Standard Article

Analytical Aspects of Organomagnesium Compounds

Organomagnesium Compounds (2008)

  1. Jacob Zabicky

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0406

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Zabicky, J. 2009. Analytical Aspects of Organomagnesium Compounds. Patai's Chemistry of Functional Groups. .

Author Information

  1. Ben-Gurion University of the Negev, Department of Chemical Engineering, Beer-Sheva, Israel

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction and Scope of the Chapter
  • 2
    Elemental Analysis of Magnesium
  • 3
    Speciation Analysis of Organomagnesium Compounds
  • 4
    Grignard Reagents as Analytical Reagents and AIDS

Keywords:

  • elemental analysis in organic analysis;
  • Mg speciation in complex matrices;
  • artificial neural network (ANN) methodology;
  • dry ashing and low temperature ashing (LTA);
  • wet mineralization in organic matter elimination in matrix;
  • column separation methods;
  • stable and long-lived radioisotopes - MS quantitation techniques;
  • silanol group concentration and Grignard titration method

Featured Compounds

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  1. 1 - 116
Compound 1
Molecular Weight:614.731
Molecular Formula:C20H48Cl4Cr2MgN4
InChIKey:LWBHHXGCEKRMHW-UHFFFAOYSA-J
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Compound 2
Molecular Weight:735.218
Molecular Formula:C26H56Cl5Mg4N2O4
InChIKey:TWBCKNDTCHLMRY-UHFFFAOYSA-I
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Compound 3a
Molecular Weight:312.517
Molecular Formula:C10H12MgN2O8
InChIKey:KOLOHTSFJKVHEP-UHFFFAOYSA-J
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Compound 3b
Molecular Weight:328.29
Molecular Formula:C10H12CaN2O8
InChIKey:NVTRPRFAWJGJAJ-UHFFFAOYSA-J
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Compound 4a
Molecular Weight:366.607
Molecular Formula:C14H18MgN2O8
InChIKey:AQTKKWVMSCWETQ-DHTOPLTISA-J
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Compound 4b
Molecular Weight:382.38
Molecular Formula:C14H18CaN2O8
InChIKey:GBAXQXOTJLFUTE-DHTOPLTISA-J
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Compound 5
Molecular Weight:145.158
Molecular Formula:C9H7NO
InChIKey:Not Available
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Compound 6
Molecular Weight:213.252
Molecular Formula:C6H15NO5S
InChIKey:AJTVSSFTXWNIRG-UHFFFAOYSA-N
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Compound 7
Molecular Weight:68.0773
Molecular Formula:C3H4N2
InChIKey:RAXXELZNTBOGNW-UHFFFAOYSA-N
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Compound 8
Molecular Weight:90.0349
Molecular Formula:C2H2O4
InChIKey:MUBZPKHOEPUJKR-UHFFFAOYSA-N
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Compound 9
Molecular Weight:113.1179
Molecular Formula:C4H7N3O
InChIKey:Not Available
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Compound 10
Molecular Weight:150.0868
Molecular Formula:C4H6O6
InChIKey:FEWJPZIEWOKRBE-UHFFFAOYSA-N
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Compound 11a
Molecular Weight:538.8059
Molecular Formula:C30H58N4O4
InChIKey:YDEBJEQEXQRSCQ-UHFFFAOYSA-N
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Compound 11b
Molecular Weight:538.8059
Molecular Formula:C30H58N4O4
InChIKey:MXMJPDBVBJZBCA-UHFFFAOYSA-N
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Compound 12
Molecular Weight:863.3073
Molecular Formula:C49H94N6O6
InChIKey:JYBGTBZZVHYIJI-UHFFFAOYSA-N
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Compound 13
Molecular Weight:925.3766
Molecular Formula:C54H96N6O6
InChIKey:BGUIEMNKZGDHPN-UHFFFAOYSA-N
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Compound 14
