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Energetics of Organomanganese Compounds

Organomanganese Compounds (2011)

  1. Joel F. Liebman1,
  2. Suzanne W. Slayden2

Published Online: 15 FEB 2011

DOI: 10.1002/9780470682531.pat0533

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Liebman, J. F. and Slayden, S. W. 2011. Energetics of Organomanganese Compounds. Patai's Chemistry of Functional Groups.

Author Information

  1. 1

    University of Maryland, Department of Chemistry and Biochemistry, Baltimore, Maryland, USA

  2. 2

    Department of Chemistry George Mason University, Fairfax, Virginia, USA

Publication History

  1. Published Online: 15 FEB 2011

Abstract

Diverse aspects of the energetics of organomanganese compounds are considered in this chapter. Bond energies, enthalpies of formation and enthalpies of reaction are discussed. Classical combustion calorimetry plays only a small role compared to reaction calorimetry and techniques from contemporary ion energetics. While carbonyl, cyano, cyclopentadienyl, and benzene derivatives dominate the discussion, species with numerous other σ and/or π-bonded ligands also appear. Quantitation is given whenever possible.

Keywords:

  • benzene and phenyl derivatives;
  • bond energy;
  • calorimetry;
  • carbonyls;
  • cyclopentadienyl (cyclopentadienide);
  • cyano derivatives;
  • cymantrene;
  • enthalpy of formation;
  • homoleptic;
  • ion energetics;
  • ligands;
  • manganese tricarbonyl derivatives;
  • manganocene