Catalytic Enantioselective Reactions using Organomanganese Compounds
Published Online: 15 JUN 2011
Copyright © 2009 John Wiley & Sons, Ltd. All rights reserved.
Patai's Chemistry of Functional Groups
How to Cite
Chinkov, N. 2011. Catalytic Enantioselective Reactions using Organomanganese Compounds. Patai's Chemistry of Functional Groups.
- Published Online: 15 JUN 2011
The use of organomanganese reagents in asymmetric catalysis represents an attractive niche for synthetic chemists mainly due to the toxicological benignancy and low cost.
Yet, the arsenal of the existing organomanganese catalysts, processes and substrates used in the enantioselective reactions is quite limited. This chapter covers the chief achievements made within the last quarter of a century in this area. The majority of the transformations are made by the Mn
Keywords: Chiral manganese(salen); Jacobsen epoxidation; Katsuki epoxidation; asymmetric sulfoxidation; chiral manganese(porphyrin); asymmetric oxidation; asymmetric amidation