Standard Article

The Coordination and Catalytic Chemistry of Phosphinoferrocene Ligands—A Concise Introduction and Update

Organoiron Compounds (2013)

  1. Petr Štěpnička

Published Online: 14 DEC 2012

DOI: 10.1002/9780470682531.pat0650

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Štěpnička, P. 2012. The Coordination and Catalytic Chemistry of Phosphinoferrocene Ligands—A Concise Introduction and Update. Patai's Chemistry of Functional Groups. .

Author Information

  1. Faculty of Science, Charles University in Prague, Department of Inorganic Chemistry, Prague, Czech Republic

Publication History

  1. Published Online: 14 DEC 2012

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Abstract

This chapter attempts to briefly summarise the research carried out on the design, synthesis and practical, mostly catalytic, applications of phosphinoferrocene donors. Presented are selected basic concepts that illustrate milestones and major routes in the development of ferrocene-based phosphines since the discovery of ferrocene, as well as recent trends demonstrating the vast applications of these compounds as ligands in coordination chemistry and, mainly, in numerous conventional and asymmetric transition-metal-mediated organic transformations.

Keywords:

  • ferrocene;
  • phosphines;
  • ligands;
  • coordination chemistry;
  • catalysis;
  • transition metals

Featured Compounds

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  1. 1 - 130
Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 89
Molecular Weight:512.101
Molecular Formula:C22H18FeIOP
InChIKey:LBYRWWLXCWJRJG-UHFFFAOYSA-N
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Compound 2
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 3
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound A
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound B
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 4
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound C
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound D
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 5
Molecular Weight:680.549
Molecular Formula:C41H37FeO4P
InChIKey:KZRNGDDRNBEACL-VJXHLTRHSA-N
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Compound 6
Molecular Weight:726.428
Molecular Formula:C40H44Fe2N2P2
InChIKey:VLZVZJLGDQRGSS-KPORBVJDSA-N
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Compound 7
Molecular Weight:747.4
Molecular Formula:C37H43ClFeP2Pd
InChIKey:LJJVRUYNGIPAQC-UHFFFAOYSA-M
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Compound 8
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 9
Molecular Weight:446.301
Molecular Formula:C28H23FeP
InChIKey:NDSTUVGGMVCFIC-UHFFFAOYSA-N
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Compound 10
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 10a
Molecular Weight:306.101
Molecular Formula:C14H20FeP2
InChIKey:UBLCREXFPCOOSX-UHFFFAOYSA-N
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Compound 10b
Molecular Weight:362.207
Molecular Formula:C18H28FeP2
InChIKey:BCPVFKXAPLQYIE-UHFFFAOYSA-N
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Compound 10c
Molecular Weight:418.314
Molecular Formula:C22H36FeP2
InChIKey:IDLVJIDYJDJHOI-UHFFFAOYSA-N
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Compound 10d
Molecular Weight:474.42
Molecular Formula:C26H44FeP2
InChIKey:WDUDHEOUGWAKFD-UHFFFAOYSA-N
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Compound 10e
Molecular Weight:578.569
Molecular Formula:C34H52FeP2
InChIKey:DTQIHJBOJNZKNL-UHFFFAOYSA-N
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Compound 11
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 12a
Molecular Weight:582.432
Molecular Formula:C36H32FeP2
InChIKey:ZUWUSYSSRHHJPE-UHFFFAOYSA-N
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Compound 12b
Molecular Weight:610.485
Molecular Formula:C38H36FeP2
InChIKey:RCAUARQTBHQRPD-UHFFFAOYSA-N
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Compound 13
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 14
Molecular Weight:285.129
Molecular Formula:C16H21BNOP
InChIKey:FANITLDTNCZSML-WROXITFLSA-N
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Compound 16
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 15
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 17
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 18
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 19
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 20
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 21
Molecular Weight:484.33
Molecular Formula:C28H30FeP2
InChIKey:PIPMIPQTBZVLQJ-XCONSJKQSA-N
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Compound 25
Molecular Weight:506.291
Molecular Formula:C26H28FeO3P2
InChIKey:AAJPWIHYZNNPGI-UHFFFAOYSA-N
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Compound 22a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 22b
Molecular Weight:454.397
Molecular Formula:C26H27FePSi
InChIKey:HPIZLEBICUHQRT-UHFFFAOYSA-N
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Compound 23
