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Thermochemistry of Organoselenium and Organotellurium Compounds

Organic Selenium and Tellurium Compounds (2012)

  1. Joel F. Liebman1,
  2. Suzanne W. Slayden2

Published Online: 15 DEC 2011

DOI: 10.1002/9780470682531.pat0563

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Liebman, J. F. and Slayden, S. W. 2011. Thermochemistry of Organoselenium and Organotellurium Compounds. Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    University of Maryland Baltimore County (UMBC), Department of Chemistry and Biochemistry, Baltimore, USA

  2. 2

    George Mason University, Department of Chemistry, Fairfax, USA

Publication History

  1. Published Online: 15 DEC 2011

Abstract

The current study deals with the thermochemistry of organoselenium and organotellurium compounds in which we focus on the enthalpy of formation, with additional mention of other quantities such as Gibbs free energy, chemical equilibria and bond energies. The chapter starts with a discussion of the energetics of binary carbon selenides and tellurides and related ternary species, proceeds to aliphatic selenides and tellurides, then the oxygen-containing selenoxides, selenones, telluroxides, tellurones, selenenates and tellurenates, and concludes with aronmatic selenides and tellurides including aryl selenides, selenophenes and tellurium counterparts.

Keywords:

  • organoselenium compounds;
  • organotellurium compounds;
  • thermochemistry;
  • enthalpy of formation;
  • enthalpy of combustion;
  • enthalpy of reaction;
  • enthalpy of vaporization and sublimation;
  • Gibbs free energy and chemical equilibria;
  • bond energies;
  • homologous series;
  • methylene increment