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Acid–Base and Solvation Properties of Metal Phenolates

Metal Phenolates (2013)

  1. Erick L. Bastos1,
  2. Fernando H. Bartoloni2,
  3. Letícia C. P. Gonçalves2

Published Online: 22 MAY 2012

DOI: 10.1002/9780470682531.pat0605

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Bastos, E. L., Bartoloni, F. H. and Gonçalves, L. C. P. 2012. Acid–Base and Solvation Properties of Metal Phenolates . Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    Instituto de Química Universidade de São Paulo, SP Brazil

  2. 2

    Universidade Federal do ABC. Rua Santa Adélia, Centro de Ciências Naturais e Humanas, Santo André, SP Brazil

Publication History

  1. Published Online: 22 MAY 2012

Chemistry Terms

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Abstract

This chapter presents an overview of the acid-base and solvation properties of metal phenolates. The effect of the metal counterion on the structure, physicochemical properties and chemical reactivity is discussed. Medium effects on the acid-base equilibrium as well as on chemical reactivity and electronic properties of metal phenolates are summarized. Reference data, such as dissociation constants and partition coefficients, are compiled.

Keywords:

  • metal Lewis acids;
  • dissociation constants;
  • solvent effects;
  • solvatochromism;
  • halosolvatochromism;
  • phenolates;
  • partition coefficients;
  • solubility;
  • acid-base equilibrium