Molecular Weight:236.266
Molecular Formula:C9H13N2NaO2S
InChIKey:XHYIXOLPLIWNRV-UHFFFAOYSA-M
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Compound 15
Molecular Weight:576.166
Molecular Formula:C19H12Br2O9S
InChIKey:YJCROBBLFUDXCG-UHFFFAOYSA-N
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Compound 16
Molecular Weight:270.2073
Molecular Formula:C12H9F3N2O2
InChIKey:XJJDGTPFEFAAMV-UHFFFAOYSA-N
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Compound 17
Molecular Weight:256.2103
Molecular Formula:C14H8O5
InChIKey:BBNQQADTFFCFGB-UHFFFAOYSA-N
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Compound 18
Molecular Weight:272.2097
Molecular Formula:C14H8O6
InChIKey:VBHKTXLEJZIDJF-UHFFFAOYSA-N
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Compound 19
Molecular Weight:380.3478
Molecular Formula:C14H24N2O10
InChIKey:DEFVIWRASFVYLL-UHFFFAOYSA-N
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Compound 20
Molecular Weight:346.3759
Molecular Formula:C22H18O4
InChIKey:CPBJMKMKNCRKQB-UHFFFAOYSA-N
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Compound 21
Molecular Weight:180.2053
Molecular Formula:C12H8N2
InChIKey:DGEZNRSVGBDHLK-UHFFFAOYSA-N
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Compound 22
Molecular Weight:636.6027
Molecular Formula:C32H32N2O12
InChIKey:IYZPEGVSBUNMBE-UHFFFAOYSA-N
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Compound 23
Molecular Weight:698.014
Molecular Formula:C21H14Br4O5S
InChIKey:FRPHFZCDPYBUAU-UHFFFAOYSA-N
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Compound 24
Molecular Weight:756.816
Molecular Formula:C37H44N2O13S
InChIKey:KIHCHVIVBXSLBU-UHFFFAOYSA-N
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Compound 25
Molecular Weight:513.412
Molecular Formula:C17H11N3O12S2
InChIKey:DWLDDHHNGAKDDJ-VHEBQXMUSA-N
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Compound 26
Molecular Weight:520.468
Molecular Formula:C16H12N2O12S3
InChIKey:JNYDSMCAWGHHAA-ISLYRVAYSA-N
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Compound 27
Molecular Weight:342.369
Molecular Formula:C17H14N2O4S
InChIKey:NPGCBUXAXAUGTF-VHEBQXMUSA-N
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Compound 28
Molecular Weight:419.05
Molecular Formula:C14H7Cl4N5O2
InChIKey:JIVDOFLPGFPRRU-OXYYMIMUSA-N
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Compound 29
Molecular Weight:476.4334
Molecular Formula:C22H24N2O10
InChIKey:FTEDXVNDVHYDQW-UHFFFAOYSA-N
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Compound 30
Molecular Weight:411.4525
Molecular Formula:C25H21N3O3
InChIKey:JSSROCUNTZVPCI-BYYHNAKLSA-N
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Compound 31
Molecular Weight:233.286
Molecular Formula:C12H11NO2S
InChIKey:ZUYVNBCUHLGDGV-UHFFFAOYSA-N
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Compound 32a
Molecular Weight:304.2979
Molecular Formula:C15H16N2O5
InChIKey:XJAPXUFBLWEPNK-UHFFFAOYSA-N
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Compound 32b
Molecular Weight:290.2714
Molecular Formula:C14H14N2O5
InChIKey:LHVKYAAAILOYFM-UHFFFAOYSA-N
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Compound 33a
Molecular Weight:725.439
Molecular Formula:C33H22Cl2N2O13
InChIKey:UMJJHLJWFYINGG-UHFFFAOYSA-N
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Compound 33b
Molecular Weight:710.6861
Molecular Formula:C37H34N4O11
InChIKey:RVRLFKFIFCFFJP-UHFFFAOYSA-N
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Compound 34a
Molecular Weight:722.5612
Molecular Formula:C30H30N2O19
InChIKey:PCDUVTXECKTHBH-UHFFFAOYSA-N
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Compound 34b
Molecular Weight:448.3371
Molecular Formula:C19H16N2O11
