Standard Article

Catalysis Using β-Diketonato Metal Complexes

Metal Enolates (2009)

  1. Stephen A. Westcott

Published Online: 15 SEP 2010

DOI: 10.1002/9780470682531.pat0426

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Westcott, S. A. 2010. Catalysis Using β-Diketonato Metal Complexes. Patai's Chemistry of Functional Groups. .

Author Information

  1. Mount Allison University, Department of Chemistry, Sackville, Canada

Publication History

  1. Published Online: 15 SEP 2010

Chemistry Terms

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Abstract

  • 1
    Introduction
  • 2
    Hydroformylation
  • 3
    Oxidation
  • 4
    Hydrogenation
  • 5
    Addition of Main Group Compounds
  • 6
    C[BOND]C Bond Formation
  • 7
    Isomerization
  • 8
    Acknowledgment

Keywords:

  • catalysis using β-diketonato metal complexes;
  • transition metals - used as catalysts for industrial processes;
  • metal enolates, used as precursors to impregnate heterogenous catalysts;
  • β-diketonato metal complexes - and catalyzed hydroformylations;
  • metal β-diketonates, significant impact on oxidation of alkanes;
  • hydrogenation;
  • catalytic carbon–carbon bond-forming reactions - types of transformations in organic synthesis and metal enolate complexes;
  • metal enolates, limited role in metal-catalyzed alkene isomerization

