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Energetics of Organomanganese Compounds

Organomanganese Compounds (2011)

  1. Joel F. Liebman1,
  2. Suzanne W. Slayden2

Published Online: 15 FEB 2011

DOI: 10.1002/9780470682531.pat0533

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Liebman, J. F. and Slayden, S. W. 2011. Energetics of Organomanganese Compounds. Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    University of Maryland, Department of Chemistry and Biochemistry, Baltimore, Maryland, USA

  2. 2

    Department of Chemistry George Mason University, Fairfax, Virginia, USA

Publication History

  1. Published Online: 15 FEB 2011

Abstract

Diverse aspects of the energetics of organomanganese compounds are considered in this chapter. Bond energies, enthalpies of formation and enthalpies of reaction are discussed. Classical combustion calorimetry plays only a small role compared to reaction calorimetry and techniques from contemporary ion energetics. While carbonyl, cyano, cyclopentadienyl, and benzene derivatives dominate the discussion, species with numerous other σ and/or π-bonded ligands also appear. Quantitation is given whenever possible.

Keywords:

  • benzene and phenyl derivatives;
  • bond energy;
  • calorimetry;
  • carbonyls;
  • cyclopentadienyl (cyclopentadienide);
  • cyano derivatives;
  • cymantrene;
  • enthalpy of formation;
  • homoleptic;
  • ion energetics;
  • ligands;
  • manganese tricarbonyl derivatives;
  • manganocene

Featured Compounds

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  1. 1 - 29
Compound 1
Molecular Weight:185.1244
Molecular Formula:C10H10Mn
InChIKey:BENYMRWARBDAQB-UHFFFAOYSA-N
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Compound 2
Molecular Weight:204.0615
Molecular Formula:C8H5MnO3
InChIKey:OWUDJNGZBGIAFN-UHFFFAOYSA-N
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Compound 3
Molecular Weight:503.9592
Molecular Formula:C12H3Mn3O12
InChIKey:OCWLFXIGUYHJQQ-UHFFFAOYSA-N
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Compound 4
Molecular Weight:670.9381
Molecular Formula:C16H3Mn4O16
InChIKey:GLASZDRSDLKKDV-UHFFFAOYSA-N
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Compound 5
Molecular Weight:476.717
Molecular Formula:C6H3AlBr3MnO5
InChIKey:FQUSUZJBUFLRFT-UHFFFAOYSA-K
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Compound 6
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 7
Molecular Weight:539.438
Molecular Formula:C22H29MnO8PS
InChIKey:QOPZHWBANSRHSJ-UHFFFAOYSA-N
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Compound 8
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 9
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 10
Molecular Weight:941.5198
Molecular Formula:C52H94Mn2Si4
InChIKey:VXOUVJVRPRFKOO-UHFFFAOYSA-N
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Compound 11
Molecular Weight:287.2577
Molecular Formula:C18H16Mn
InChIKey:CHZVYDBQMSKYKH-UHFFFAOYSA-N
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Compound 12
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 13
Molecular Weight:Not Available
Molecular Formula:(CH2)nC10H17MnOP2
InChIKey:YVRNJZFKEYXNFV-UHFFFAOYSA-N
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Compound 14
Molecular Weight:Not Available
Molecular Formula:(CH2)nC9H7MnO3S
InChIKey:WSVZHVDLVWPIRY-UHFFFAOYSA-N
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Compound 15
Molecular Weight:Not Available
Molecular Formula:(CH2)nC9H7MnO4
InChIKey:JUJBCSCSQIMDCH-UHFFFAOYSA-N
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Compound 16a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 16b
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 17
Molecular Weight:418.2917
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 18
Molecular Weight:879.916
Molecular Formula:C54H66Mn3
InChIKey:AUSTYNXPQYGICQ-UHFFFAOYSA-N
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Compound 19
Molecular Weight:406.1072
Molecular Formula:C16H8Mn2O6
InChIKey:CTSQWDJVKGWZIS-UHFFFAOYSA-N
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Compound 20
Molecular Weight:406.1072
Molecular Formula:C16H8Mn2O6
InChIKey:MROOGVGLLLGNHR-UHFFFAOYSA-N
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Compound 21
Molecular Weight:406.1072
Molecular Formula:C16H8Mn2O6
InChIKey:TWCQTXXMOQLPII-UHFFFAOYSA-N
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Compound 22
Molecular Weight:382.0858
Molecular Formula:C14H8Mn2O6
InChIKey:GIFQGNPVBUDURI-XCSAYFGZSA-N
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Compound 23
Molecular Weight:385.3586
Molecular Formula:C26H18Mn
InChIKey:HPSLJSHETRESKA-UHFFFAOYSA-N
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Compound 24a
Molecular Weight:432.2306
Molecular Formula:C20H18Mn2O4
InChIKey:GSLKQUUTJQVNPO-UHFFFAOYSA-N
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Compound 24b
Molecular Weight:432.2306
Molecular Formula:C20H18Mn2O4
InChIKey:GSLKQUUTJQVNPO-UHFFFAOYSA-N
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Compound 25
Molecular Weight:165.1343
Molecular Formula:C8H13Mn
InChIKey:SRRKICGMSSAMCT-UHFFFAOYSA-N
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Compound 26
Molecular Weight:252.0962
Molecular Formula:C10H7F2MnO2
InChIKey:DLZCSZKTSHKDIZ-UHFFFAOYSA-N
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Compound 27
Molecular Weight:580.1283
Molecular Formula:C18H10F12Mn2O
InChIKey:FCNVQFZVBUXWFI-BTCYBTQLSA-N
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