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Iron-Catalyzed Reactions of Grignard Reagents

Organomagnesium Compounds (2008)

  1. Gérard Cahiez,
  2. Christophe Duplais

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0412

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Cahiez, G. and Duplais, C. 2009. Iron-Catalyzed Reactions of Grignard Reagents. Patai's Chemistry of Functional Groups. .

Author Information

  1. UMR 8123 CNRS-ESCOM-UCP, Laboratoire de Synthèse Organique Sélective et de Chimie Organométallique (SOSCO), Cergy-Pontoise, Neuvilles/Oise, France

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Deprotonation of Ketones
  • 3
    Iron-Catalyzed Acylation of Grignard Reagents
  • 4
    Iron-Catalyzed Cross-Coupling Reactions
  • 5
    Iron-Catalyzed Homocoupling of Aromatic Grignard Reagents
  • 6
    Other Reactions
  • 7
    Applications of Iron-Catalyzed Reactions of Grignard Reagents in Organic Synthesis

Keywords:

  • Grignard reagent iron-catalyzed acylation;
  • ketone deprotonation;
  • linear aliphatic carboxylic acid chlorides;
  • functionalized aryl Grignard compounds;
  • iron-catalyzed cross-coupling reactions;
  • aryl Grignard reagents and alkyl bromides and cross-coupling;
  • radical cyclization;
  • Grignard reagent iron-catalyzed reactions in organic synthesis