Standard Article

Analytical Aspects of Metal Enolates

Metal Enolates (2009)

  1. Eli Harlev1,
  2. Shmuel Bittner1,
  3. Jacob Zabicky2

Published Online: 15 SEP 2010

DOI: 10.1002/9780470682531.pat0428

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Harlev, E., Bittner, S. and Zabicky, J. 2010. Analytical Aspects of Metal Enolates. Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    Ben-Gurion University of the Negev, Department of Chemistry, Beer-Sheva, Israel

  2. 2

    Ben-Gurion University of the Negev, Department of Chemical Engineering, Beer-Sheva, Israel

Publication History

  1. Published Online: 15 SEP 2010

Abstract

  • 1
    Introduction and Scope of the Chapter
  • 2
    Detection and Determination of Metal Enolates
  • 3
    Metal Enolates as Analytical Reagents and Aids

Keywords:

  • analytical aspects of metal enolates;
  • metal enolate detection and determination;
  • X-ray fluorescence and absorption spectroscopies;
  • electrochemical methods;
  • liquid chromatography - column chromatography;
  • metal enolates as analytical reagents and aids;
  • optodes, photoluminescent and chemiluminescent tracers;
  • specific reagents - β-diketonates

Featured Compounds

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  1. 1 - 101
Compound 1
Molecular Weight:176.1241
Molecular Formula:C6H8O6
InChIKey:CIWBSHSKHKDKBQ-JLAZNSOCSA-N
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Compound 2
Molecular Weight:176.1241
Molecular Formula:C6H8O6
InChIKey:CIWBSHSKHKDKBQ-DUZGATOHSA-N
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Compound 3
Molecular Weight:170.1261
Molecular Formula:C5H6N4O3
InChIKey:TVWHNULVHGKJHS-UHFFFAOYSA-N
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Compound 4
Molecular Weight:151.1626
Molecular Formula:C8H9NO2
InChIKey:RZVAJINKPMORJF-UHFFFAOYSA-N
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Compound 5
Molecular Weight:153.1784
Molecular Formula:C8H11NO2
InChIKey:VYFYYTLLBUKUHU-UHFFFAOYSA-N
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Compound 6
Molecular Weight:277.386
Molecular Formula:C6H6MgO9P
InChIKey:ACFGRWJEQJVZTM-LEJBHHMKSA-K
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Compound 7
Molecular Weight:244.289
Molecular Formula:C14H16N2O2
InChIKey:CMVLEYPAEBGDKZ-UHFFFAOYSA-N
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Compound 8
Molecular Weight:142.1094
Molecular Formula:C6H6O4
InChIKey:BEJNERDRQOWKJM-UHFFFAOYSA-N
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Compound 9
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 10
Molecular Weight:214.223
Molecular Formula:C5H15N2O3PS
InChIKey:JKOQGQFVAUAYPM-UHFFFAOYSA-N
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Compound 11
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 12
Molecular Weight:590.7878
Molecular Formula:C34H54O8
InChIKey:BBMULGJBVDDDNI-OWKLGTHSSA-N
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Compound 13
Molecular Weight:443.5573
Molecular Formula:C28H31N2O3
InChIKey:CVAVMIODJQHEEH-UHFFFAOYSA-O
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Compound 14
Molecular Weight:394.3178
Molecular Formula:C18H12N5O6
InChIKey:WCBPJVKVIMMEQC-UHFFFAOYSA-N
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Compound 15
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 16
Molecular Weight:342.256
Molecular Formula:C14H8NaO7S
InChIKey:HFVAFDPGUJEFBQ-UHFFFAOYSA-M
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Compound 17
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 18
Molecular Weight:174.1082
Molecular Formula:C6H6O6
InChIKey:SBJKKFFYIZUCET-JLAZNSOCSA-N
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Compound 19
Molecular Weight:142.176
Molecular Formula:C6H6O2S
InChIKey:GKWLILHTTGWKLQ-UHFFFAOYSA-N
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Compound 20
Molecular Weight:176.2151
Molecular Formula:C10H12N2O
InChIKey:QZAYGJVTTNCVMB-UHFFFAOYSA-N
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Compound 21
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 22
Molecular Weight:183.2044
Molecular Formula:C9H13NO3
InChIKey:UCTWMZQNUQWSLP-VIFPVBQESA-N
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Compound 23
Molecular Weight:182.1733
Molecular Formula:C9H10O4
InChIKey:QRMZSPFSDQBLIX-UHFFFAOYSA-N
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Compound 24
Molecular Weight:108.1179
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 25
Molecular Weight:215.2081
Molecular Formula:C11H9N3O2
InChIKey:RMRYLOYUZBBPEK-BUHFOSPRSA-N
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Compound 26
Molecular Weight:271.268
Molecular Formula:C15H13NO4
InChIKey:TWIIVLKQFJBFPW-UHFFFAOYSA-N
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Compound 27
Molecular Weight:1134.9843
Molecular Formula:C42H70O35
InChIKey:WHGYBXFWUBPSRW-FOUAGVGXSA-N
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Compound 28