Featured Compounds

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  1. 1 - 107
Compound 1'
Molecular Weight:94.1112
Molecular Formula:C6H6O
InChIKey:ISWSIDIOOBJBQZ-UHFFFAOYSA-N
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Compound 2a
Molecular Weight:94.1112
Molecular Formula:C6H6O
InChIKey:ISWSIDIOOBJBQZ-UHFFFAOYSA-N
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Compound 2b
Molecular Weight:122.1644
Molecular Formula:C8H10O
InChIKey:Not Available
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Compound 2c
Molecular Weight:178.2707
Molecular Formula:C12H18O
InChIKey:Not Available
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Compound 2d
Molecular Weight:206.3239
Molecular Formula:C14H22O
InChIKey:Not Available
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Compound 2e
Molecular Weight:246.3032
Molecular Formula:C18H14O
InChIKey:ATGFTMUSEPZNJD-UHFFFAOYSA-N
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Compound 2
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 3
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 3'
Molecular Weight:212.019
Molecular Formula:C9H9BN6
InChIKey:IQCRCBFHPOOBKA-UHFFFAOYSA-N
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Compound 4
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 5
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 6
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 8
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 9
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 7
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 10
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 11
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 12
Molecular Weight:139.1088
Molecular Formula:C6H5NO3
InChIKey:BTJIUGUIPKRLHP-UHFFFAOYSA-N
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Compound 13
Molecular Weight:139.1088
Molecular Formula:C6H5NO3
InChIKey:RTZZCYNQPHTPPL-UHFFFAOYSA-N
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Compound 14
Molecular Weight:110.1106
Molecular Formula:C6H6O2
InChIKey:YCIMNLLNPGFGHC-UHFFFAOYSA-N
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Compound A
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound B
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound C
Molecular Weight:433.365
Molecular Formula:C16H14O2Pt
InChIKey:WMAYRDZUTZRPEB-UHFFFAOYSA-L
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Compound D
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound E
Molecular Weight:650.11
Molecular Formula:C36H60Gd
InChIKey:ZMOOQBHWSDYJLY-UHFFFAOYSA-N
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Compound 15
Molecular Weight:110.1106
Molecular Formula:C6H6O2
InChIKey:Not Available
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Compound 16
Molecular Weight:110.1106
Molecular Formula:C6H6O2
InChIKey:QIGBRXMKCJKVMJ-UHFFFAOYSA-N
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Compound 17
Molecular Weight:160.1693
Molecular Formula:C10H8O2
InChIKey:OENHRRVNRZBNNS-UHFFFAOYSA-N
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Compound 18
Molecular Weight:174.1528
Molecular Formula:C10H6O3
InChIKey:KQPYUDDGWXQXHS-UHFFFAOYSA-N
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Compound 19
Molecular Weight:324.4649
Molecular Formula:C16H32N6O
InChIKey:QTYQMDRECVKARG-UHFFFAOYSA-N
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Compound 20
Molecular Weight:473.3205
Molecular Formula:C16H31Co2N6O3
InChIKey:JKEUMAWNUIPTAZ-UHFFFAOYSA-M
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Compound 21
Molecular Weight:467.555
Molecular Formula:C16H32Cu2N6O2
InChIKey:FYOYQGRZOBOYCA-UHFFFAOYSA-L
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Compound 22
Molecular Weight:210.2728
Molecular Formula:C11H18N2O2
InChIKey:FCWNPHGWLDJRPA-UHFFFAOYSA-N
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Compound 23
Molecular Weight:543.651
Molecular Formula:C22H36Cu2N6O2
InChIKey:DKAMWQDCBNSQKC-UHFFFAOYSA-L
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Compound 24
Molecular Weight:657.8866
Molecular Formula:C42H51N5O2
InChIKey:GGDPPTIKSZUUPC-UHFFFAOYSA-N
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Compound 25
Molecular Weight:833.019
Molecular Formula:C43H55Cu2N5O4
InChIKey:XXQXLMJAVJTQGA-UHFFFAOYSA-M
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Compound 26
Molecular Weight:818.992
Molecular Formula:C42H53Cu2N5O4
InChIKey:RTQHXKVSIVDGFN-UHFFFAOYSA-L
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Compound 27
Molecular Weight:818.993
Molecular Formula:C42H53Cu2N5O4
InChIKey:VFTJRUKJSNJHOA-UHFFFAOYSA-L
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Compound 28
Molecular Weight:834.993
Molecular Formula:C42H53Cu2N5O5
InChIKey:VTNZFRQWJDFDRR-UHFFFAOYSA-J
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Compound 29
Molecular Weight:416.5602
Molecular Formula:C22H36N6O2
InChIKey:MACOQRGAVRZMEZ-UHFFFAOYSA-N
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Compound 30
Molecular Weight:472.5046
Molecular Formula:C22H37MnN6O2
InChIKey:QJVAGPFYTBQGSF-UHFFFAOYSA-O
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Compound 31
Molecular Weight:581.392
Molecular Formula:C22H38N6O4Zn2
InChIKey:IMNWJKBEQLJKNG-UHFFFAOYSA-L
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Compound 32
Molecular Weight:559.651
Molecular Formula:C22H36Cu2N6O3
InChIKey:QEHOQHJJJIVBFG-UHFFFAOYSA-L
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Compound 33
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 34
Molecular Weight:132.2016
Molecular Formula:C6H5KO
InChIKey:ZGJADVGJIVEEGF-UHFFFAOYSA-M
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Compound 38
Molecular Weight:176.2111
Molecular Formula:C7H5KO3
InChIKey:FRMWBRPWYBNAFB-UHFFFAOYSA-M
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Compound 40
Molecular Weight:176.2111
Molecular Formula:C7H5KO3
