Standard Article

Thermochemical Considerations of Metal Enolates

Metal Enolates (2009)

  1. Joel F. Liebman1,
  2. Suzanne W. Slayden2

Published Online: 15 SEP 2010

DOI: 10.1002/9780470682531.pat0420

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Liebman, J. F. and Slayden, S. W. 2010. Thermochemical Considerations of Metal Enolates. Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    University of Maryland, Department of Chemistry and Biochemistry, Baltimore, USA

  2. 2

    George Mason University, Department of Chemistry, Fairfax, USA

Publication History

  1. Published Online: 15 SEP 2010

Abstract

  • 1
    Introduction
  • 2
    Group 1: Lithium, Sodium, Potassium, Rubidium and Cesium
  • 3
    Group 2: Beryllium, Magnesium, Calcium, Strontium and Barium
  • 4
    Group 13: Aluminum, Gallium, Indium and Thallium
  • 5
    Group 14: Tin and Lead
  • 6
    Group 11: Copper, Silver and Gold
  • 7
    Group 12: Zinc, Cadmium and Mercury
  • 8
    Group 3: Scandium, Yttrium and the Lanthanides
  • 9
    Actinides
  • 10
    Group 4: Titanium, Zirconium and Hafnium
  • 11
    Group 5: Vanadium, Niobium and Tantalum
  • 12
    Group 6: Chromium, Molybdenum and Tungsten
  • 13
    Group 7: Manganese and Rhenium
  • 14
    Group 8: Iron, Ruthenium and Osmium
  • 15
    Group 9: Cobalt, Rhodium and Iridium
  • 16
    Group 10: Nickel, Palladium and Platinum

Keywords:

  • thermochemical considerations of metal enolates;
  • group 1-lithium, sodium, potassium, rubidium and cesium;
  • group 2-beryllium, magnesium, calcium, strontium and barium;
  • group 4-titanium, zirconium and hafnium;
  • group 5-vanadium, niobium and tantalum;
  • group 7-manganese and rhenium;
  • group 9-cobalt, rhodium and iridium;
  • carboxylic ester enolates