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 24
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 26
Molecular Weight:386.204
Molecular Formula:C22H19FeOP
InChIKey:TWYVDGPAPNCDGT-UHFFFAOYSA-N
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Compound 27
Molecular Weight:400.231
Molecular Formula:C23H21FeOP
InChIKey:GGWQPZYFIIJCMH-UHFFFAOYSA-N
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Compound 28
Molecular Weight:402.27
Molecular Formula:C22H19FePS
InChIKey:SEIOWWWTUGQLDO-UHFFFAOYSA-N
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Compound 29
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 30
Molecular Weight:525.26
Molecular Formula:C28H23FePSe
InChIKey:UAFJGDMRARMQBJ-UHFFFAOYSA-N
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Compound 31
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 32a
Molecular Weight:447.289
Molecular Formula:C27H22FeNP
InChIKey:KFGGDSIORPMFRY-UHFFFAOYSA-N
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Compound 32b
Molecular Weight:461.316
Molecular Formula:C28H24FeNP
InChIKey:DWTRNCYJYNAAAA-UHFFFAOYSA-N
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Compound 32c
Molecular Weight:447.289
Molecular Formula:C27H22FeNP
InChIKey:RKFIGUVGDOMDGZ-UHFFFAOYSA-N
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Compound 33
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 34
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 35
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 36
Molecular Weight:687.526
Molecular Formula:C42H35FeNOP2
InChIKey:HLNKJFPCBZJNNM-UHFFFAOYSA-N
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Compound 37a
Molecular Weight:457.282
Molecular Formula:C25H24FeNO2P
InChIKey:SUGHDZVRSKLNTH-UHFFFAOYSA-N
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Compound 37b
Molecular Weight:501.335
Molecular Formula:C27H28FeNO3P
InChIKey:IASLGERCRHBEPP-UHFFFAOYSA-N
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Compound 38
Molecular Weight:Not Available
Molecular Formula:(CH2)nC29H35FeN2O4PS
InChIKey:WOKINQHPJDOSLH-UHFFFAOYSA-N
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Compound 38a
Molecular Weight:608.51
Molecular Formula:C30H38FeN2O4PS
InChIKey:WOKINQHPJDOSLH-UHFFFAOYSA-N
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Compound 38b
Molecular Weight:622.536
Molecular Formula:C31H40FeN2O4PS
InChIKey:FXIBXRLVCFJZOL-UHFFFAOYSA-N
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Compound 38c
Molecular Weight:636.563
Molecular Formula:C32H42FeN2O4PS
InChIKey:KGRVHGOUFHIGDY-UHFFFAOYSA-N
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Compound 39
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 39a
Molecular Weight:485.292
Molecular Formula:C26H24FeNO3P
InChIKey:LERYCJQRIPUXEA-UHFFFAOYSA-N
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Compound 39b
Molecular Weight:471.266
Molecular Formula:C25H22FeNO3P
InChIKey:MHTMECDDGIDBOB-UHFFFAOYSA-N
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Compound 39c
Molecular Weight:470.281
Molecular Formula:C25H23FeN2O2P
InChIKey:NRQWIBWAUVXCDS-UHFFFAOYSA-N
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Compound 40
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 35a
Molecular Weight:504.34
Molecular Formula:C29H25FeN2OP
InChIKey:CLLFJWXAESJRHT-UHFFFAOYSA-N
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Compound 35b
Molecular Weight:518.367
Molecular Formula:C30H27FeN2OP
InChIKey:UWKPOSLTDAGOOZ-UHFFFAOYSA-N
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Compound 35c
Molecular Weight:504.34
Molecular Formula:C29H25FeN2OP
InChIKey:IYLMRMZXHLJCQK-UHFFFAOYSA-N
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Compound 41
Molecular Weight:428.244
Molecular Formula:C23H21FeN2OP
InChIKey:HLIWDENLHWBYNZ-UHFFFAOYSA-N
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Compound 42
Molecular Weight:515.323
Molecular Formula:C29H22FeN3OP
InChIKey:MZQFEAXDYMLPNC-UHFFFAOYSA-N
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Compound 43
Molecular Weight:428.241
Molecular Formula:C24H21FeO2P
InChIKey:RFIQGPOAIMOUJV-UHFFFAOYSA-N
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Compound 44
Molecular Weight:438.239
Molecular Formula:C24H19FeN2OP
InChIKey:UPYUTCQJHZTROW-UHFFFAOYSA-N
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Compound 45
Molecular Weight:506.356
Molecular Formula:C29H27FeN2OP
InChIKey:XVZOJSUCVBJUMA-UHFFFAOYSA-N
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Compound 46
Molecular Weight:492.33
Molecular Formula:C28H25FeN2OP
InChIKey:DVOJIINPYGZIPH-UHFFFAOYSA-N
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Compound 47
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 48
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 49
Molecular Weight:601.457
Molecular Formula:C37H28FeN3P
InChIKey:JERNJYBXMLIAMI-UHFFFAOYSA-N
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Compound 50
Molecular Weight:501.336
Molecular Formula:C30H24FeNOP
InChIKey:TUGCBUHBSPPNEZ-NWALZDBPSA-N
