Standard Article

Formation, Chemistry and Structure of Organomagnesium Species in Solvent-Free Environments

Organomagnesium Compounds (2008)

  1. Richard A. J. O'Hair

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0403

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

A. J. O'Hair, R. 2009. Formation, Chemistry and Structure of Organomagnesium Species in Solvent-Free Environments. Patai's Chemistry of Functional Groups. .

Author Information

  1. The University of Melbourne, School of Chemistry, Bio21 Molecular Science and Biotechnology Institute, ARC Centre of Excellence in Free Radical Chemistry and Biotechnology, Victoria, Australia

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Formation of Organomagnesium Species in Solvent-Free Environments
  • 3
    Bimolecular Reactions of Organomagnesium Ions in the Gas Phase
  • 4
    Unimolecular Reactions of Organomagnesium Ions in the Gas Phase
  • 5
    Structures of Organomagnesiums and Magnesium Halides in the Gas Phase
  • 6
    Concluding Remarks
  • 7
    Acknowledgments

Keywords:

  • organomagnesium species in solvent-free environments;
  • ‘The Chemistry of Functional Groups’ series;
  • matrix assisted laser desorption ionization (MALDI) and organomagnesium compound analysis;
  • magnesium atom reaction and matrix isolation techniques;
  • long-lived vibrationally excited [RMgH] complexes;
  • selected ion flow tube technique (SIFT);
  • magnesium surface and film reactions with organic substrates;
  • bimolecular reactivity of organomagnesium species in gas phase

