOYSA-N
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Compound 69
Molecular Weight:592.6824
Molecular Formula:C39H32N2O4
InChIKey:DJOOVHVLVDFEIV-PGUFJCEWSA-N
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Compound 70
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 71
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 72
Molecular Weight:333.4235
Molecular Formula:C22H23NO2
InChIKey:VHDLKHOHZAWXOH-UHFFFAOYSA-N
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Compound 73
Molecular Weight:482.5669
Molecular Formula:C31H30O5
InChIKey:PZQAFTPHLUVABV-VSGBNLITSA-N
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Compound 74
Molecular Weight:96.1702
Molecular Formula:C7H12
InChIKey:CTMHWPIWNRWQEG-UHFFFAOYSA-N
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Compound 75
Molecular Weight:144.1684
Molecular Formula:C7H12O3
InChIKey:Not Available
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Compound 77
Molecular Weight:248.321
Molecular Formula:C12H8O2S2
InChIKey:YAOMBFIYBNUKHD-UHFFFAOYSA-N
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Compound 78
Molecular Weight:248.321
Molecular Formula:C12H8O2S2
InChIKey:CEJYDWOCESGOJP-UHFFFAOYSA-N
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Compound 79
Molecular Weight:248.321
Molecular Formula:C12H8O2S2
InChIKey:CEJYDWOCESGOJP-UHFFFAOYSA-N
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Compound 80
Molecular Weight:182.306
Molecular Formula:C9H10S2
InChIKey:RKBPDPLCHXWHRQ-UHFFFAOYSA-N
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Compound 81
Molecular Weight:198.305
Molecular Formula:C9H10OS2
InChIKey:IWWRMSOVOAHAGD-QHGLUPRGSA-N
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Compound 82
Molecular Weight:198.305
Molecular Formula:C9H10OS2
InChIKey:IWWRMSOVOAHAGD-QHGLUPRGSA-N
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Compound 83
Molecular Weight:432.581
Molecular Formula:C25H28N4OS
InChIKey:POQMHHDKXWTFHB-UHFFFAOYSA-N
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Compound 84
Molecular Weight:345.416
Molecular Formula:C17H19N3O3S
InChIKey:SUBDBMMJDZJVOS-UHFFFAOYSA-N
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Compound 85
Molecular Weight:286.324
Molecular Formula:C20H14O2
InChIKey:PPTXVXKCQZKFBN-UHFFFAOYSA-N
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Compound 86
Molecular Weight:174.2805
Molecular Formula:C10H22O2
InChIKey:AVZDCZIXVMGOQQ-YUMQZZPRSA-N
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Compound 87
Molecular Weight:214.2598
Molecular Formula:C14H14O2
InChIKey:IHPDTPWNFBQHEB-KBPBESRZSA-N
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Compound 88
Molecular Weight:660.322
Molecular Formula:C32H28N4O6Ti2
InChIKey:YGCVVVWGIYBSRS-IGKNZCCUSA-J
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Compound 89
Molecular Weight:376.229
Molecular Formula:C18H20N2O4Ti
InChIKey:LSGVNVDPHZJTTN-MCRPVJKSSA-L
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Compound 90
Molecular Weight:346.16
Molecular Formula:C16H14N2O4Ti
InChIKey:ZWMULJBQAULVKT-SNTCFBDDSA-L
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Compound 91
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 92
Molecular Weight:881.1134
Molecular Formula:C56H60N6O4
InChIKey:SWKRDCRSJPRVNF-OFFPPDKCSA-N
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Compound 93
Molecular Weight:138.1638
Molecular Formula:C8H10O2
InChIKey:GQNOPVSQPBUJKQ-ZETCQYMHSA-N
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Compound 94
Molecular Weight:447.3779
Molecular Formula:C22H24N2O5V
InChIKey:DJXGCJBHQWBGKB-KJKYZMEESA-L
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Compound 95
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 96
Molecular Weight:397.5088
Molecular Formula:C27H27NO2
InChIKey:VYTVJOUAWQZLDL-SWOYFSSUSA-N
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Compound 97
Molecular Weight:455.5464
Molecular Formula:C32H25NO2
InChIKey:XIYOEKABFHQDLF-HYGOAYKSSA-N
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Compound 98
Molecular Weight:473.0885
Molecular Formula:C13H17I2NO2
InChIKey:WVBNUUNXQNMMOB-OHUUDMDPSA-N
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Compound 99
Molecular Weight:543.67
Molecular Formula:O11W2
InChIKey:GUSCKSFRFRRAJH-UHFFFAOYSA-N
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Compound 100
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 101
Molecular Weight:299.05
Molecular Formula:C6H4MoNO7
InChIKey:PHUJXDPEWFHMLD-UHFFFAOYSA-N
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Compound 102
Molecular Weight:540.5
Molecular Formula:C22H40MoN2O7
InChIKey:XAPWMAXJZZZDAY-UHFFFAOYSA-M
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Compound 103
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 104
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 105
Molecular Weight:327.06
Molecular Formula:C7H5MoNO8
InChIKey:ZYNGPXUMTDTIGQ-UHFFFAOYSA-L
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Compound 106
Molecular Weight:834.243
Molecular Formula:C28H26BCl2F7P2Pt
InChIKey:BACBCUWVDXWIRP-UHFFFAOYSA-N
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Compound 107
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 108
Molecular Weight:1450.731
Molecular Formula:C56H58B2F8O2P4Pt2
InChIKey:WXOACORYJNUPBC-UHFFFAOYSA-L
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Compound 109
Molecular Weight:108.1378
Molecular Formula:C7H8O
InChIKey:LNLLHUHPGPKRBM-UHFFFAOYSA-N
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Compound 110
Molecular Weight:152.2334
Molecular Formula:C10H16O
InChIKey:AZOCECCLWFDTAP-UHFFFAOYSA-N
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Compound 111
Molecular Weight:967.888
Molecular Formula:C52H38O3P2Pt
InChIKey:UPQDTZUNGHKHDH-UHFFFAOYSA-M
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Compound 112
Molecular Weight:1843.137
Molecular Formula:C88H66B2F8O2P4Pt2
InChIKey:WKWJYTDACJZPNI-UHFFFAOYSA-L
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Compound 113
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 114
Molecular Weight:124.1803
Molecular Formula:C8H12O
InChIKey:SUIWRIPFUAFDJP-UHFFFAOYSA-N
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Compound 115
Molecular Weight:140.1797
Molecular Formula:C8H12O2
InChIKey:WLYUMBPDHPMKHM-BQBZGAKWSA-N
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Compound 116
Molecular Weight:140.1797
Molecular Formula:C8H12O2
InChIKey:WLYUMBPDHPMKHM-RNFRBKRXSA-N
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Compound 117
Molecular Weight:1102.434
Molecular Formula:C72H54N2O4Zr
InChIKey:FTPAOQCGUGCDMX-AXNCXKPRSA-J
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Compound 120
Molecular Weight:368.2
Molecular Formula:C10H16MoN4O5
InChIKey:MGUYCBZWHWSONL-UHFFFAOYSA-N
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Compound 121
Molecular Weight:172.18
Molecular Formula:C11H8O2
InChIKey:OPKFWRVRCVCMJH-UHFFFAOYSA-N
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Compound 122
Molecular Weight:627.212
Molecular Formula:C22H24Cl2FeN6O8
InChIKey:ZMKAOCBMLSHQJH-UHFFFAOYSA-L
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  1. 1 - 120