Standard Article

Dynamic Behavior of Organozinc Compounds

Organozinc Compounds (2007)

  1. Albert Guijarro

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0369

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Guijarro, A. 2009. Dynamic Behavior of Organozinc Compounds. Patai's Chemistry of Functional Groups. .

Author Information

  1. Universidad de Alicante, Departamento de Química Orgánica, Instituto de Síntesis Orgánica (ISO), Alicante, Spain

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Dynamics of Carbon[BOND]Zinc Bond Exchange: C[BOND]Zn Exchange
  • 3
    Dynamics of Inversion at Carbon Bonded to Zinc: C[BOND]Zn Inversion
  • 4
    Appendix

Keywords:

  • dynamic behavior of organozinc compounds;
  • intermolecular C–Zn exchange;
  • Schlenk equilibrium;
  • metallotropic exchange in organozinc reagents;
  • alkyl–Zn exchange with organometallic compounds;
  • dynamics of inversion at carbon bonded to zinc;
  • inversion at primary alkyl carbon bonded to zinc;
  • vinylic carbon bonded to zinc

Featured Compounds

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  1. 1 - 42
Compound 7
Molecular Weight:219.617
Molecular Formula:C12H10Zn
InChIKey:Not Available
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Compound 3
Molecular Weight:190.956
Molecular Formula:C4H12Zn2
InChIKey:OAOAYJINQCQHRU-UHFFFAOYSA-N
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Compound 4
Molecular Weight:179.638
Molecular Formula:C8H18Zn
InChIKey:YDNAWKQOSYKOSA-UHFFFAOYSA-N
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Compound 5
Molecular Weight:151.584
Molecular Formula:C6H14Zn
InChIKey:KDUNMLRPPVCIGP-UHFFFAOYSA-N
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Compound 6
Molecular Weight:165.611
Molecular Formula:C7H16Zn
InChIKey:TZJGKZXDRVSUSR-UHFFFAOYSA-N
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Compound 8
Molecular Weight:439.234
Molecular Formula:C24H20Zn2
InChIKey:AATDTEGSLCIMFX-UHFFFAOYSA-N
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Compound 9
Molecular Weight:343.148
Molecular Formula:C16H20Zn2
InChIKey:KPKARZWHKVSAGP-UHFFFAOYSA-N
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Compound 11
Molecular Weight:171.574
Molecular Formula:C8H10Zn
InChIKey:FPJRBOLOJPHOMZ-UHFFFAOYSA-N
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Compound 12
Molecular Weight:208.93
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 13
Molecular Weight:571.861
Molecular Formula:C24H45N3Zn3
InChIKey:ZTPDKZRVXHCWSA-UHFFFAOYSA-N
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Compound 14
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 16
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 17
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 18
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 19
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 20
Molecular Weight:175.606
Molecular Formula:C8H14Zn
InChIKey:PXPSZHJVUPMPKY-UHFFFAOYSA-N
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Compound 21
Molecular Weight:175.606
Molecular Formula:C8H14Zn
InChIKey:SRYDABIEWPHLGE-SYWGCQIGSA-N
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Compound 22
Molecular Weight:203.659
Molecular Formula:C10H18Zn
InChIKey:JWWSOFTVCVKDOI-UHFFFAOYSA-N
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Compound 19a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 27
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 28
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 29
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 30
Molecular Weight:203.659
Molecular Formula:C10H18Zn
InChIKey:IFXVFZBJUWAYLY-UHFFFAOYSA-N
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Compound (E)-32
Molecular Weight:284.176
Molecular Formula:C11H23ClN2Zn
InChIKey:CGEPHBJSCXIQNP-WBFLYLAESA-M
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Compound (E)-31
Molecular Weight:315.832
Molecular Formula:C16H30N2Zn
InChIKey:LITOKLQUJMRTLS-KTHMRSEASA-N
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Compound (Z)-31
Molecular Weight:315.832
Molecular Formula:C16H30N2Zn
InChIKey:LITOKLQUJMRTLS-HJVSNYSHSA-N
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Compound (Z)-33a
Molecular Weight:371.938
Molecular Formula:C20H38N2Zn
InChIKey:OBSVDZZMZCUJQC-SVHDLYHKSA-N
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Compound (E)-33a
Molecular Weight:371.938
Molecular Formula:C20H38N2Zn
InChIKey:OBSVDZZMZCUJQC-JRCUNKIOSA-N
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Compound 34a
Molecular Weight:367.906
Molecular Formula:C20H34N2Zn
InChIKey:IUOHTIYIDYSNKA-UHFFFAOYSA-N
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Compound 34b
Molecular Weight:210.598
Molecular Formula:C14H18Mg
InChIKey:MMGJQKKWSFOZIZ-UHFFFAOYSA-N
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Compound (Z)-33b
Molecular Weight:330.834
Molecular Formula:C20H38MgN2
InChIKey:LLCYZZRRFIOTKD-SVHDLYHKSA-N
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Compound (E)-33b
Molecular Weight:330.834
Molecular Formula:C20H38MgN2
InChIKey:LLCYZZRRFIOTKD-JRCUNKIOSA-N
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Compound 36
Molecular Weight:151.393
Molecular Formula:C5H15BZn
InChIKey:BCAXAKPCPDUPBP-UHFFFAOYSA-N
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Compound 44a
Molecular Weight:470.637
Molecular Formula:C15H20INO4Zn
InChIKey:KMSOBZXYEWDASK-IDMXKUIJSA-M
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Compound 44b
Molecular Weight:394.541
Molecular Formula:C9H16INO4Zn
InChIKey:MAXWDGWVXLFOJY-ILKKLZGPSA-M
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Compound (R)-45
Molecular Weight:334.4116
Molecular Formula:C21H22N2O2
InChIKey:JTNVCJCSECAMLD-ROUUACIJSA-N
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Compound (S)-45
Molecular Weight:334.4116
Molecular Formula:C21H22N2O2
InChIKey:Not Available
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Compound 46
Molecular Weight:225.299
Molecular Formula:C15H24LiN
InChIKey:DPBSRJUQZJNNCC-RSAXXLAASA-N
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Compound syn-47
Molecular Weight:363.671
Molecular Formula:C15H24BrNZn
InChIKey:QFSWMQHPWHIXOV-CKUXDGONSA-M
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Compound anti-47
Molecular Weight:363.671
Molecular Formula:C15H24BrNZn
InChIKey:QFSWMQHPWHIXOV-CKUXDGONSA-M
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Compound (R)-48
Molecular Weight:298.63
Molecular Formula:C9H17BrSiZn
InChIKey:ASLOJVMUGJXRIY-UHFFFAOYSA-M
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Compound (S)-48
Molecular Weight:298.63
Molecular Formula:C9H17BrSiZn
InChIKey:ASLOJVMUGJXRIY-UHFFFAOYSA-M
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  1. 1 - 42