Featured Compounds

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  1. 1 - 126
Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 2
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 3
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 5
Molecular Weight:259.0415
Molecular Formula:C7H8O4Rh
InChIKey:CPRFTFJQMGHRRM-UHFFFAOYSA-N
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Compound 6
Molecular Weight:259.1276
Molecular Formula:C9H16O2Rh
InChIKey:BUBVUHUOCLVAIH-UHFFFAOYSA-N
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Compound 9
Molecular Weight:142.1956
Molecular Formula:C8H14O2
InChIKey:SJMYWORNLPSJQO-UHFFFAOYSA-N
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Compound 12
Molecular Weight:246.1984
Molecular Formula:C13H11O3P
InChIKey:AWOHBYYDSORLNL-UHFFFAOYSA-N
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Compound 10
Molecular Weight:172.2215
Molecular Formula:C9H16O3
InChIKey:JWRQJTAGHDNUQX-UHFFFAOYSA-N
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Compound 11
Molecular Weight:172.2215
Molecular Formula:C9H16O3
InChIKey:PWGOVYXBFXJPQX-UHFFFAOYSA-N
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Compound 13
Molecular Weight:532.5193
Molecular Formula:C27H33O9P
InChIKey:JQKHNBQZGUKYPX-UHFFFAOYSA-N
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Compound 16
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 14a
Molecular Weight:82.1436
Molecular Formula:C6H10
InChIKey:HGCIXCUEYOPUTN-UHFFFAOYSA-N
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Compound 14b
Molecular Weight:96.1702
Molecular Formula:C7H12
InChIKey:Not Available
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Compound 15
Molecular Weight:Not Available
Molecular Formula:(CH2)nC6H10O
InChIKey:KVFDZFBHBWTVID-UHFFFAOYSA-N
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Compound 17
Molecular Weight:466.532
Molecular Formula:C25H28N2O3PS
InChIKey:SWAHZJDOTZQWDL-UHFFFAOYSA-M
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Compound 14
Molecular Weight:Not Available
Molecular Formula:(CH2)nC5H8
InChIKey:HGCIXCUEYOPUTN-UHFFFAOYSA-N
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Compound 15a
Molecular Weight:112.1696
Molecular Formula:C7H12O
InChIKey:Not Available
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Compound 15b
Molecular Weight:126.1962
Molecular Formula:C8H14O
InChIKey:UGBFRCHGZFHSBC-UHFFFAOYSA-N
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Compound 48
Molecular Weight:104.1491
Molecular Formula:C8H8
InChIKey:PPBRXRYQALVLMV-UHFFFAOYSA-N
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Compound 20
Molecular Weight:268.4177
Molecular Formula:C17H33P
InChIKey:LCEQCOWQYGWUCN-HPPSQRKUSA-N
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Compound 18
Molecular Weight:94.1543
Molecular Formula:C7H10
InChIKey:JFNLZVQOOSMTJK-KNVOCYPGSA-N
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Compound 19
Molecular Weight:124.1803
Molecular Formula:C8H12O
InChIKey:UAQYREPFSVCDHT-RNJXMRFFSA-N
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Compound 23
Molecular Weight:325.4876
Molecular Formula:C22H31NO
InChIKey:OOGJQPCLVADCPB-UHFFFAOYSA-N
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Compound 22
Molecular Weight:240.297
Molecular Formula:C16H16O2
InChIKey:YAFNYXMBAKCMCF-UHFFFAOYSA-N
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Compound 24
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 25a
Molecular Weight:446.5348
Molecular Formula:C28H30O5
InChIKey:ZBZYPJHJWLRKHH-ADHCPZQOSA-N
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Compound 25b
Molecular Weight:302.2772
Molecular Formula:C13H18O8
InChIKey:JZHGLZUWXDWWSN-HYWTVENDSA-N
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Compound 26a
Molecular Weight:446.5348
Molecular Formula:C28H30O5
InChIKey:YRJXDALLXFVRDI-RFBUSEEYSA-N
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Compound 26b
Molecular Weight:302.2772
Molecular Formula:C13H18O8
InChIKey:CUWXDGCHBLIRGH-KIGPFUIMSA-N
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Compound 28
Molecular Weight:544.7947
Molecular Formula:C31H48O6Si
InChIKey:Not Available
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Compound 27
Molecular Weight:514.7687
Molecular Formula:C30H46O5Si
InChIKey:Not Available
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Compound 25
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 26
