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Silyl and Stannyl Derivatives of Organocopper Compounds

Organocopper Compounds (2009)

  1. Francisco J. Pulido,
  2. Asunción Barbero

Published Online: 17 JAN 2011

DOI: 10.1002/9780470682531.pat0449

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Pulido, F. J. and Barbero, A. 2011. Silyl and Stannyl Derivatives of Organocopper Compounds. Patai's Chemistry of Functional Groups. .

Author Information

  1. Universidad de Valladolid, Departamento de Química Orgánica, Facultad de Ciencias, Valladolid, Spain

Publication History

  1. Published Online: 17 JAN 2011

Abstract

  • 1
    Introduction
  • 2
    Silylcuprates
  • 3
    Stannylcuprates

Keywords:

  • silyl and stannyl derivatives of organocopper compounds;
  • organocuprate chemistry, emerging as fundamental topics in organic chemistry;
  • heteroatomcuprates containing Group IVA ligands;
  • silylcuprates - interest of silylcuprates - in high reactivity toward electrophiles;
  • structure of silylcuprates;
  • synthesis of allylsilanes from α,β-unsaturated esters;
  • success of cyclization - depending on relative reactivity of silylcuprate;
  • stannylcuprates - preparation of stannylcuprates