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The Chemistry of Organomagnesium Ate Complexes

Organomagnesium Compounds (2008)

  1. Hideki Yorimitsu,
  2. Koichiro Oshima

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0414

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Yorimitsu, H. and Oshima, K. 2009. The Chemistry of Organomagnesium Ate Complexes. Patai's Chemistry of Functional Groups. .

Author Information

  1. Kyoto University, Kyoto-daigaku Katsura, Department of Material Chemistry, Graduate School of Engineering, Kyoto, Nishikyo, Japan

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Preparation of Triorganomagnesates
  • 3
    Reactions of Triorganomagnesates
  • 4
    Additional Important Chemistry of Organomagnesates
  • 5
    Summary

Keywords:

  • triorganomagnesate preparation;
  • ate complexes and organometallic chemists;
  • fluorene deprotonation reaction efficiency;
  • halogen–lithium exchange reactions;
  • controlled dihaloarene metalation;
  • monomethylation with lithium trimethylmagnesate;
  • triorganomagnesate position in organic synthesis;
  • triorganomagnesate reaction

Featured Compounds

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  1. 1 - 14
Compound 1
Molecular Weight:486.706
Molecular Formula:C29H42O4S
InChIKey:PQAXSDZKLWYBKK-NIORVENWSA-N
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Compound 2
Molecular Weight:486.706
Molecular Formula:C29H42O4S
InChIKey:CYPRRMUGAAMNEJ-ODVCYQEDSA-N
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Compound 3
Molecular Weight:352.062
Molecular Formula:C12H16Br2O2
InChIKey:NHYXXIPTDAPPOO-UHFFFAOYSA-N
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Compound 4
Molecular Weight:296.307
Molecular Formula:C15H11F3OS
InChIKey:RDBJQDMMWXAZRS-UHFFFAOYSA-N
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Compound 5
Molecular Weight:481.531
Molecular Formula:C23H26F3N3O3S
InChIKey:VYFDSJLOCIGIKP-SFTDATJTSA-N
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Compound 6
Molecular Weight:284.031
Molecular Formula:C9H16Br2
InChIKey:WPTBDWWKCWNJPL-MRVPVSSYSA-N
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Compound 7
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 8
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 9
Molecular Weight:1077.949
Molecular Formula:C56H58BrIO7Si
InChIKey:XMIIYANPNUKHGV-SNEIGPGPSA-N
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Compound 10
Molecular Weight:871.141
Molecular Formula:C56H58O7Si
InChIKey:SHPTVALZYYTMKM-CIEWLVHQSA-N
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Compound 11
Molecular Weight:953.059
Molecular Formula:C56H59BrO7Si
InChIKey:Not Available
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Compound 14
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 13
Molecular Weight:594.5818
Molecular Formula:C21H26F12O2Si2
InChIKey:NMOMEDMXJVGWQE-UHFFFAOYSA-N
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Compound 12
Molecular Weight:680.4144
Molecular Formula:C18H21F12IO2Si2
InChIKey:OWVZCUNQMOSINS-UHFFFAOYSA-N
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  1. 1 - 14