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 29
Molecular Weight:306.65
Molecular Formula:C10H16O4Pd
InChIKey:YNUJADNRNHJXDT-UHFFFAOYSA-N
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Compound 31
Molecular Weight:356.192
Molecular Formula:C15H24FeO6
InChIKey:KULJRCSOKIBGHK-UHFFFAOYSA-N
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Compound 35
Molecular Weight:267.1725
Molecular Formula:C10H16O5V
InChIKey:GGUKAPURIDGXAJ-UHFFFAOYSA-N
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Compound 37
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 38
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 39
Molecular Weight:152.1904
Molecular Formula:C9H12O2
InChIKey:UDJYVJWCIAORAU-QMMMGPOBSA-N
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Compound 40
Molecular Weight:168.1898
Molecular Formula:C9H12O3
InChIKey:UKIDJYWKJZKXGP-UHFFFAOYSA-N
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Compound 41
Molecular Weight:136.234
Molecular Formula:C10H16
InChIKey:ORILYTVJVMAKLC-UHFFFAOYSA-N
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Compound 42
Molecular Weight:216.297
Molecular Formula:C10H16O3S
InChIKey:QPHBUJJTFKRYHM-UHFFFAOYSA-N
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Compound 43
Molecular Weight:263.778
Molecular Formula:C10H16CuO4
InChIKey:NPJDQKHHXAPMKK-UHFFFAOYSA-N
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Compound 44
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 46
Molecular Weight:258.925
Molecular Formula:C10H16NiO4
InChIKey:MRMOJNWIZDYILS-UHFFFAOYSA-N
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Compound 45
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 47
Molecular Weight:258.925
Molecular Formula:C10H16NiO4
InChIKey:MRMOJNWIZDYILS-UHFFFAOYSA-N
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Compound 49
Molecular Weight:273.35
Molecular Formula:C15H15NO2S
InChIKey:KUWCTOOXSUPLAW-UHFFFAOYSA-N
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Compound 51
Molecular Weight:401.42
Molecular Formula:C15H24O6Ru
InChIKey:AGBKQGSACOPLMB-UHFFFAOYSA-N
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Compound 52
Molecular Weight:100.0728
Molecular Formula:C4H4O3
InChIKey:Not Available
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Compound 53
Molecular Weight:86.0892
Molecular Formula:C4H6O2
InChIKey:Not Available
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Compound 54
Molecular Weight:423.4148
Molecular Formula:C21H36O2Rh
InChIKey:YFWAAMXDFAKVHI-SUXDNRKISA-N
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Compound 57
Molecular Weight:295.1597
Molecular Formula:C12H16O2Rh
InChIKey:JHPQEWVZOZWOGI-UHFFFAOYSA-N
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Compound 58
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 59
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 60
Molecular Weight:395.316
Molecular Formula:C10H16O4Pt
InChIKey:WXIWSQBJNUSTTO-UHFFFAOYSA-N
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Compound 61
Molecular Weight:80.1277
Molecular Formula:C6H8
InChIKey:Not Available
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Compound 62
Molecular Weight:262.228
Molecular Formula:C14H23BO2Si
InChIKey:ARMSAQNLTKGMGM-UHFFFAOYSA-N
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Compound 63
Molecular Weight:342.355
Molecular Formula:C20H31BO2Si
InChIKey:ROZYQBXOMNMBMQ-AEFFLSMTSA-N
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Compound 64
Molecular Weight:166.3031
Molecular Formula:C12H22
InChIKey:Not Available
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Compound 65
Molecular Weight:302.5695
Molecular Formula:C20H34Si
InChIKey:JXTMINZNHULJTM-VBKFSLOCSA-N
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Compound 66
Molecular Weight:292.264
Molecular Formula:C18H33BO2
InChIKey:HKMCTABLUNACQO-OKHIERNBSA-N
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Compound 67
Molecular Weight:464.7455
Molecular Formula:C30H32OSi2
InChIKey:JBFGDGQLXXGLDE-DAQGNMOOSA-N
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Compound 68
Molecular Weight:266.4528
Molecular Formula:C18H22Si
InChIKey:CTTOBQWZICTRLK-PPCLGBEZSA-N
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Compound 69
Molecular Weight:82.1436
Molecular Formula:C6H10
InChIKey:CGHIBGNXEGJPQZ-UHFFFAOYSA-N
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Compound 70
