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Carbozincation of Alkenes and Alkynes

Organozinc Compounds (2007)

  1. Edwige Lorthiois1,
  2. Christophe Meyer2

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0382

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Lorthiois, E. and Meyer, C. 2009. Carbozincation of Alkenes and Alkynes. Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    Novartis Pharma AG, Novartis Institutes for Biomedical Research, Protease Platform WKL-122-3-27, Basel, Switzerland

  2. 2

    associé au CNRS, ESPCI, Laboratoire de Chimie Organique, Paris Cedex 05, France

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Reactivity of Alkyl and Aryl Organozinc Reagents
  • 3
    Reactivity of Allylic Organozinc Reagents
  • 4
    Reactivity of Allenylzinc Reagents
  • 5
    Reactivity of Zinc Enolates and Aza-Enolates
  • 6
    Conclusion

Keywords:

  • carbozincation of alkenes and alkynes;
  • intermolecular additions to alkynes;
  • uncatalyzed intramolecular carbozincations;
  • intramolecular carbozincation of alkenes;
  • transition metal-catalyzed or promoted carbozincations;
  • zirconium-promoted carbozincations;
  • allylzincation of alkenylmetals;
  • allenylzinc reagent reactivity