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Compound 51
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 52
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound (R)-53
Molecular Weight:257.152
Molecular Formula:C14H19FeN
InChIKey:UNMQCGHIBZALKM-YCBDHFTFSA-N
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Compound (R,R)-54
Molecular Weight:263.085
Molecular Formula:C14H18FeLiN
InChIKey:ZFAVANNSNNQSRQ-VFIYQRISSA-N
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Compound (R,S)-54
Molecular Weight:263.085
Molecular Formula:C14H18FeLiN
InChIKey:ZFAVANNSNNQSRQ-UHFFFAOYSA-N
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Compound (S)-53
Molecular Weight:257.152
Molecular Formula:C14H19FeN
InChIKey:UNMQCGHIBZALKM-JZGIKJSDSA-N
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Compound 55a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 55b
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 56
Molecular Weight:329.333
Molecular Formula:C17H27FeNSi
InChIKey:BNPWKLMGQOEXCT-YQFADDPSSA-N
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Compound 57
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 55
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 58
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 59
Molecular Weight:456.294
Molecular Formula:C26H25FeO2P
InChIKey:CTSKCYOIJQUHIX-GGMCWBHBSA-N
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Compound 60
Molecular Weight:428.284
Molecular Formula:C25H25FeOP
InChIKey:UGIBJYDKGSQYFT-GGMCWBHBSA-N
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Compound 61
Molecular Weight:414.258
Molecular Formula:C24H23FeOP
InChIKey:AWZBMIVGMCHWIU-QCUBGVIVSA-N
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Compound 62
Molecular Weight:430.323
Molecular Formula:C24H23FePS
InChIKey:JWWJGIUJTALGFT-QCUBGVIVSA-N
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Compound 63
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 65
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 64
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 66
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 67
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 68
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 69
Molecular Weight:718.563
Molecular Formula:C44H41FeP3
InChIKey:BFWSSIDAAFKTEG-UHFFFAOYSA-N
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Compound 70
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 71
Molecular Weight:908.626
Molecular Formula:C54H55Fe2P3
InChIKey:PIOYPCCUGYRHCT-KUOFJQFLSA-N
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Compound 72
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 73
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 74
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 75
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 77
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 78
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 79
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 80
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 81
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 84
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 83
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 82
Molecular Weight:383.049
Molecular Formula:C14H18FeIN
InChIKey:FBTJEAAKFDLVOI-XCUBXKJBSA-N
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Compound 85
Molecular Weight:574.276
Molecular Formula:C30H40Fe2P2
InChIKey:IJUQWYIHQRFORA-UHFFFAOYSA-N
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Compound 86
Molecular Weight:297.173
Molecular Formula:C16H19FeNO
InChIKey:MOTUFOCNRSDOMK-YQFADDPSSA-N
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Compound 87
Molecular Weight:430.042
Molecular Formula:C15H20FeIOP
InChIKey:VMAVOQAHRPXWTH-UHFFFAOYSA-N
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Compound 88
Molecular Weight:738.394
Molecular Formula:C44H36Fe2P2
InChIKey:VADPYXYBFVOWCG-UHFFFAOYSA-N
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Compound 90
Molecular Weight:770.393
Molecular Formula:C44H36Fe2O2P2
InChIKey:YJVWSRSTCZSOBA-UHFFFAOYSA-N
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Compound 91
Molecular Weight:912.46
Molecular Formula:C50H54Fe3N2P2
InChIKey:YNALISCXEIESNH-MUFRMHGMSA-N
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Compound (R)-92
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound (S)-92
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 93
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 94
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 95
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 96
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 98
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 97
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 99
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 100
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 101
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 102
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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