Featured Compounds

VIEW

  1. 1 - 66
Compound 1
Molecular Weight:114.0563
Molecular Formula:C4H2O4
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 2
Molecular Weight:142.0664
Molecular Formula:C5H2O5
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 3
Molecular Weight:170.0765
Molecular Formula:C6H2O6
InChIKey:WCJLIWFWHPOTAC-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 4
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 6
Molecular Weight:600.8295
Molecular Formula:C34H58N4Na2O2
InChIKey:TUVNCILZFZYHBQ-UHFFFAOYSA-L
View compound in article | Full details | Search for this compound
Compound 7
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 8
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 9
Molecular Weight:140.1797
Molecular Formula:C8H12O2
InChIKey:BADXJIPKFRBFOT-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 10
Molecular Weight:26.0373
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 11
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 11a
Molecular Weight:242.2699
Molecular Formula:C15H14O3
InChIKey:CIEYTVIYYGTCCI-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 11b
Molecular Weight:244.2857
Molecular Formula:C15H16O3
InChIKey:CBIBTBSDPZSTOE-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 12
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 13
Molecular Weight:366.47
Molecular Formula:C12H20ClNO2Sn
InChIKey:CNAGRSSUEIEUJQ-KDLXQMMSSA-L
View compound in article | Full details | Search for this compound
Compound 14
Molecular Weight:160.28
Molecular Formula:C5H4S3
InChIKey:JUEJPBZMWHMMPS-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 15
Molecular Weight:190.77
Molecular Formula:C3H4O2Sn
InChIKey:ZPBCGGUGCYYARM-GDNGEXCGSA-L
View compound in article | Full details | Search for this compound
Compound 16
Molecular Weight:142.1094
Molecular Formula:C6H6O4
InChIKey:BEJNERDRQOWKJM-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 17
Molecular Weight:146.1427
Molecular Formula:C9H6O2
InChIKey:ZYGHJZDHTFUPRJ-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 18
Molecular Weight:146.1427
Molecular Formula:C9H6O2
InChIKey:OTAFHZMPRISVEM-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 19
Molecular Weight:196.2014
Molecular Formula:C13H8O2
InChIKey:JNELGWHKGNBSMD-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 20
Molecular Weight:433.701
Molecular Formula:C16H24BrN4OZn
InChIKey:XYSACNAJRRYJRO-UNVLYCKESA-M
View compound in article | Full details | Search for this compound
Compound 22a
Molecular Weight:1080.53
Molecular Formula:C52H79N6O5P2Sm
InChIKey:NCYNUJVCFMVHAF-UHFFFAOYSA-K
View compound in article | Full details | Search for this compound
Compound 23
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 22
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 24
Molecular Weight:486.6448
Molecular Formula:C38H30
InChIKey:FWSYACUVHKGULL-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 22b
Molecular Weight:1103.21
Molecular Formula:C52H79N6O5P2Yb
InChIKey:FXNBSQPZTFGICQ-UHFFFAOYSA-K
View compound in article | Full details | Search for this compound
Compound 25
Molecular Weight:1231.2494
Molecular Formula:C52H78O4Th2
InChIKey:UQWAGJUVUDMKOD-FBJMTUJNSA-L
View compound in article | Full details | Search for this compound
Compound 26
Molecular Weight:836.576
Molecular Formula:C32H38Lu2O4
InChIKey:MLSMYPCPXXBDDN-FBJMTUJNSA-L
View compound in article | Full details | Search for this compound
Compound 27
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 27'
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 28
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 29
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 30
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 31
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 32
Molecular Weight:741.4064
Molecular Formula:C24H70N4Si8V2
InChIKey:VFTHXULZOPTTCU-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 33
Molecular Weight:797.4266
Molecular Formula:C26H70N4O2Si8V2
InChIKey:PEWAITTWSIYPGT-UHFFFAOYSA-L
View compound in article | Full details | Search for this compound
Compound 34
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 35
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 36
Molecular Weight:382.084
Molecular Formula:C11H8BrCrNO6
InChIKey:XVNQJQTUGMCJQS-HEANBJSFSA-M
View compound in article | Full details | Search for this compound
Compound 37
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 38
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 39
Molecular Weight:982.019
Molecular Formula:C35H32NO7PRe2
InChIKey:VZFJGNHAWMEXHO-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 40
Molecular Weight:982.019
Molecular Formula:C35H32NO7PRe2
InChIKey:HPCGGKZTBMEGRD-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 41
Molecular Weight:98.0999
Molecular Formula:C5H6O2
InChIKey:BGLUXFNVVSVEET-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 42
Molecular Weight:98.0999
Molecular Formula:C5H6O2
InChIKey:SIFBVNDLLGPEKT-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 43
Molecular Weight:98.0999
Molecular Formula:C5H6O2
InChIKey:BGLUXFNVVSVEET-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 44
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 45
Molecular Weight:461.44
Molecular Formula:C15H40OP4Ru
InChIKey:DNJWJYGHIYFNBZ-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 46
Molecular Weight:385.36
Molecular Formula:C12H31OP3Ru
InChIKey:ZYSHAKYJSGWQHL-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 47
Molecular Weight:459.47
Molecular Formula:C16H42P4Ru
InChIKey:OBJAIVDSCRTIHG-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 48
Molecular Weight:1047.04
Molecular Formula:C24H12O11Os3
InChIKey:SLHAEOSLURXKKZ-UHFFFAOYSA-M
View compound in article | Full details | Search for this compound
Compound 49
Molecular Weight:935.87
Molecular Formula:C14H5O12Os3
InChIKey:DQVCWUFZMJGXNP-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 50
Molecular Weight:430.3553
Molecular Formula:C22H32Co2O
InChIKey:NGLFUPAWHVVBLA-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 51a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 52a
Molecular Weight:289.1544
Molecular Formula:C8H14CoN4O4
InChIKey:MILFBTCSLXIBQM-BVHINDLDSA-L
View compound in article | Full details | Search for this compound
Compound 51b
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 52b
Molecular Weight:408.2949
Molecular Formula:C16H21CoN4O5
InChIKey:FCNNWKDQGBGAFX-HZBWDVPZSA-L
View compound in article | Full details | Search for this compound
Compound 51c
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 51d
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 53
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 54
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound 55
Molecular Weight:575.2423
Molecular Formula:C34H30NiOP2
InChIKey:DCFPYKBULXXRKX-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 56
Molecular Weight:575.2423
Molecular Formula:C34H30NiOP2
InChIKey:AZBRFHODVVEQJT-UHFFFAOYSA-M
View compound in article | Full details | Search for this compound
Compound 57
Molecular Weight:859.792
Molecular Formula:C43H38O3P2Pt
InChIKey:WRLGALKTCUCLJG-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound 58
Molecular Weight:984.937
Molecular Formula:C53H43O3P2Pt
InChIKey:HXYCXNOYFQWAJE-RBXRIXKVSA-N
View compound in article | Full details | Search for this compound
Compound 59
Molecular Weight:921.861
Molecular Formula:C48H40O3P2Pt
InChIKey:VMHYJQNCZHAKLN-NKKLIDNXSA-L
View compound in article | Full details | Search for this compound

VIEW

  1. 1 - 66