Standard Article

Biological and Biochemical Aspects of Tellurium Derivatives

Organic Selenium and Tellurium Compounds (2012)

  1. Michael R. Detty

Published Online: 15 APR 2011

DOI: 10.1002/9780470682531.pat0574

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Detty, M. R. 2011. Biological and Biochemical Aspects of Tellurium Derivatives. Patai's Chemistry of Functional Groups. .

Author Information

  1. Department of Chemistry, University at Buffalo, NY, USA

Publication History

  1. Published Online: 15 APR 2011

Chemistry Terms

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Abstract

Biological and biochemical studies of inorganic and organic complexes of tellurium are reviewed. Subject areas include the biosequestration and bioincorporation of tellurite and other inorganic tellurium compounds as well as tellurite-resistant bacteria. The incorporation of tellurium into amino acids (tellurocysteine) and the formation of unnatural glutathione peroxidases and thioredoxin reductases incorporating tellurocysteine are also described. Low molecular weight organotellurium compounds that mimic glutathione peroxidase and the thioredoxin reductases are discussed as are inorganic and organic tellurium compounds that inhibit cysteine proteases and related enzymes. The interactions of P-glycoprotein with organotellurium compounds to give stimulators and inhibitors of ATPase activity in the enzyme are described. The role of tellurium-containing chromophores in the photodynamic therapy of cancer and the photodynamic inactivation of viral and bacterial pathogens is also reviewed. The binding modes of tellurium-containing chromophores to DNA are also described.

Keywords:

  • tellurite;
  • organotellurides;
  • diorgano ditellurides;
  • inorganic tellurium complexes;
  • glutathione peroxidase;
  • thioredoxin reductase;
  • tellurocysteine;
  • P-glycoprotein;
  • photodynamic therapy;
  • anti-microbial activity

