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1,1-Bismetallated Species

Organozinc Compounds (2007)

  1. Seijiro Matsubara

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0377

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Matsubara, S. 2009. 1,1-Bismetallated Species. Patai's Chemistry of Functional Groups. .

Author Information

  1. Kyoto University, Department of Material Chemistry, Graduate School of Engineering, Nishikyo, Kyoto, Japan

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Preparation of sp3-Geminated Organodizinc Reagents
  • 3
    Reaction of sp3-Geminated Organodizinc Reagents
  • 4
    Preparation and Reaction of sp2-Geminated Organodizinc Reagents
  • 5
    Conclusion

Keywords:

  • 1,1-bismetallated species;
  • zinca-ene-allene and zinc-enolate cyclizations;
  • alkylidenation;
  • sequential reaction with two electrophiles;
  • nucleophilic cyclopropanation;
  • bis(iodozincio)methane;
  • nucleophilic cyclopropanation;
  • gem-Dizincio reagent working as carbenoid