InChIKey:JVTZHGYZHLYCOO-UHFFFAOYSA-N
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Compound 35
Molecular Weight:398.3661
Molecular Formula:C20H18N2O7
InChIKey:DBGQURHGEJPPBW-UHFFFAOYSA-N
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Compound 36
Molecular Weight:449.391
Molecular Formula:C18H15N3O9S
InChIKey:SQCNLQVEXMAQAO-UHFFFAOYSA-N
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Compound 37
Molecular Weight:225.221
Molecular Formula:C9H7NO4S
InChIKey:LGDFHDKSYGVKDC-UHFFFAOYSA-N
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Compound 38
Molecular Weight:348.05
Molecular Formula:C21H46ClN
InChIKey:VBIIFPGSPJYLRR-UHFFFAOYSA-M
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Compound 39
Molecular Weight:355.3893
Molecular Formula:C22H17N3O2
InChIKey:BAIMADHJRKDQIX-RNIAWFEPSA-N
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Compound 40a
Molecular Weight:285.2946
Molecular Formula:C16H15NO4
InChIKey:Not Available
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Compound 40b
Molecular Weight:357.3573
Molecular Formula:C19H19NO6
InChIKey:PHFHFZDHYYOHJM-UHFFFAOYSA-N
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Compound 40c
Molecular Weight:413.4636
Molecular Formula:C23H27NO6
InChIKey:WYULISBOVWVSDX-UHFFFAOYSA-N
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Compound 41
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 42a
Molecular Weight:154.186
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 42b
Molecular Weight:224.319
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 43a
Molecular Weight:154.186
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 43b
Molecular Weight:224.319
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 44
Molecular Weight:172.2661
Molecular Formula:C6H13NaO2Si
InChIKey:Not Available
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Compound 45
Molecular Weight:503.1493
Molecular Formula:C10H16N5O13P3
InChIKey:ZKHQWZAMYRWXGA-KQYNXXCUSA-J
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Compound 46
Molecular Weight:256.3013
Molecular Formula:C18H12N2
InChIKey:WPTCSQBWLUUYDV-UHFFFAOYSA-N
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Compound 47a
Molecular Weight:260.2867
Molecular Formula:C18H12O2
InChIKey:Not Available
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Compound 47b
Molecular Weight:232.2766
Molecular Formula:C17H12O
InChIKey:NGDMLQSGYUCLDC-UHFFFAOYSA-N
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Compound 48
Molecular Weight:180.2451
Molecular Formula:C14H12
InChIKey:ZVEJRZRAUYJYCO-UHFFFAOYSA-N
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Compound 49
Molecular Weight:219.2811
Molecular Formula:C16H13N
InChIKey:XQVWYOYUZDUNRW-UHFFFAOYSA-N
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Compound 50
Molecular Weight:273.3318
Molecular Formula:C18H15N3
InChIKey:VXLFYNFOITWQPM-UHFFFAOYSA-N
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Compound 51
Molecular Weight:409.4
Molecular Formula:C12H10Te2
InChIKey:VRLFOXMNTSYGMX-UHFFFAOYSA-N
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Compound 52
Molecular Weight:212.2472
Molecular Formula:C13H12N2O
InChIKey:SERARPRVBWDEBA-GXDHUFHOSA-N
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Compound 53
Molecular Weight:212.2472
Molecular Formula:C13H12N2O
InChIKey:SERARPRVBWDEBA-GXDHUFHOSA-N
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Compound 54
Molecular Weight:212.2472
Molecular Formula:C13H12N2O
InChIKey:SERARPRVBWDEBA-GXDHUFHOSA-N
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Compound 55
Molecular Weight:242.339
Molecular Formula:C14H14N2S
InChIKey:MRCQXBFPTAPZEA-UHFFFAOYSA-N
