Standard Article

Structures and Reaction Mechanisms of Manganese Oxidants

Organomanganese Compounds (2011)

  1. Donald G. Lee

Published Online: 15 SEP 2010

DOI: 10.1002/9780470682531.pat0531

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Lee, D. G. 2010. Structures and Reaction Mechanisms of Manganese Oxidants. Patai's Chemistry of Functional Groups. .

Author Information

  1. University of Regina, Department of Chemistry and Biochemistry, Regina, SK, Canada

Publication History

  1. Published Online: 15 SEP 2010

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Abstract

The chemistry of manganese based oxidants (permanganate, manganese dioxide, manganese(III) acetate and manganese(V) complexes) is reviewed. Possible mechanisms for the reactions between manganese based oxidants and organic compounds are described and the evidence, both experimental and theoretical, on which the proposed mechanisms are based is presented. Special emphasis is placed on identification of the structures of the transition states and reactive intermediates that are formed as these reactions proceed.

Keywords:

  • Oxidant;
  • Permanganate;
  • Manganese dioxide;
  • Manganese(III) acetate;
  • Manganese(V) salen;
  • Manganese(V) porphyrin

Featured Compounds

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  1. 1 - 152
Compound 1
Molecular Weight:422.3493
Molecular Formula:C12H24KMnO10
InChIKey:YNBLTBZQIZYPPH-UHFFFAOYSA-N
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Compound 2
Molecular Weight:482.4013
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 5
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 120
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 6
Molecular Weight:120.9521
Molecular Formula:H3MnO4
InChIKey:VTINEGZUBCMJDR-UHFFFAOYSA-L
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Compound 3
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 12
Molecular Weight:68.117
Molecular Formula:C5H8
InChIKey:LPIQUOYDBNQMRZ-UHFFFAOYSA-N
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Compound 13
Molecular Weight:102.1317
Molecular Formula:C5H10O2
InChIKey:VCVOSERVUCJNPR-SYDPRGILSA-N
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Compound 14
Molecular Weight:116.0722
Molecular Formula:C4H4O4
InChIKey:VZCYOOQTPOCHFL-UPHRSURJSA-N
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Compound 15
Molecular Weight:150.0868
Molecular Formula:C4H6O6
InChIKey:FEWJPZIEWOKRBE-XIXRPRMCSA-N
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Compound 16
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 17
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 18
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 19
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 20
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 21
Molecular Weight:104.9521
Molecular Formula:H2MnO3
InChIKey:LZMCUTZPLPUFMB-UHFFFAOYSA-L
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Compound 22
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 24
Molecular Weight:88.9527
Molecular Formula:H2MnO2
InChIKey:IPJKJLXEVHOKSE-UHFFFAOYSA-L
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Compound 138
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 27
Molecular Weight:148.1586
Molecular Formula:C9H8O2
InChIKey:WBYWAXJHAXSJNI-VOTSOKGWSA-N
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Compound 32
Molecular Weight:162.1852
Molecular Formula:C10H10O2
InChIKey:CCRCUPLGCSFEDV-BQYQJAHWSA-N
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Compound 53
Molecular Weight:162.1852
Molecular Formula:C10H10O2
InChIKey:CCRCUPLGCSFEDV-BQYQJAHWSA-N
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Compound 25
Molecular Weight:282.4614
Molecular Formula:C18H34O2
InChIKey:ZQPPMHVWECSIRJ-KTKRTIGZSA-N
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Compound 26
Molecular Weight:320.4756
Molecular Formula:C18H36O4
InChIKey:VACHUYIREGFMSP-UHFFFAOYSA-N
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Compound 36
Molecular Weight:132.2023
Molecular Formula:C10H12
InChIKey:HECLRDQVFMWTQS-AFWXGSBKSA-N
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Compound 35
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 30
Molecular Weight:106.1219
Molecular Formula:C7H6O
InChIKey:HUMNYLRZRPPJDN-UHFFFAOYSA-N
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Compound 93
Molecular Weight:106.1219
Molecular Formula:C7H6O
InChIKey:HUMNYLRZRPPJDN-UHFFFAOYSA-N
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Compound 133
Molecular Weight:106.1219
Molecular Formula:C7H6O
InChIKey:HUMNYLRZRPPJDN-UHFFFAOYSA-N
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Compound 31
Molecular Weight:74.0355