Featured Compounds

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  1. 1 - 109
Compound As-101
Molecular Weight:312
Molecular Formula:C2H8Cl3NO2Te
InChIKey:AXWLPMGUUAIGJK-UHFFFAOYSA-O
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Compound SAS
Molecular Weight:547.3
Molecular Formula:C8H4O12Te2
InChIKey:PFFMVNCHHFWTSD-UHFFFAOYSA-N
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Compound 1
Molecular Weight:633.7
Molecular Formula:C29H43ClSeTe
InChIKey:OYAPCCVHGRIPDU-UHFFFAOYSA-M
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Compound 2
Molecular Weight:667.7
Molecular Formula:C29H45ClO2SeTe
InChIKey:MJVPVPMZZUZLMC-UHFFFAOYSA-N
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Compound 3
Molecular Weight:313.8
Molecular Formula:C12H10O2Te
InChIKey:KNEWDCWTYCKNKS-UHFFFAOYSA-N
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Compound 4
Molecular Weight:367.9
Molecular Formula:C16H20N2Te
InChIKey:VOLJXUIKBLWFPA-UHFFFAOYSA-N
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Compound 5
Molecular Weight:369.9
Molecular Formula:C16H18O2Te
InChIKey:IYLWETOBQLJKCS-UHFFFAOYSA-N
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Compound 6
Molecular Weight:369.8
Molecular Formula:C14H10O4Te
InChIKey:OWCNQWSTAVOKGI-UHFFFAOYSA-N
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Compound 7
Molecular Weight:353.9
Molecular Formula:C12H18O4Te
InChIKey:MRFNXODMGFSHIO-UHFFFAOYSA-N
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Compound Se1
Molecular Weight:293.22
Molecular Formula:C14H14O2Se
InChIKey:YAHBTUUYGUSGKS-UHFFFAOYSA-N
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Compound Te1
Molecular Weight:271.9
Molecular Formula:C9H20OTe
InChIKey:UOJRBVLWDPXRRM-UHFFFAOYSA-N
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Compound 16-Te
Molecular Weight:247.7
Molecular Formula:C8H8OTe
InChIKey:BXNGCJSMSNAJKD-UHFFFAOYSA-N
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Compound 17-Te
Molecular Weight:484
Molecular Formula:C20H24N2O4Te
InChIKey:SKUHFYRTEXVRRF-UHFFFAOYSA-N
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Compound 18-Te
Molecular Weight:656.2
Molecular Formula:C28H36N2O8Te
InChIKey:VLANJAYJEKZDBH-UHFFFAOYSA-N
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Compound 19-Te
Molecular Weight:527.1
Molecular Formula:C23H29NO5Te
InChIKey:XQKMMNVYMKVMAR-UHFFFAOYSA-N
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Compound 20-Te
Molecular Weight:541.1
Molecular Formula:C24H31NO5Te
InChIKey:UTPVVFFQSCACRM-UHFFFAOYSA-N
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Compound 21-Te
Molecular Weight:Not Available
Molecular Formula:(CH2)nC16H17NO3Te
InChIKey:KNEMVOFCKZZMAY-UHFFFAOYSA-N
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Compound 22-Te
Molecular Weight:531
Molecular Formula:C21H25NO7Te
InChIKey:PHESSWSFRSFFPG-UHFFFAOYSA-N
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Compound 23-Te
Molecular Weight:545.1
Molecular Formula:C22H27NO7Te
InChIKey:MFMGZZVCUWYIJI-UHFFFAOYSA-N
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Compound 24-Te
Molecular Weight:413.9
Molecular Formula:C17H18O4Te
InChIKey:ZKSRZAUDFPSQFE-UHFFFAOYSA-N
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Compound 25-Te
Molecular Weight:313.8
Molecular Formula:C12H10O2Te
InChIKey:KNEWDCWTYCKNKS-UHFFFAOYSA-N
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Compound 26-Se
Molecular Weight:233.17
Molecular Formula:C12H10Se
InChIKey:Not Available
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Compound 26-Te
Molecular Weight:281.8
Molecular Formula:C12H10Te
InChIKey:XTCBHFKSTRGVMZ-UHFFFAOYSA-N
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Compound 16-O
Molecular Weight:136.1479
Molecular Formula:C8H8O2
InChIKey:JNYKOGUXPNAUIB-UHFFFAOYSA-N
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Compound 16-S
Molecular Weight:152.214
Molecular Formula:C8H8OS
InChIKey:ZYMXZSZJIUOWDL-UHFFFAOYSA-N
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Compound 16-Se
Molecular Weight:199.11
Molecular Formula:C8H8OSe
InChIKey:KUGBTJVRWXUGMO-UHFFFAOYSA-N
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Compound 27-Te
Molecular Weight:469.5
Molecular Formula:C14H14O2Te2
InChIKey:YYFGVTIQGPAGRR-UHFFFAOYSA-N
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Compound 28-Te
Molecular Weight:525.5
Molecular Formula:C16H14O4Te2