InChIKey:DKGFIVSGQRBSOG-UHFFFAOYSA-M
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Compound 41
Molecular Weight:480.7011
Molecular Formula:C31H49AlO2
InChIKey:CXNGYHAYLBTIPZ-UHFFFAOYSA-L
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Compound 42
Molecular Weight:610.44
Molecular Formula:C29H43AlBr2O2
InChIKey:UEKDBDAWIKHROY-UHFFFAOYSA-L
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Compound 43
Molecular Weight:532.6065
Molecular Formula:C37H29AlO2
InChIKey:VQYOKDLEFVOVEV-UHFFFAOYSA-L
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Compound 44
Molecular Weight:762.8672
Molecular Formula:C54H39AlO3
InChIKey:CKRHKYHOTKICCR-UHFFFAOYSA-K
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Compound 45
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 46
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 47
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 48
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 49
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 51
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 52
Molecular Weight:620.6409
Molecular Formula:C30H47O2Ta
InChIKey:UXWRUYFNQFQPDS-UHFFFAOYSA-L
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Compound 50'
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 53
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 54
Molecular Weight:816.24
Molecular Formula:C36H26Cl4O2W
InChIKey:PQRQCMXHYXQLBU-UHFFFAOYSA-H
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Compound 56
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 55
Molecular Weight:874.65
Molecular Formula:C49H39O2PW
InChIKey:QHBBUYOQXVJTTP-UHFFFAOYSA-L
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Compound 57
Molecular Weight:302.2357
Molecular Formula:C15H10O7
InChIKey:REFJWTPEDVJJIY-UHFFFAOYSA-N
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Compound 58
Molecular Weight:286.2363
Molecular Formula:C15H10O6
InChIKey:IYRMWMYZSQPJKC-UHFFFAOYSA-N
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Compound 59
Molecular Weight:610.5175
Molecular Formula:C27H30O16
InChIKey:IKGXIBQEEMLURG-NVPNHPEKSA-N
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Compound 60
Molecular Weight:110.1106
Molecular Formula:C6H6O2
InChIKey:YCIMNLLNPGFGHC-UHFFFAOYSA-N
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Compound 61
Molecular Weight:109.1027
Molecular Formula:C6H5O2
InChIKey:YCIMNLLNPGFGHC-UHFFFAOYSA-N
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Compound 62
Molecular Weight:108.0948
Molecular Formula:C6H4O2
InChIKey:WOAHJDHKFWSLKE-UHFFFAOYSA-N
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Compound 63
Molecular Weight:163.939
Molecular Formula:C6H4FeO2
InChIKey:BEEAKIYQAFESFE-UHFFFAOYSA-L
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Compound 63'
Molecular Weight:163.939
Molecular Formula:C6H4FeO2
InChIKey:UQXYSBQIBBKQDL-UHFFFAOYSA-M
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Compound 63''
Molecular Weight:163.939
Molecular Formula:C6H4FeO2
InChIKey:WAKINHHIZVAVQV-UHFFFAOYSA-M
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Compound 64
Molecular Weight:440.037
Molecular Formula:C24H28CuN2O2
InChIKey:NDZPOZBKOOHRFI-UHFFFAOYSA-L
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Compound 65
Molecular Weight:696.212
Molecular Formula:C42H34CuO2P2
InChIKey:ZRASGOGUNQHDKX-UHFFFAOYSA-M
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Compound 66
Molecular Weight:503.713
Molecular Formula:C20H48Cu2N4O2
InChIKey:PGPPGFDXNZLQMK-UHFFFAOYSA-N
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Compound 67
Molecular Weight:709.028
Molecular Formula:C34H69Cu2N4O3
InChIKey:NSVFHBVXCUEAAP-UHFFFAOYSA-M
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Compound 68
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 69
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 71
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 72
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 73
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 74
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 75
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 76
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 77
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 78
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 79
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 80
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 81
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 82
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 85
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 86
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 87
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 90
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 91
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 92
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 93
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 94
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 96
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 97
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 95
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 98
Molecular Weight:551.6751
Molecular Formula:C41H29NO
InChIKey:UWOVWIIOKHRNKU-UHFFFAOYSA-N
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Compound 99
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 102
Molecular Weight:Not Available
Molecular Formula:(C2H4O)nC33H27NO3
InChIKey:BPFITFNJWBOFJS-UHFFFAOYSA-N
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Compound 103
Molecular Weight:792.336
Molecular Formula:C47H47ClN3NaO5
InChIKey:MTIAJRJHZKTZKR-UHFFFAOYSA-M
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Compound 104
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 105
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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