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Proton Sponges

Anilines (2007)

  1. Alexander F. Pozharskii,
  2. Valery A. Ozeryanskii

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0399

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Pozharskii, A. F. and Ozeryanskii, V. A. 2009. Proton Sponges. Patai's Chemistry of Functional Groups. .

Author Information

  1. Rostov State University, Department of Organic Chemistry, Rostov-on-Don, Russian Federation

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Synthesis of Proton Sponges
  • 3
    Physicochemical Properties
  • 4
    Reactivity
  • 5
    Application of Proton Sponges
  • 6
    Conclusion
  • 7
    Acknowledgement

Keywords:

  • proton sponge synthesis;
  • neutral organic bases and lowered proton addition–elimination rates;
  • proton sponge molecular structure analysis and high basicity and unusual reactivity;
  • dimethylamino group conformations in naphthalene proton sponges;
  • ‘proton localization index’ (PL);
  • NMR spectra and molecular dynamics;
  • electron-donating and electron-accepting properties;
  • quantum-chemical calculations