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Compound 56
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 57
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 58
Molecular Weight:219.004
Molecular Formula:C9H19ClMgO2
InChIKey:VXPSATCOXXYCOI-UHFFFAOYSA-M
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Compound 59a
Molecular Weight:182.2179
Molecular Formula:C13H10O
InChIKey:RWCCWEUUXYIKHB-UHFFFAOYSA-N
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Compound 59b
Molecular Weight:120.1485
Molecular Formula:C8H8O
InChIKey:KWOLFJPFCHCOCG-UHFFFAOYSA-N
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Compound 61
Molecular Weight:234.2925
Molecular Formula:C17H14O
InChIKey:YVEWEFYDUGFSKQ-UHFFFAOYSA-N
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Compound 60
Molecular Weight:206.2393
Molecular Formula:C15H10O
InChIKey:YMNKUHIVVMFOFO-UHFFFAOYSA-N
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Compound 72
Molecular Weight:131.254
Molecular Formula:C2H3BrMg
InChIKey:XHHHAXOHMKAOSL-UHFFFAOYSA-M
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Compound 62
Molecular Weight:740.903
Molecular Formula:C36H28MgO16
InChIKey:WGNAOUKKQARTQS-YFIGGHQTSA-L
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Compound 63
Molecular Weight:538.4564
Molecular Formula:C27H22O12
InChIKey:UJZQBMQZMKFSRV-RGKBJLTCSA-N
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Compound 64
Molecular Weight:360.3148
Molecular Formula:C18H16O8
InChIKey:DOUMFZQKYFQNTF-GIZXNFQBSA-N
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Compound 65
Molecular Weight:484.4521
Molecular Formula:C25H24O10
InChIKey:VLGROHBNWZUINI-JRQVOLNWSA-N
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Compound 66
Molecular Weight:268.3535
Molecular Formula:C17H20N2O
InChIKey:Not Available
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Compound 67
Molecular Weight:67.0892
Molecular Formula:C4H5N
InChIKey:KAESVJOAVNADME-UHFFFAOYSA-N
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Compound 68
Molecular Weight:85.1475
Molecular Formula:C5H11N
InChIKey:Not Available
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Compound 69
Molecular Weight:110.1968
Molecular Formula:C8H14
InChIKey:URYYVOIYTNXXBN-UPHRSURJSA-N
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Compound 70
Molecular Weight:108.1809
Molecular Formula:C8H12
InChIKey:Not Available
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Compound 71
Molecular Weight:100.83
Molecular Formula:C3H5ClMg
InChIKey:Not Available
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Compound 73
Molecular Weight:567.617
Molecular Formula:C28H66Mg2N2O2Si2
InChIKey:LBHXURLLSRLSJD-UHFFFAOYSA-N
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Compound 74
Molecular Weight:355.094
Molecular Formula:C20H35Mg2O2
InChIKey:QVECVVPZIDMBDU-UHFFFAOYSA-N
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Compound 75a
Molecular Weight:758.064
Molecular Formula:C52H36Mg4
InChIKey:YJOIBWCWFDUGAZ-UHFFFAOYSA-N
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Compound 75b
Molecular Weight:1189.74
Molecular Formula:C68H52Fe4Mg4
InChIKey:XZCFVSWHVPXZSR-UHFFFAOYSA-N
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Compound 76
Molecular Weight:523.244
Molecular Formula:C34H34Mg2O2
InChIKey:YFBDNFBSCRHURM-UHFFFAOYSA-N
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Compound 75
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 77
Molecular Weight:757.839
Molecular Formula:C36H70Mg2O2P2Si4
InChIKey:WOJICMLBRWLBCA-UHFFFAOYSA-N
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Compound 78
Molecular Weight:619.306
Molecular Formula:C28H52MgO2P2Si4
InChIKey:ILCCMVACNFFZKB-UHFFFAOYSA-N