Molecular Weight:204.2252
Molecular Formula:C11H12N2O2
InChIKey:Not Available
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Compound 29
Molecular Weight:181.1885
Molecular Formula:C9H11NO3
InChIKey:OUYCCCASQSFEME-UHFFFAOYSA-N
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Compound 30
Molecular Weight:727.02
Molecular Formula:C34H35Cl3NP2Ru
InChIKey:IJJNPVXSYWIDEI-UHFFFAOYSA-K
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Compound 33
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 33a
Molecular Weight:944.807
Molecular Formula:C40H36FeN4O12S4
InChIKey:ZYCJZJGANGFOLR-VDUIZXOZSA-J
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Compound 33b
Molecular Weight:952.508
Molecular Formula:C40H36CuN4O12S4
InChIKey:KYIFBKFEZQTTPG-VDUIZXOZSA-J
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Compound 33c
Molecular Weight:947.655
Molecular Formula:C40H36N4NiO12S4
InChIKey:TUCSUDGFDHLMIZ-VDUIZXOZSA-J
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Compound 43
Molecular Weight:110.1106
Molecular Formula:C6H6O2
InChIKey:QIGBRXMKCJKVMJ-UHFFFAOYSA-N
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Compound 34
Molecular Weight:131.1332
Molecular Formula:C4H9N3O2
InChIKey:CVSVTCORWBXHQV-UHFFFAOYSA-N
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Compound 35
Molecular Weight:113.1179
Molecular Formula:C4H7N3O
InChIKey:Not Available
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Compound 36
Molecular Weight:194.1873
Molecular Formula:C9H10N2O3
InChIKey:HSMNQINEKMPTIC-UHFFFAOYSA-N
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Compound 37
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 38
Molecular Weight:716.7123
Molecular Formula:C36H45CoN6O6
InChIKey:CCEYFKBLDDETLQ-UHFFFAOYSA-K
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Compound 39
Molecular Weight:577.3504
Molecular Formula:C12H28CoN11O12
InChIKey:ZHKSBYUYZZVELT-XKQYSACFSA-L
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Compound 40
Molecular Weight:324.783
Molecular Formula:C14H13ClN2O3S
InChIKey:XWJYSHXJIZVDPH-UHFFFAOYSA-N
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Compound 41
Molecular Weight:338.2647
Molecular Formula:C12H18O11
InChIKey:MLSJBGYKDYSOAE-DCWMUDTNSA-N
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Compound 42
Molecular Weight:256.2518
Molecular Formula:C12H16O6
InChIKey:OMWLKUOQGQENOP-ZIQFBCGOSA-N
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Compound 44
Molecular Weight:169.1778
Molecular Formula:C8H11NO3
InChIKey:LXNHXLLTXMVWPM-UHFFFAOYSA-N
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Compound 45
Molecular Weight:307.323
Molecular Formula:C10H17N3O6S
InChIKey:RWSXRVCMGQZWBV-WDSKDSINSA-N
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Compound 46a
Molecular Weight:123.1094
Molecular Formula:C6H5NO2
InChIKey:PVNIIMVLHYAWGP-UHFFFAOYSA-N
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Compound 47
Molecular Weight:154.251
Molecular Formula:C4H10O2S2
InChIKey:VHJLVAABSRFDPM-UHFFFAOYSA-N
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Compound 46
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 46b
Molecular Weight:122.1246
Molecular Formula:C6H6N2O
InChIKey:DFPAKSUCGFBDDF-UHFFFAOYSA-N
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Compound 48
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 49
Molecular Weight:133.1027
Molecular Formula:C4H7NO4
InChIKey:CKLJMWTZIZZHCS-UHFFFAOYSA-N
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Compound 50
Molecular Weight:192.1235
Molecular Formula:C6H8O7
InChIKey:KRKNYBCHXYNGOX-UHFFFAOYSA-N
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Compound 51a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 51b
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 52
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 53
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 51
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 53a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 53b
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 54a
Molecular Weight:432.917
Molecular Formula:C19H19CuN3O5
InChIKey:HNOKFHMGKPAGGZ-MECAPONASA-M
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Compound 54b
Molecular Weight:557.056
Molecular Formula:C29H23CuN3O5
InChIKey:XNKCXWGGZVSZIS-MECAPONASA-M
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Compound 54
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 55
Molecular Weight:177.1601
Molecular Formula:C8H7N3O2
InChIKey:HWYHZTIRURJOHG-UHFFFAOYSA-N
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Compound 56a
Molecular Weight:737.441
Molecular Formula:C24H30EuF9O6
InChIKey:ZYPKRKSQLAPAGI-KYQUTVEVSA-K
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Compound 56b
Molecular Weight:1037.486
Molecular Formula:C30H30EuF21O6
InChIKey:NWBNFEYYYNUYIQ-KYQUTVEVSA-K
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Compound 56c
Molecular Weight:797.41