Molecular Formula:C2H2O3
InChIKey:Not Available
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Compound 34
Molecular Weight:491.4318
Molecular Formula:C23H31FMnNO6
InChIKey:ZFNAJQWODLXIQK-UHFFFAOYSA-N
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Compound 39
Molecular Weight:166.217
Molecular Formula:C10H14O2
InChIKey:BRLVNMUMYFAMGL-BQKDNTBBSA-N
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Compound 38
Molecular Weight:166.217
Molecular Formula:C10H14O2
InChIKey:LTUWXBXVKKDINJ-GOHJYUCNSA-N
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Compound 40
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 42
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 43
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 46
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 48
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 49
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 51
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 52
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 56
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 57
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 58
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 59
Molecular Weight:280.4455
Molecular Formula:C18H32O2
InChIKey:RGTIBVZDHOMOKC-UHFFFAOYSA-N
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Compound 60
Molecular Weight:312.4443
Molecular Formula:C18H32O4
InChIKey:UCJSYDRGZVWHJS-UHFFFAOYSA-N
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Compound 62
Molecular Weight:254.4082
Molecular Formula:C16H30O2
InChIKey:CWRWTVQQOXCDEU-UHFFFAOYSA-N
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Compound 61
Molecular Weight:222.4094
Molecular Formula:C16H30
InChIKey:YSDKMBBHKZXPME-UHFFFAOYSA-N
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Compound 64
Molecular Weight:88.1051
Molecular Formula:C4H8O2
InChIKey:FERIUCNNQQJTOY-UHFFFAOYSA-N
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Compound 65
Molecular Weight:73.0706
Molecular Formula:C3H6O2
InChIKey:XBDQKXXYIPTUBI-UHFFFAOYSA-M
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Compound 63
Molecular Weight:142.1956
Molecular Formula:C8H14O2
InChIKey:XYZAPOXYXNIBEU-UHFFFAOYSA-N
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Compound 66
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 68
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 69
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 70
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 73
Molecular Weight:230.325
Molecular Formula:C14H14OS
InChIKey:FAWFBIHSPIZYHU-UHFFFAOYSA-N
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Compound 74
Molecular Weight:230.325
Molecular Formula:C14H14OS
InChIKey:FAWFBIHSPIZYHU-UHFFFAOYSA-O
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Compound 75
Molecular Weight:122.1644
Molecular Formula:C8H10O
InChIKey:CHLICZRVGGXEOD-UHFFFAOYSA-N
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Compound 76
Molecular Weight:218.338
Molecular Formula:C12H10S2
InChIKey:Not Available
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Compound 112
Molecular Weight:218.338
Molecular Formula:C12H10S2
InChIKey:Not Available
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Compound 77
Molecular Weight:138.1638
Molecular Formula:C8H10O2
InChIKey:MSHFRERJPWKJFX-UHFFFAOYSA-N
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Compound 78
Molecular Weight:180.2005
Molecular Formula:C10H12O3
InChIKey:HFNGYHHRRMSKEU-UHFFFAOYSA-N
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Compound 144
Molecular Weight:122.1644
Molecular Formula:C8H10O
InChIKey:CHLICZRVGGXEOD-UHFFFAOYSA-N
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Compound 79
Molecular Weight:262.324
Molecular Formula:C14H14O3S
InChIKey:MSYOECFLRPQTSV-UHFFFAOYSA-N
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Compound 86
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 87
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 88
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 123
Molecular Weight:138.1638
Molecular Formula:C8H10O2
InChIKey:MSHFRERJPWKJFX-UHFFFAOYSA-N
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Compound 89
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 90
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 91
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 92
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 94
Molecular Weight:124.1211
Molecular Formula:C7H6O2
InChIKey:WPYMKLBDIGXBTP-UHFFFAOYSA-N
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Compound 95
Molecular Weight:124.1372
Molecular Formula:C7H8O2
InChIKey:SNGARVZXPNQWEY-UHFFFAOYSA-N
