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Metal Enolates as Synthons in Organic Chemistry

Metal Enolates (2009)

  1. Daniel Stolz,
  2. Uli Kazmaier

Published Online: 15 SEP 2010

DOI: 10.1002/9780470682531.pat0423

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Stolz, D. and Kazmaier, U. 2010. Metal Enolates as Synthons in Organic Chemistry. Patai's Chemistry of Functional Groups. .

Author Information

  1. Saarland University, Department of Organic Chemistry, Germany

Publication History

  1. Published Online: 15 SEP 2010

Abstract

  • 1
    C[BOND]C Bond Formation by α-Substitution of Ketone Enolates
  • 2
    C[BOND]C Bond Formation by Addition of Ketone Enolates to Carbonyl Groups
  • 3
    C[BOND]C Bond Formation by Michael Addition of Metal Enolates
  • 4
    Ester Enolates

Keywords:

  • metal enolates as synthons in organic chemistry;
  • C–C bond formation by α-substitution of ketone enolates;
  • control of stereo- and regioselectivity in enolate preparation;
  • ketone enolates as nucleophiles in transition-metal catalyzed allylic alkylations;
  • C–C bond formation by addition of ketone enolates to carbonyl groups;
  • C–C bond formation by Michael addition of metal enolates;
  • ester enolates;
  • amino acid enolates - asymmetric syntheses with amino acid enolates