Molecular Formula:C30H18EuF9O6
InChIKey:HGFMGZVIRYAVFJ-KYZRAZBSSA-K
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Compound 56d
Molecular Weight:767.296
Molecular Formula:C24H12EuF9O9
InChIKey:DFYJDPUCGJEGCO-YHHPVXJTSA-K
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Compound 56e
Molecular Weight:815.493
Molecular Formula:C24H12EuF9O6S3
InChIKey:KOZFKJVQLAWXDK-YHHPVXJTSA-K
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Compound 56f
Molecular Weight:947.586
Molecular Formula:C42H24EuF9O6
InChIKey:ALTMFGJKLMFKDK-QBNVKMTMSA-K
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Compound 57a
Molecular Weight:917.646
Molecular Formula:C36H38EuF9N2O6
InChIKey:VZYFEZIRMZZUBG-XRPAYOKVSA-K
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Compound 57b
Molecular Weight:1217.691
Molecular Formula:C42H38EuF21N2O6
InChIKey:IXDWEMQNZBHGRW-XRPAYOKVSA-K
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Compound 57c
Molecular Weight:977.615
Molecular Formula:C42H26EuF9N2O6
InChIKey:ZNNMPCGOLYJWGN-GNTOZPBLSA-K
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Compound 57d
Molecular Weight:947.502
Molecular Formula:C36H20EuF9N2O9
InChIKey:PGFJNNSMWBYYOP-QSDLRBNBSA-K
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Compound 57e
Molecular Weight:995.698
Molecular Formula:C36H20EuF9N2O6S3
InChIKey:JKHRQEJUERYSBW-QSDLRBNBSA-K
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Compound 57f
Molecular Weight:1127.791
Molecular Formula:C54H32EuF9N2O6
InChIKey:AIOYLTKXTMSAET-VBVTYZGFSA-K
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Compound 57g
Molecular Weight:924.6077
Molecular Formula:C36H38F9N2O6Tb
InChIKey:KDGYMCSZEXVHHG-XRPAYOKVSA-K
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Compound 57h
Molecular Weight:1224.6527
Molecular Formula:C42H38F21N2O6Tb
InChIKey:YGAJEJDZPSRVMX-XRPAYOKVSA-K
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Compound 56
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 57
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 58
Molecular Weight:261.762
Molecular Formula:C10H14CuO4
InChIKey:QYJPSWYYEKYVEJ-FDGPNNRMSA-L
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Compound 59
Molecular Weight:321.814
Molecular Formula:C12H18CuO6
InChIKey:OXIPIJDRMRFUKB-NVWHPRHESA-L
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Compound 60
Molecular Weight:305.773
Molecular Formula:C14H10CuO4
InChIKey:ITUFJMIZRRRYMT-UHFFFAOYSA-L
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Compound 61
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 62a
Molecular Weight:995.406
Molecular Formula:C27H24EuF21O6
InChIKey:CDRSZHOGXBSDMY-XQCJSWFGSA-K
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Compound 62b
Molecular Weight:617.607
Molecular Formula:C27H45EuO6
InChIKey:NWRBNGYQLMUNDR-YXKGCPEZSA-K
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Compound 62c
Molecular Weight:695.361
Molecular Formula:C21H24EuF9O6
InChIKey:ORYIMPWNUIOBSN-XQCJSWFGSA-K
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Compound 62
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 63
Molecular Weight:308.4589
Molecular Formula:C18H32N2O2
InChIKey:UVBOCFWIQKGGMH-IWGRKNQJSA-N
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Compound 64
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 65
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 66
Molecular Weight:370.3973
Molecular Formula:C24H18O4
InChIKey:IIJQXSWPACKCHL-UHFFFAOYSA-N
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Compound 67
Molecular Weight:568.572
Molecular Formula:C26H24N2Na2O6S2
InChIKey:MBZXAVMLVZKQQP-UHFFFAOYSA-L
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Compound 68
Molecular Weight:305.0941
Molecular Formula:C7H10NNaO7P2
InChIKey:DRFDPXKCEWYIAW-UHFFFAOYSA-M
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Compound 69
Molecular Weight:202.1386
Molecular Formula:C5KNaO5
InChIKey:YKCUPZNZKBPZOU-UHFFFAOYSA-L
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Compound 70
Molecular Weight:214.0401
Molecular Formula:C6Na2O6
InChIKey:SXWPCWBFJXDMAI-UHFFFAOYSA-L
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Compound 71
Molecular Weight:541.575
Molecular Formula:C20H19N3O9S3
InChIKey:WWVJUCNOSUHCFP-XYARLGNMSA-N
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Compound 72
Molecular Weight:803.963
Molecular Formula:C40H41N3O9S3
InChIKey:CUUOPPQUKDRNDK-UHFFFAOYSA-N
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Compound 73
Molecular Weight:695.999
Molecular Formula:C21H14Br4O5S
InChIKey:INBQSOALTMPZQK-GHRIWEEISA-L
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Compound 74
Molecular Weight:401.5858
Molecular Formula:C27H35N3
InChIKey:ZRJYQNPSWSGCMS-UHFFFAOYSA-N
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Compound 75
Molecular Weight:883.082
Molecular Formula:C46H48N3O9S3
InChIKey:VBXGMFWDJIQNSX-UHFFFAOYSA-O
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