Molecular Weight:374.15
Molecular Formula:C16H33NOSn
InChIKey:UFRJHGBLPVTMDZ-UHFFFAOYSA-N
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Compound 72
Molecular Weight:275.0552
Molecular Formula:C16H24Ni
InChIKey:JRTIUDXYIUKIIE-KZUMESAESA-N
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Compound 71
Molecular Weight:374.15
Molecular Formula:C16H33NOSn
InChIKey:FRUZTDPXQAGPDL-UHFFFAOYSA-N
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Compound 75
Molecular Weight:448.385
Molecular Formula:C23H27Cl2N3O2
InChIKey:CEUORZQYGODEFX-UHFFFAOYSA-N
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Compound 73
Molecular Weight:203.2371
Molecular Formula:C12H13NO2
InChIKey:YDXMSFFNNQQPRD-UHFFFAOYSA-N
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Compound 74
Molecular Weight:231.122
Molecular Formula:C10H12Cl2N2
InChIKey:UDQMXYJSNNCRAS-UHFFFAOYSA-N
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Compound 76
Molecular Weight:102.1332
Molecular Formula:C8H6
InChIKey:UEXCJVNBTNXOEH-UHFFFAOYSA-N
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Compound 86
Molecular Weight:102.1332
Molecular Formula:C8H6
InChIKey:UEXCJVNBTNXOEH-UHFFFAOYSA-N
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Compound 77
Molecular Weight:288.3227
Molecular Formula:C20H17P
InChIKey:VWSQXAYZRJDUAN-UHFFFAOYSA-N
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Compound 78
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 80
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 81
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 79
Molecular Weight:301.3
Molecular Formula:C10H16O4Ru
InChIKey:ANZPFKUGSPLSEX-UHFFFAOYSA-N
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Compound 82
Molecular Weight:74.1216
Molecular Formula:C4H10O
InChIKey:LRHPLDYGYMQRHN-UHFFFAOYSA-N
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Compound 83
Molecular Weight:84.1164
Molecular Formula:C5H8O
InChIKey:BUDQDWGNQVEFAC-UHFFFAOYSA-N
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Compound 84
Molecular Weight:158.238
Molecular Formula:C9H18O2
InChIKey:HVHNQFALNKRKQY-UHFFFAOYSA-N
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Compound 85
Molecular Weight:110.177
Molecular Formula:C6H6S
InChIKey:RMVRSNDYEFQCLF-UHFFFAOYSA-N
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Compound 87
Molecular Weight:212.31
Molecular Formula:C14H12S
InChIKey:UKRUNIUJAMCKER-UHFFFAOYSA-N
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Compound 88
Molecular Weight:234.2909
Molecular Formula:C14H18O3
InChIKey:KFGYUZRTWCEGFJ-UHFFFAOYSA-N
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Compound 89
Molecular Weight:252.2814
Molecular Formula:C14H17FO3
InChIKey:PMMUAKZDPTUIBE-CQSZACIVSA-N
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Compound 90
Molecular Weight:985.129
Molecular Formula:C30H48Ir2O12
InChIKey:ZRQSOCKSATYUEK-UHFFFAOYSA-N
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Compound 91
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 92
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 93
Molecular Weight:131.1745
Molecular Formula:C9H9N
InChIKey:BLRHMMGNCXNXJL-UHFFFAOYSA-N
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Compound 94
Molecular Weight:158.1519
Molecular Formula:C7H10O4
InChIKey:IMOQCGSCOCUDGV-UHFFFAOYSA-N
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Compound 95
Molecular Weight:229.2744
Molecular Formula:C14H15NO2
InChIKey:RHVSWBHWWALJMM-UHFFFAOYSA-N
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Compound 96
Molecular Weight:630.58
Molecular Formula:C32H44ClN2O2Pd
InChIKey:JQWHCIAMXCBUIN-MECAPONASA-L
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Compound 97
Molecular Weight:134.1751
Molecular Formula:C9H10O
InChIKey:KRIOVPPHQSLHCZ-UHFFFAOYSA-N
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Compound 98
Molecular Weight:126.583
Molecular Formula:C7H7Cl
InChIKey:Not Available
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Compound 99
Molecular Weight:224.2976
Molecular Formula:C16H16O
InChIKey:NKWNLWFVNOMGNF-UHFFFAOYSA-N
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Compound 100
Molecular Weight:391.06
Molecular Formula:C15H9Br2N3
InChIKey:OEUXIMQOMAMKQY-UHFFFAOYSA-N
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Compound 101
Molecular Weight:455.31
Molecular Formula:C20H32S2Sn
InChIKey:VXBHLQIFGXDFDS-UHFFFAOYSA-N