InChIKey:KPXKIALHJWLVOT-UHFFFAOYSA-N
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Compound 29-Te
Molecular Weight:516.8
Molecular Formula:C16H25Cl4NOTe
InChIKey:XELDEQDMQFYTQU-UHFFFAOYSA-N
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Compound 30-Te
Molecular Weight:425.2
Molecular Formula:C12H15Cl3O2Te
InChIKey:QFIIGWPAUHZVQA-FLIBITNWSA-N
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Compound 31-Te
Molecular Weight:517.7
Molecular Formula:C15H18Br2O2Te
InChIKey:DEWVODGYQJTLFX-SDNWHVSQSA-N
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Compound 32-Te
Molecular Weight:442.8
Molecular Formula:C16H20Cl2O2Te
InChIKey:CXUAIRCRSBMHIB-NTCAYCPXSA-N
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Compound 33-Te
Molecular Weight:443.2
Molecular Formula:C15H13Cl3OTe
InChIKey:WEICXSZZQHJPHD-PTNGSMBKSA-N
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Compound 34-Te
Molecular Weight:515.3
Molecular Formula:C18H17Cl3O3Te
InChIKey:ZTRQWQFZNFEISA-ACCUITESSA-N
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Compound 35-Te
Molecular Weight:401.6
Molecular Formula:C9H8Cl4OTe
InChIKey:VBTGXIWQPCNFPY-SOFGYWHQSA-N
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Compound RT-03
Molecular Weight:428.8
Molecular Formula:C15H18Cl2O2Te
InChIKey:OCCZRIQZJSXKQT-SDNWHVSQSA-N
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Compound RT-04
Molecular Weight:425.2
Molecular Formula:C12H15Cl3O2Te
InChIKey:QFIIGWPAUHZVQA-DHZHZOJOSA-N
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Compound QZ59-RRR
Molecular Weight:687.41
Molecular Formula:C24H30N6O3Se3
InChIKey:FWRNUSMIPQTUHH-KZNAEPCWSA-N
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Compound QZ59-SSS
Molecular Weight:687.41
Molecular Formula:C24H30N6O3Se3
InChIKey:FWRNUSMIPQTUHH-BZSNNMDCSA-N
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Compound TeRh II
Molecular Weight:644
Molecular Formula:C24H23F6N2O2PTe
InChIKey:HVWIRWKBBUOCOH-UHFFFAOYSA-O
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Compound 36-S
Molecular Weight:556.546
Molecular Formula:C27H27F6N2PS
InChIKey:XWOCGHDAQHRVDY-UHFFFAOYSA-N
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Compound 36-Se
Molecular Weight:603.44
Molecular Formula:C27H27F6N2PSe
InChIKey:PRBLWUOKOUWPIK-UHFFFAOYSA-N
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Compound 36-Te
Molecular Weight:652.1
Molecular Formula:C27H27F6N2PTe
InChIKey:AHKAYRWYAVDBRL-UHFFFAOYSA-N
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Compound 37-S
Molecular Weight:554.509
Molecular Formula:C22H21F6N2O2PS2
InChIKey:QEJHNXPWAUWWMS-UHFFFAOYSA-O
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Compound 37-Se
Molecular Weight:601.4
Molecular Formula:C22H21F6N2O2PSSe
InChIKey:KSGLVFDCJFCWAS-UHFFFAOYSA-O
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Compound 37-Te
Molecular Weight:650
Molecular Formula:C22H21F6N2O2PSTe
InChIKey:FXSNNCDERHXFHG-UHFFFAOYSA-O
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Compound 38-S
Molecular Weight:637.706
Molecular Formula:C27H30F6N3PS3
InChIKey:UAVJUXXEJQFNHX-UHFFFAOYSA-N
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Compound 38-Se
Molecular Weight:684.6
Molecular Formula:C27H30F6N3PS2Se
InChIKey:VPXVXPPISIVAAN-UHFFFAOYSA-N
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Compound 38-Te
Molecular Weight:733.2
Molecular Formula:C27H30F6N3PS2Te
InChIKey:IOCJYOXGIMRLID-UHFFFAOYSA-N
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Compound 39-S
Molecular Weight:689.781
Molecular Formula:C31H34F6N3PS3
InChIKey:CZYFVOCRWZBMIO-UHFFFAOYSA-N
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Compound 39-Se
Molecular Weight:736.68
Molecular Formula:C31H34F6N3PS2Se
InChIKey:CKGDIGTWEFOYNC-UHFFFAOYSA-N
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Compound 39-Te
Molecular Weight:785.3
Molecular Formula:C31H34F6N3PS2Te
InChIKey:AEJHCSRJKTXHEK-UHFFFAOYSA-N
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Compound 40-S
Molecular Weight:691.754
Molecular Formula:C30H32F6N3OPS3
InChIKey:QEZFAPAVLYOTLD-UHFFFAOYSA-N
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Compound 40-Se
Molecular Weight:738.65
Molecular Formula:C30H32F6N3OPS2Se
InChIKey:NEGYIBYUVJZDAO-UHFFFAOYSA-N
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Compound TMR
Molecular Weight:423.346
Molecular Formula:C23H23BrN2O