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Compound 96
Molecular Weight:124.1372
Molecular Formula:C7H8O2
InChIKey:SNGARVZXPNQWEY-UHFFFAOYSA-N
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Compound 97
Molecular Weight:124.1372
Molecular Formula:C7H8O2
InChIKey:SNGARVZXPNQWEY-UHFFFAOYSA-N
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Compound 99
Molecular Weight:128.212
Molecular Formula:C8H16O
InChIKey:VSMOENVRRABVKN-UHFFFAOYSA-N
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Compound 100
Molecular Weight:126.1962
Molecular Formula:C8H14O
InChIKey:KLTVSWGXIAYTHO-UHFFFAOYSA-N
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Compound 108
Molecular Weight:148.2017
Molecular Formula:C10H12O
InChIKey:ZIJWGEHOVHJHKB-BQYQJAHWSA-N
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Compound 113
Molecular Weight:90.187
Molecular Formula:C4H10S
InChIKey:Not Available
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Compound 114
Molecular Weight:178.359
Molecular Formula:C8H18S2
InChIKey:CUDSBWGCGSUXDB-UHFFFAOYSA-N
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Compound 104
Molecular Weight:82.1436
Molecular Formula:C6H10
InChIKey:HGCIXCUEYOPUTN-UHFFFAOYSA-N
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Compound 103
Molecular Weight:98.143
Molecular Formula:C6H10O
InChIKey:Not Available
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Compound 102
Molecular Weight:100.1589
Molecular Formula:C6H12O
InChIKey:Not Available
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Compound 105
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 106
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 107
Molecular Weight:100.1589
Molecular Formula:C6H12O
InChIKey:Not Available
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Compound 110
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 109
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 111
Molecular Weight:110.177
Molecular Formula:C6H6S
InChIKey:RMVRSNDYEFQCLF-UHFFFAOYSA-N
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Compound 116
Molecular Weight:120.236
Molecular Formula:C4H8S2
InChIKey:Not Available
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Compound 115
Molecular Weight:122.252
Molecular Formula:C4H10S2
InChIKey:SMTOKHQOVJRXLK-UHFFFAOYSA-N
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Compound 117
Molecular Weight:170.295
Molecular Formula:C8H10S2
InChIKey:IYPNRTQAOXLCQW-UHFFFAOYSA-N
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Compound 118
Molecular Weight:674.124
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 119
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 121
Molecular Weight:88.1482
Molecular Formula:C5H12O
InChIKey:AMQJEAYHLZJPGS-UHFFFAOYSA-N
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Compound 122
Molecular Weight:86.1323
Molecular Formula:C5H10O
InChIKey:HGBOYTHUEUWSSQ-UHFFFAOYSA-N
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Compound 124
Molecular Weight:136.1479
Molecular Formula:C8H8O2
InChIKey:ZRSNZINYAWTAHE-UHFFFAOYSA-N
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Compound 125
Molecular Weight:220.3828
Molecular Formula:C13H20OSi
InChIKey:WMERTRBKZZLRDC-UHFFFAOYSA-N
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Compound 126
Molecular Weight:180.2005
Molecular Formula:C10H12O3
InChIKey:QBXPWENAGCUSPV-UHFFFAOYSA-N
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Compound 127
Molecular Weight:164.2011
Molecular Formula:C10H12O2
InChIKey:GAOQAPRPYXWTFK-UHFFFAOYSA-N
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Compound 128
Molecular Weight:121.1366
Molecular Formula:C7H7NO
InChIKey:Not Available
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Compound 129
Molecular Weight:177.2031
Molecular Formula:C9H11N3O
InChIKey:CPXYGYOMIMOSCX-XFFZJAGNSA-N
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Compound 130
Molecular Weight:296.8411
Molecular Formula:H4Mn3O8
InChIKey:MCUKRGNDQRLDGM-UHFFFAOYSA-J
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Compound 131
Molecular Weight:109.144
Molecular Formula:C7H8O
InChIKey:Not Available
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Compound 132
Molecular Weight:107.1281
Molecular Formula:C7H6O
InChIKey:Not Available
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Compound 134
Molecular Weight:144.1684
Molecular Formula:C7H12O3
InChIKey:HFFPGANQUSYUNI-BQBZGAKWSA-N
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Compound 135
Molecular Weight:142.1525
Molecular Formula:C7H10O3
InChIKey:YFWBNHSYXGFXLE-ZETCQYMHSA-N
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Compound 136
Molecular Weight:144.1684
Molecular Formula:C7H12O3
InChIKey:HFFPGANQUSYUNI-NKWVEPMBSA-N