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Compound 102
Molecular Weight:561.763
Molecular Formula:C31H19N3S4
InChIKey:MCUBQWNCIINKRA-UHFFFAOYSA-N
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Compound 103
Molecular Weight:136.214
Molecular Formula:C8H8S
InChIKey:GMPDOIGGGXSAPL-UHFFFAOYSA-N
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Compound 104
Molecular Weight:211.339
Molecular Formula:C7H7BrMgO
InChIKey:JKXAZEXIOPFJSC-UHFFFAOYSA-M
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Compound 105
Molecular Weight:134.1751
Molecular Formula:C9H10O
InChIKey:UAJRSHJHFRVGMG-UHFFFAOYSA-N
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Compound 106
Molecular Weight:184.2338
Molecular Formula:C13H12O
InChIKey:RHDYQUZYHZWTCI-UHFFFAOYSA-N
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Compound 109
Molecular Weight:252.443
Molecular Formula:C7H7BrOZn
InChIKey:UIEWSJCYOUQCBZ-UHFFFAOYSA-M
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Compound 110
Molecular Weight:171.034
Molecular Formula:C7H7Br
InChIKey:ZBTMRBYMKUEVEU-UHFFFAOYSA-N
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Compound 111
Molecular Weight:198.2604
Molecular Formula:C14H14O
InChIKey:ASKBXZKXIBPNRA-UHFFFAOYSA-N
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Compound 112
Molecular Weight:188.2225
Molecular Formula:C12H12O2
InChIKey:ZLMSVRKKQGBUOW-UHFFFAOYSA-N
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Compound 113
Molecular Weight:70.0898
Molecular Formula:C4H6O
InChIKey:FUSUHKVFWTUUBE-UHFFFAOYSA-N
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Compound 114
Molecular Weight:258.3123
Molecular Formula:C16H18O3
InChIKey:XODUZVJHGYSNES-UHFFFAOYSA-N
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Compound 115
Molecular Weight:121.93
Molecular Formula:C6H7BO2
InChIKey:HXITXNWTGFUOAU-UHFFFAOYSA-N
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Compound 116
Molecular Weight:70.0898
Molecular Formula:C4H6O
InChIKey:FUSUHKVFWTUUBE-UHFFFAOYSA-N
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Compound 117
Molecular Weight:148.2017
Molecular Formula:C10H12O
InChIKey:AKGGYBADQZYZPD-UHFFFAOYSA-N
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Compound 118
Molecular Weight:191.248
Molecular Formula:C7H13NO3S
InChIKey:ZNYXZULGRNGSKN-VMPITWQZSA-N
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Compound 119
Molecular Weight:269.36
Molecular Formula:C13H19NO3S
InChIKey:ADKYOJJZYMKJDL-SSJGJQFISA-N
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Compound 120
Molecular Weight:160.1693
Molecular Formula:C10H8O2
InChIKey:FXFYOPQLGGEACP-UHFFFAOYSA-N
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Compound 121
Molecular Weight:238.2812
Molecular Formula:C16H14O2
InChIKey:SUHIZPDCJOQZLN-CYBMUJFWSA-N
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Compound 122
Molecular Weight:610.574
Molecular Formula:C38H28O4P2
InChIKey:RZZDRSHFIVOQAF-UHFFFAOYSA-N
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Compound 123
Molecular Weight:448.5061
Molecular Formula:C24H32O8
InChIKey:ZRMZLSQYURCONC-BUHFOSPRSA-N
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Compound 124
Molecular Weight:584.7725
Molecular Formula:C32H44O8Si
InChIKey:AZYHAAHHDWGECQ-FRNXTAFCSA-N
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Compound 125
Molecular Weight:303.419
Molecular Formula:C17H21NO2S
InChIKey:QSWUWXQFHDMZNV-CDJQDVQCSA-N
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Compound 126
Molecular Weight:377.498
Molecular Formula:C20H27NO4S
InChIKey:ZYFZJHJFAWMBKX-ANHNSEMMSA-N
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Compound 127
Molecular Weight:468.5248
Molecular Formula:C33H25OP
InChIKey:KRWTWSSMURUMDE-UHFFFAOYSA-N
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Compound 128
Molecular Weight:82.1005
Molecular Formula:C5H6O
InChIKey:Not Available
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Compound 129
Molecular Weight:168.1898
Molecular Formula:C9H12O3
InChIKey:WTXWGJHLNCVWJH-NJUXHZRNSA-N
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Compound 130
Molecular Weight:168.1898
Molecular Formula:C9H12O3
InChIKey:WTXWGJHLNCVWJH-GEVIPFJHSA-N
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Compound 131
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 132
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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