InChIKey:VLBFZJOTEMBOEV-UHFFFAOYSA-M
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Compound TMR-S
Molecular Weight:439.411
Molecular Formula:C23H23BrN2S
InChIKey:NJMIZUBBCHUZCR-UHFFFAOYSA-M
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Compound TMR-Se
Molecular Weight:486.31
Molecular Formula:C23H23BrN2Se
InChIKey:JRHYJIYFOWKMHM-UHFFFAOYSA-M
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Compound TMR-Te
Molecular Weight:534.9
Molecular Formula:C23H23BrN2Te
InChIKey:OBCWVKXUZWKYGY-UHFFFAOYSA-M
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Compound 41-S
Molecular Weight:518.497
Molecular Formula:C25H31IN2S
InChIKey:BSUVCJIQGAEYOX-UHFFFAOYSA-M
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Compound 42-S
Molecular Weight:528.493
Molecular Formula:C25H23F6N2PS
InChIKey:AIDKFRHIRZLPMM-UHFFFAOYSA-N
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Compound 43-S
Molecular Weight:598.626
Molecular Formula:C30H33F6N2PS
InChIKey:MXUJBCDWGVPANJ-UHFFFAOYSA-N
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Compound 43-Te
Molecular Weight:694.2
Molecular Formula:C30H33F6N2PTe
InChIKey:LTNHIRUWRZANNW-UHFFFAOYSA-N
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Compound 44-Te
Molecular Weight:531.517
Molecular Formula:C25H26F6N2PS
InChIKey:QQNOVZIJPNJTQB-UHFFFAOYSA-N
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Compound 41-Se
Molecular Weight:565.39
Molecular Formula:C25H31IN2Se
InChIKey:QSFOWNDQBNXZKY-UHFFFAOYSA-M
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Compound 42-Se
Molecular Weight:575.39
Molecular Formula:C25H23F6N2PSe
InChIKey:NFJXECSRYOGMKA-UHFFFAOYSA-N
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Compound Rh-123
Molecular Weight:380.824
Molecular Formula:C21H17ClN2O3
InChIKey:MYFATKRONKHHQL-UHFFFAOYSA-N
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Compound AA1
Molecular Weight:433.996
Molecular Formula:C25H24ClN3S
InChIKey:QBKVWLCRWBRVEV-UHFFFAOYSA-M
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Compound 45-Te
Molecular Weight:573.9
Molecular Formula:C20H19IN2STe
InChIKey:JCOSKQROYOJHLH-UHFFFAOYSA-M
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Compound AA1-Se
Molecular Weight:480.89
Molecular Formula:C25H24ClN3Se
InChIKey:JOAZAALXGKYTDO-UHFFFAOYSA-M
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Compound AA1-Te
Molecular Weight:529.5
Molecular Formula:C25H24ClN3Te
InChIKey:UCXABYBHOYXXEJ-UHFFFAOYSA-M
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Compound 46-S
Molecular Weight:476.033
Molecular Formula:C27H26ClN3OS
InChIKey:YPOXKVDRDBFKAE-UHFFFAOYSA-M
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Compound 46-Se
Molecular Weight:522.93
Molecular Formula:C27H26ClN3OSe
InChIKey:HAJPZHGWKVOPRJ-UHFFFAOYSA-M
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Compound 46-Te
Molecular Weight:571.6
Molecular Formula:C27H26ClN3OTe
InChIKey:JAMIMTBUGFYLCG-UHFFFAOYSA-M
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Compound 47-S
Molecular Weight:461.018
Molecular Formula:C27H25ClN2OS
InChIKey:JUBRPJBSPNFUIP-UHFFFAOYSA-M
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Compound 47-Se
Molecular Weight:507.91
Molecular Formula:C27H25ClN2OSe
InChIKey:GEOONTOLXNPKKZ-UHFFFAOYSA-M
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Compound 47-Te
Molecular Weight:556.6
Molecular Formula:C27H25ClN2OTe
InChIKey:KBKYAYFBFBBUFO-UHFFFAOYSA-M
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Compound 48-S
Molecular Weight:546.123
Molecular Formula:C31H32ClN3O2S
InChIKey:UJRHPXFTEXLLHY-UHFFFAOYSA-M
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Compound 48-Se
Molecular Weight:593.02
Molecular Formula:C31H32ClN3O2Se
InChIKey:SJRCAKQEEFNPHG-UHFFFAOYSA-M
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Compound 48-Te
Molecular Weight:641.7
Molecular Formula:C31H32ClN3O2Te
InChIKey:QDKYSYDUYBVVBE-UHFFFAOYSA-M
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Compound 49-S
Molecular Weight:504.086
Molecular Formula:C29H30ClN3OS
InChIKey:WESOMEFBAKJKMZ-UHFFFAOYSA-M
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Compound 49-Se
Molecular Weight:550.98
Molecular Formula:C29H30ClN3OSe
InChIKey:GEOVAKCTDBDYNX-UHFFFAOYSA-M
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Compound 49-Te
Molecular Weight:599.6
Molecular Formula:C29H30ClN3OTe
InChIKey:ULKVOCQJLCATPO-UHFFFAOYSA-M