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Compound 79
Molecular Weight:321.805
Molecular Formula:C14H26MgOPSi2
InChIKey:GQSLLMSFRUHZDQ-UHFFFAOYSA-N
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Compound 80
Molecular Weight:312.5349
Molecular Formula:C15H29OPSi2
InChIKey:LUYGDZCUYXLQIQ-UHFFFAOYSA-N
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Compound 81
Molecular Weight:496.073
Molecular Formula:C17H43BrMgO2Si4
InChIKey:RQLMOQVQLXZAIW-UHFFFAOYSA-M
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Compound 82
Molecular Weight:663.822
Molecular Formula:C26H70MgO2Si8
InChIKey:KZPSUXVKGIIMNW-UHFFFAOYSA-N
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Compound 85
Molecular Weight:156.916
Molecular Formula:C5H5ClMgS
InChIKey:XCOYZWQZZZBROF-UHFFFAOYSA-M
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Compound 83
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 86
Molecular Weight:277.067
Molecular Formula:C16H36Mg2
InChIKey:VOJOPWYMESDYAR-UHFFFAOYSA-N
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Compound 87a
Molecular Weight:152.1473
Molecular Formula:C8H8O3
InChIKey:MWOOGOJBHIARFG-UHFFFAOYSA-N
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Compound 87b
Molecular Weight:152.1473
Molecular Formula:C8H8O3
InChIKey:JVTZFYYHCGSXJV-UHFFFAOYSA-N
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Compound 87c
Molecular Weight:166.1739
Molecular Formula:C9H10O3
InChIKey:WJUFSDZVCOTFON-UHFFFAOYSA-N
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Compound 88
Molecular Weight:332.3478
Molecular Formula:C18H20O6
InChIKey:PBPZFIDICRTSRM-UHFFFAOYSA-N
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Compound 89
Molecular Weight:122.1213
Molecular Formula:C7H6O2
InChIKey:MDYOLVRUBBJPFM-UHFFFAOYSA-N
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Compound 90
Molecular Weight:240.2606
Molecular Formula:C13H12N4O
InChIKey:ZFWAHZCOKGWUIT-BMRADRMJSA-N
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Compound 91
Molecular Weight:171.259
Molecular Formula:C5H10NNaS2
InChIKey:IOEJYZSZYUROLN-UHFFFAOYSA-M
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Compound 92
Molecular Weight:164.292
Molecular Formula:C5H12N2S2
InChIKey:MDDIUTVUBYEEEM-UHFFFAOYSA-N
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Compound 93
Molecular Weight:385.17
Molecular Formula:C18H34OSn
InChIKey:WCMMILVIRZAPLE-UHFFFAOYSA-M
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Compound 94
Molecular Weight:680.26
Molecular Formula:C30H66OSn2
InChIKey:XMMLWZGDLISQER-UHFFFAOYSA-N
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Compound 95
Molecular Weight:263.153
Molecular Formula:C5H4F6LiNS2
InChIKey:KCCXGARYAHZPIC-UHFFFAOYSA-M
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Compound 96a
Molecular Weight:719.6
Molecular Formula:C10H8F12N2PbS4
InChIKey:ATSMHBZOFVJTRX-UHFFFAOYSA-L
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Compound 97a
Molecular Weight:397.4
Molecular Formula:C12H8F2Pb
InChIKey:ZHJIVGGYOSWALV-UHFFFAOYSA-N
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Compound 98
Molecular Weight:312
Molecular Formula:C2H8Cl3NO2Te
InChIKey:VSJCJBQENUBFJC-UHFFFAOYSA-N
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Compound 96b
Molecular Weight:640
Molecular Formula:C10H8F12N2S4Te
InChIKey:CIYHDXXJANLUIF-UHFFFAOYSA-N
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Compound 97b
Molecular Weight:317.8
Molecular Formula:C12H8F2Te
InChIKey:ASDHETSGUKNIBB-UHFFFAOYSA-N
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Compound 99
Molecular Weight:333.4727
Molecular Formula:Not Available
InChIKey:Not Available
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  1. 1 - 116