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Compound 137
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 139
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 140
Molecular Weight:535.0771
Molecular Formula:C12H18Mn3O13
InChIKey:NFSYFMDZRLRSPT-UHFFFAOYSA-H
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Compound 142
Molecular Weight:234.086
Molecular Formula:C6H11MnO6
InChIKey:IQPJTQDYVJUKPT-UHFFFAOYSA-N
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Compound 143
Molecular Weight:121.1565
Molecular Formula:C8H9O
InChIKey:CHLICZRVGGXEOD-UHFFFAOYSA-N
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Compound 145
Molecular Weight:180.2005
Molecular Formula:C10H12O3
InChIKey:HFNGYHHRRMSKEU-UHFFFAOYSA-N
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Compound 146
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 147
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 148
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 149
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 150
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 151
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 152
Molecular Weight:104.1491
Molecular Formula:C8H8
InChIKey:PPBRXRYQALVLMV-UHFFFAOYSA-N
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Compound 153
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 154
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 155
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 156
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 157
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 158
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 159
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 160
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 161
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 162
Molecular Weight:310.352
Molecular Formula:C20H14N4
InChIKey:RKCAIXNGYQCCAL-DRVLFLLISA-N
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Compound 164
Molecular Weight:268.3104
Molecular Formula:C16H16N2O2
InChIKey:Not Available
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Compound 163
Molecular Weight:363.2741
Molecular Formula:C20H12MnN4
InChIKey:SHGAIWMPHRJNOD-QDJBTJTOSA-N
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Compound 165
Molecular Weight:321.2326
Molecular Formula:C16H14MnN2O2
InChIKey:NTVWCXCBGJMISE-OYJDLGDISA-L
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Compound 166
Molecular Weight:363.2736
Molecular Formula:C20H12MnN4
InChIKey:MHFJBFLQEVEQAF-QDJBTJTOSA-N
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Compound 167
Molecular Weight:321.2321
Molecular Formula:C16H14MnN2O2
InChIKey:ZTVLCLVMEVOQRI-OYJDLGDISA-L
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Compound 168
Molecular Weight:172.566
Molecular Formula:C7H5ClO3
InChIKey:NHQDETIJWKXCTC-UHFFFAOYSA-N
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Compound 170
Molecular Weight:220.0078
Molecular Formula:C6H5IO
InChIKey:Not Available
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Compound 169
Molecular Weight:379.273
Molecular Formula:C20H12MnN4O
InChIKey:YQJRSQLTYWMEBZ-IAULSPAKSA-N
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Compound 171
Molecular Weight:337.2315
Molecular Formula:C16H14MnN2O3
InChIKey:PTMBMVSDKBOVMU-SNTCFBDDSA-L
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Compound 172
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 173
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 174
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 175
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 176
Molecular Weight:411.2272
Molecular Formula:C16H12MnN4O6
InChIKey:JSADYVQWXFMCSQ-MQMNHWTGSA-L
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Compound 177
Molecular Weight:118.1757
Molecular Formula:C9H10
InChIKey:QROGIFZRVHSFLM-KXFIGUGUSA-N
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Compound 178
Molecular Weight:134.1751
Molecular Formula:C9H10O
InChIKey:YVCOJTATJWDGEU-VXNVDRBHSA-N
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Compound 179
Molecular Weight:134.1751
Molecular Formula:C9H10O
InChIKey:YVCOJTATJWDGEU-APPZFPTMSA-N
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Compound 181
Molecular Weight:176.2118
Molecular Formula:C11H12O2
InChIKey:Not Available
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Compound 180
Molecular Weight:635.201
Molecular Formula:C36H52ClMnN2O2
InChIKey:LJVAWOSDJSQANR-OHRASPNLSA-K
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Compound 182
Molecular Weight:192.2112
Molecular Formula:C11H12O3
InChIKey:GOMAKLPNAAZVCJ-UWVGGRQHSA-N
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