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Compound 50-S
Molecular Weight:490.102
Molecular Formula:C29H32ClN3S
InChIKey:SHVCQMPPZQKXGB-UHFFFAOYSA-M
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Compound 50-Se
Molecular Weight:537
Molecular Formula:C29H32ClN3Se
InChIKey:MENPHPIAMRSBRP-UHFFFAOYSA-M
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Compound 50-Te
Molecular Weight:585.6
Molecular Formula:C29H32ClN3Te
InChIKey:BFZXSYLKSASGDH-UHFFFAOYSA-M
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Compound 51-Se
Molecular Weight:465.88
Molecular Formula:C25H23ClN2Se
InChIKey:MVVXWNRIDWXWBX-UHFFFAOYSA-M
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Compound 53-Se
Molecular Weight:656.53
Molecular Formula:C26H30F6N3OPSSe
InChIKey:KQNNYURSPZRWTI-UHFFFAOYSA-N
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Compound 52-Se
Molecular Weight:557.39
Molecular Formula:C21H21F6N2PSSe
InChIKey:YNGFIZBIVZWMOE-UHFFFAOYSA-N
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Compound 52-Te
Molecular Weight:606
Molecular Formula:C21H21F6N2PSTe
InChIKey:DRGMOOCCZZFZKT-UHFFFAOYSA-N
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Compound 52-O
Molecular Weight:494.433
Molecular Formula:C21H21F6N2OPS
InChIKey:DIXYWMYEHONACM-UHFFFAOYSA-N
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Compound 52-S
Molecular Weight:510.499
Molecular Formula:C21H21F6N2PS2
InChIKey:UNWRNVRCQXSIPM-UHFFFAOYSA-N
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Compound 54-S
Molecular Weight:384.965
Molecular Formula:C22H25ClN2S
InChIKey:FNNJDFJRCGRXIB-UHFFFAOYSA-M
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Compound 55-S
Molecular Weight:413.018
Molecular Formula:C24H29ClN2S
InChIKey:IWEKXWLCLLAZNZ-UHFFFAOYSA-M
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Compound 56-S
Molecular Weight:427.045
Molecular Formula:C25H31ClN2S
InChIKey:JPEXLPZGQSZCPE-UHFFFAOYSA-M
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Compound 56-Se
Molecular Weight:473.94
Molecular Formula:C25H31ClN2Se
InChIKey:RWCDMTJWIGXRBQ-UHFFFAOYSA-M
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Compound 56-Te
Molecular Weight:522.6
Molecular Formula:C25H31ClN2Te
InChIKey:HIKCUIUFNMWLAL-UHFFFAOYSA-M
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Compound 57-Te
Molecular Weight:542.6
Molecular Formula:C27H27ClN2Te
InChIKey:BXXYJJUYEVTXMC-UHFFFAOYSA-M
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Compound 58-Te
Molecular Weight:480.5
Molecular Formula:C22H25ClN2Te
InChIKey:HAQHBGGXXJUHQK-UHFFFAOYSA-M
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Compound 59-Te
Molecular Weight:626.6
Molecular Formula:C31H31ClN2O2Te
InChIKey:WDFSUACKPSDAOE-UHFFFAOYSA-M
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Compound 60-Te
Molecular Weight:542.6
Molecular Formula:C27H27ClN2Te
InChIKey:HKLLINDSDAYWIG-UHFFFAOYSA-M
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Compound 61-Te
Molecular Weight:480.5
Molecular Formula:C22H25ClN2Te
InChIKey:QVFLLGUXJUFLFU-UHFFFAOYSA-M
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Compound 62
Molecular Weight:409.4
Molecular Formula:C12H10Te2
InChIKey:VRLFOXMNTSYGMX-UHFFFAOYSA-N
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Compound 63
Molecular Weight:509.5
Molecular Formula:C20H14Te2
InChIKey:FZPYMCSZLFRALC-UHFFFAOYSA-N
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Compound 64
Molecular Weight:424.8
Molecular Formula:C15H14Cl2O2Te
InChIKey:LAAZKLXTJPOWSP-UHFFFAOYSA-N
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Compound 65
Molecular Weight:474.8
Molecular Formula:C19H16Cl2O2Te
InChIKey:WIDNMLKPLCKXDR-UHFFFAOYSA-N
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Compound 66
Molecular Weight:450.8
Molecular Formula:C17H16Cl2O2Te
InChIKey:XAPHJPNYJSNERW-BQYQJAHWSA-N
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Compound 67
Molecular Weight:410.7
Molecular Formula:C14H12Cl2O2Te
InChIKey:DETIXTFZXFSTNL-UHFFFAOYSA-N
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Compound 68
Molecular Weight:424.8
Molecular Formula:C15H14Cl2O2Te
InChIKey:CHYQMBYZEPMPQJ-UHFFFAOYSA-N
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Compound 69
Molecular Weight:460.8
Molecular Formula:C18H14Cl2O2Te
InChIKey:SWLYRAGKYXOXSK-UHFFFAOYSA-N
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