Featured Compounds

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  1. 1 - 54
Compound 41
Molecular Weight:119.244
Molecular Formula:CH3BrMg
InChIKey:AVFUHBJCUUTGCD-UHFFFAOYSA-M
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Compound 1
Molecular Weight:80.411
Molecular Formula:C4H8Mg
InChIKey:PKGCBDAVXAJDFC-UHFFFAOYSA-N
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Compound 2
Molecular Weight:96.368
Molecular Formula:C3H4MgO2
InChIKey:QCQOAPFIZWIOPS-UHFFFAOYSA-M
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Compound 4
Molecular Weight:228.491
Molecular Formula:C12H4MgN4
InChIKey:GFACUECDKSJCAZ-UHFFFAOYSA-N
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Compound 3
Molecular Weight:228.491
Molecular Formula:C12H4MgN4
InChIKey:QUSHSWUKPWDWCV-UHFFFAOYSA-N
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Compound 74
Molecular Weight:95.211
Molecular Formula:Cl2Mg
InChIKey:TWRXJAOTZQYOKJ-UHFFFAOYSA-L
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Compound 5a
Molecular Weight:114.0928
Molecular Formula:C6H4F2
InChIKey:GOYDNIKZWGIXJT-UHFFFAOYSA-N
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Compound 5b
Molecular Weight:114.0928
Molecular Formula:C6H4F2
InChIKey:UEMGWPRHOOEKTA-UHFFFAOYSA-N
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Compound 5c
Molecular Weight:114.0928
Molecular Formula:C6H4F2
InChIKey:QUGUFLJIAFISSW-UHFFFAOYSA-N
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Compound 6
Molecular Weight:132.0832
Molecular Formula:C6H3F3
InChIKey:PEBWOGPSYUIOBP-UHFFFAOYSA-N
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Compound 7
Molecular Weight:150.0737
Molecular Formula:C6H2F4
InChIKey:SDXUIOOHCIQXRP-UHFFFAOYSA-N
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Compound 8
Molecular Weight:168.0642
Molecular Formula:C6HF5
InChIKey:WACNXHCZHTVBJM-UHFFFAOYSA-N
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Compound 9
Molecular Weight:186.0546
Molecular Formula:C6F6
InChIKey:ZQBFAOFFOQMSGJ-UHFFFAOYSA-N
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Compound 5
Molecular Weight:130.1352
Molecular Formula:C7H8F2
InChIKey:VKVBHUYYGFTYDR-UHFFFAOYSA-N
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Compound 10
Molecular Weight:97.0904
Molecular Formula:C5H4FN
InChIKey:MTAODLNXWYIKSO-UHFFFAOYSA-N
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Compound 11
Molecular Weight:115.0808
Molecular Formula:C5H3F2N
InChIKey:MBTGBRYMJKYYOE-UHFFFAOYSA-N
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Compound 12
Molecular Weight:169.0522
Molecular Formula:C5F5N
InChIKey:XTGOWLIKIQLYRG-UHFFFAOYSA-N
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Compound 17
Molecular Weight:124.344
Molecular Formula:C2H3F3MgO
InChIKey:WUUFKNOGSRUJQE-UHFFFAOYSA-N
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Compound 21
Molecular Weight:88.1051
Molecular Formula:C4H8O2
InChIKey:Not Available
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Compound 22
Molecular Weight:88.1051
Molecular Formula:C4H8O2
InChIKey:RYHBNJHYFVUHQT-UHFFFAOYSA-N
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Compound 29
Molecular Weight:135.406
Molecular Formula:C4H5MgN3O
InChIKey:DRTXPOVJFFXGBQ-UHFFFAOYSA-N
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Compound 30
Molecular Weight:135.406
Molecular Formula:C4H5MgN3O
InChIKey:DRTXPOVJFFXGBQ-UHFFFAOYSA-N
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Compound 31
Molecular Weight:135.406
Molecular Formula:C4H5MgN3O
InChIKey:DRTXPOVJFFXGBQ-UHFFFAOYSA-N
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Compound 32
Molecular Weight:69.0847
Molecular Formula:C3H4N2
InChIKey:RORTUEWWZUJHTM-OWOJBTEDSA-O
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Compound 33
Molecular Weight:66.344
Molecular Formula:CH2MgN2
InChIKey:QGDUNIOAYJZJHY-UHFFFAOYSA-N
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Compound 35
Molecular Weight:92.382
Molecular Formula:C3H4MgN2
InChIKey:BJQNRXHYTIINPM-SEPHDYHBSA-N
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Compound 37
Molecular Weight:147.708
Molecular Formula:CH3ClMg4
InChIKey:DBILUJZRWAITMY-UHFFFAOYSA-M
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Compound 39
Molecular Weight:147.708
Molecular Formula:CH3ClMg4
InChIKey:DBILUJZRWAITMY-UHFFFAOYSA-M
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Compound 42
Molecular Weight:128.514
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 45
Molecular Weight:74.931
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 51
Molecular Weight:82.364
Molecular Formula:C2H4MgNO
InChIKey:CTOZIMNCGWEEPB-UHFFFAOYSA-M
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Compound 48
Molecular Weight:141.431
Molecular Formula:C4H9MgN2O2
InChIKey:MJPIGGWUHQJHAO-UHFFFAOYSA-M
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Compound 49
Molecular Weight:141.431
Molecular Formula:C4H9MgN2O2
InChIKey:MJPIGGWUHQJHAO-UHFFFAOYSA-M
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Compound 50
Molecular Weight:141.431
Molecular Formula:C4H9MgN2O2
InChIKey:IDMMJTMKHAYEML-UHFFFAOYSA-M
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Compound 53
Molecular Weight:82.364
Molecular Formula:C2H3MgNO
InChIKey:WTWUGANRRXLFPO-UHFFFAOYSA-N
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Compound 55
Molecular Weight:82.364
Molecular Formula:C2H4MgNO
InChIKey:WTWUGANRRXLFPO-UHFFFAOYSA-N
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Compound 56
Molecular Weight:217.522
Molecular Formula:C8H17MgO5
InChIKey:MCLXWNQTYFWABJ-UHFFFAOYSA-M
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Compound 57
Molecular Weight:199.507
Molecular Formula:C8H15MgO4
InChIKey:SZTXETOLMXVSED-UHFFFAOYSA-N
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Compound 58
Molecular Weight:155.454
Molecular Formula:C6H11MgO3
InChIKey:JALALUJTDAUHNP-UHFFFAOYSA-N
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Compound 59
Molecular Weight:201.438
Molecular Formula:C6H9MgO6
InChIKey:HHNJQTAVFGQHBP-UHFFFAOYSA-K
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Compound 61
Molecular Weight:157.428
Molecular Formula:C5H9MgO4
InChIKey:FEEMUJBRUSKFFP-UHFFFAOYSA-L
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Compound 63
Molecular Weight:110.246
Molecular Formula:CH3Cl2Mg
InChIKey:ZQEHLHHYJSHLRV-UHFFFAOYSA-L
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Compound 62
Molecular Weight:154.256
Molecular Formula:C2H3Cl2MgO2
InChIKey:QMSNCRYLZUJWAR-UHFFFAOYSA-K
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Compound 69a
Molecular Weight:156.508
Molecular Formula:C10H13Mg
InChIKey:APXWSPPOUFFBCH-UHFFFAOYSA-N
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Compound 69b
Molecular Weight:156.508
Molecular Formula:C10H13Mg
InChIKey:APXWSPPOUFFBCH-UHFFFAOYSA-N
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Compound 68
Molecular Weight:170.004
Molecular Formula:CH3Cl3Mg2
InChIKey:NPBIJPORIQUVAF-UHFFFAOYSA-K
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Compound 71
Molecular Weight:166.587
Molecular Formula:C10H22Mg
InChIKey:KKDGTKOIUZRRRB-UHFFFAOYSA-N
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Compound 73
Molecular Weight:62.302
Molecular Formula:F2Mg
InChIKey:ORUIBWPALBXDOA-UHFFFAOYSA-L
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Compound 75
Molecular Weight:184.113
Molecular Formula:Br2Mg
InChIKey:Not Available
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Compound 76
Molecular Weight:278.114
Molecular Formula:I2Mg
InChIKey:BLQJIBCZHWBKSL-UHFFFAOYSA-L
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Compound 70
Molecular Weight:296.774
Molecular Formula:C20H33Mg
InChIKey:ZQZHAUNQSUKUKJ-UHFFFAOYSA-N
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Compound 72
Molecular Weight:160.539
Molecular Formula:C10H16Mg
InChIKey:ZOHJRAGRRCDPQS-UHFFFAOYSA-N
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Compound 77
Molecular Weight:190.422
Molecular Formula:Cl4Mg2
InChIKey:OJJLEPPNZOMRPF-UHFFFAOYSA-J
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Compound 78
Molecular Weight:368.226
Molecular Formula:Br4Mg2
InChIKey:VVSUWBLWFYUYMY-UHFFFAOYSA-J
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