Standard Article

Cyclopropanation Mediated by Zinc Organometallics

Organozinc Compounds (2007)

  1. André B. Charette

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0370

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Charette, A. B. 2009. Cyclopropanation Mediated by Zinc Organometallics. Patai's Chemistry of Functional Groups. .

Author Information

  1. Université de Montréal, Department of Chemistry, Montréal, Québec, Canada

Publication History

  1. Published Online: 15 DEC 2009

Chemistry Terms

Choose one or more boxes to highlight terms.

Abstract

  • 1
    Introduction
  • 2
    Preparation and Structure of Zinc Carbenoids
  • 3
    Mechanism of the Cyclopropanation of Alkenes using Zinc Carbenoids
  • 4
    Synthetic Scope of the Cyclopropanation using Zinc Carbenoids
  • 5
    Conclusion

Keywords:

  • cyclopropanation mediated by zinc organometallics;
  • zinc carbenoids;
  • α-substituted zinc carbenoids;
  • functionalized zinc carbenoids;
  • cyclopropanating reagents;
  • cyclopropanation using zinc carbenoids;
  • cyclopropanation of alkenes and chemoselectivities;
  • chiral auxiliary-based approach

Featured Compounds

VIEW

  1. 1 - 26
Compound 1
Molecular Weight:545.573
Molecular Formula:C14H26I2O2Zn
InChIKey:SXMAUMVIFGVOOB-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 2
Molecular Weight:611.586
Molecular Formula:C14H28I2O6Zn
InChIKey:YDYKCSOEINQHKK-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 3
Molecular Weight:645.603
Molecular Formula:C17H26I2O6Zn
InChIKey:VCYPLQVFHVIAOH-UHFFFAOYSA-M
View compound in article | Full details | Search for this compound
Compound 4
Molecular Weight:605.588
Molecular Formula:C20H18I2N2Zn
InChIKey:BGGBPAOPDCOSSJ-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 5
Molecular Weight:422.685
Molecular Formula:C20H18Cl2N2Zn
InChIKey:RABJJQIGWOJCNB-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 6
Molecular Weight:1055.25
Molecular Formula:C34H40I2O10P2Zn2
InChIKey:PDEKARQTKQWSKU-UHFFFAOYSA-L
View compound in article | Full details | Search for this compound
Compound 7
Molecular Weight:1373.984
Molecular Formula:C36H44I4O8Zn4
InChIKey:YMBMXRCLZBDTFX-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 8
Molecular Weight:1008.178
Molecular Formula:C36H44Cl4O8Zn4
InChIKey:MEJNMEJKYIDJNY-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 10
Molecular Weight:335.689
Molecular Formula:C16H14O4Zn
InChIKey:YNEOFZAQYHJROM-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 12
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 13
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 11
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 14
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 15
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 16
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 17
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 18
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 19
Molecular Weight:270.133
Molecular Formula:C12H23BN2O4
InChIKey:AFQWQRBBIZKYTE-NXEZZACHSA-N
View compound in article | Full details | Search for this compound
Compound ent-19
Molecular Weight:270.133
Molecular Formula:C12H23BN2O4
InChIKey:AFQWQRBBIZKYTE-UWVGGRQHSA-N
View compound in article | Full details | Search for this compound
Compound 20
Molecular Weight:484.5861
Molecular Formula:C30H32N2O4
InChIKey:JGSMEYWVBKDWJN-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 21
Molecular Weight:260.2836
Molecular Formula:C12H20O6
InChIKey:NFHXOQDPQIQPKT-XBWDGYHZSA-N
View compound in article | Full details | Search for this compound
Compound 22
Molecular Weight:328.4039
Molecular Formula:C16H28N2O5
InChIKey:KTUXEQMESTZEQT-RYUDHWBXSA-N
View compound in article | Full details | Search for this compound
Compound 23
Molecular Weight:752.7898
Molecular Formula:C52H33O4P
InChIKey:FRXFYAVXIXQHHE-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 24
Molecular Weight:484.503
Molecular Formula:C18H20N4O8S2
InChIKey:AHFPEDLBFJTANO-QZTJIDSGSA-N
View compound in article | Full details | Search for this compound
Compound 25
Molecular Weight:270.37
Molecular Formula:C8H18N2O4S2
InChIKey:JUWLQVLCYRNWSV-HTQZYQBOSA-N
View compound in article | Full details | Search for this compound
Compound 26
Molecular Weight:630.593
Molecular Formula:C37H42O6Ti
InChIKey:ASACUCBAGWQAFH-CRMRIEQBSA-N
View compound in article | Full details | Search for this compound

VIEW

  1. 1 - 26