Standard Article

Iron Acyl Complexes

Organoiron Compounds (2013)

  1. Diana Liebmann,
  2. Marc Zastrow,
  3. Karola Rück-Braun

Published Online: 28 APR 2014

DOI: 10.1002/9780470682531.pat0658

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Liebmann, D., Zastrow, M. and Rück-Braun, K. 2014. Iron Acyl Complexes. Patai's Chemistry of Functional Groups. 1–26.

Author Information

  1. Technische Universität Berlin, Institut für Chemie, Faculty of Science, Germany

Publication History

  1. Published Online: 28 APR 2014

Chemistry Terms

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Abstract

This chapter covers a selection of acyl complexes and synthetic applications published within the past two decades. Iron acyl complexes are useful building blocks for organic synthesis. This survey covers recent synthetic applications of a selection of acyl complexes published within the last two decades. Herein, acyl complexes derived from carbonyl iron reagents are discussed, besides cyclopentadienyl dicarbonyl iron compounds, their phosphine-substituted chiral-at-iron derivatives and diiron acyl complexes. This chapter has been organized according to the above classification with additional ligands and their reactivity, for example allyl, dienes.

Keywords:

  • allyl iron complexes;
  • cyclohexadienyl iron complexes;
  • cyclopentadienyl dicarbonyl iron complexes;
  • vinylidene iron complexes;
  • chiral-at-iron acyl complexes;
  • [Fe]-hydrogenases;
  • cycloaddition reactions;
  • cyclocarbonylations;
  • conjugate addition reactions;
  • aldol reactions

Featured Compounds

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  1. 1 - 133
Compound 52d
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 111
Molecular Weight:512.358
Molecular Formula:C29H29FeO3P
InChIKey:BOPKXDCUNBPUTA-QWDPUZEJSA-N
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Compound 125
Molecular Weight:501.025
Molecular Formula:C22H14Fe2O7
InChIKey:QJORVECRXXSYHX-UHFFFAOYSA-N
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Compound 52c
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 56
Molecular Weight:627.678
Molecular Formula:C38H53FeNO3
InChIKey:FVZZVDBXDVCWKQ-UHFFFAOYSA-N
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Compound 62
Molecular Weight:232.014
Molecular Formula:C10H8FeO3
InChIKey:KBJKAVJLXYQIBW-UHFFFAOYSA-N
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Compound 110
Molecular Weight:454.279
Molecular Formula:C26H23FeO2P
InChIKey:ISNQVPRERNHURF-UHFFFAOYSA-N
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Compound 90
Molecular Weight:235.3651
Molecular Formula:C15H25NO
InChIKey:XPAKTKAWZNFEON-UHFFFAOYSA-N
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Compound 101
Molecular Weight:517.375
Molecular Formula:C26H23FeNO5S
InChIKey:ZTTAHSRUFHTIDC-UHFFFAOYSA-N
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Compound 36
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 16
Molecular Weight:300.002
Molecular Formula:C12H4FeO6
InChIKey:IZFSXIPKRWKCBS-UHFFFAOYSA-N
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Compound 55
Molecular Weight:606.588
Molecular Formula:C35H39FeO2PSi
InChIKey:QTWQBZWDILKCBV-UHFFFAOYSA-N
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Compound 54
Molecular Weight:509.377
Molecular Formula:C30H30FeO2P
InChIKey:LNPITRSYZAHQDU-UHFFFAOYSA-N
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Compound 77
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 57
Molecular Weight:439.251
Molecular Formula:C18H31FeN3O2P2
InChIKey:OIMPWCIKEPNDKC-UHFFFAOYSA-N
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Compound 14
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 1
Molecular Weight:213.865
Molecular Formula:C4FeNa2O4
InChIKey:YNOPUBSNWPRJMF-UHFFFAOYSA-N
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Compound 53
Molecular Weight:275.101
Molecular Formula:C13H15FeO3
InChIKey:KGTOJUOMEIYBDO-UHFFFAOYSA-N
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Compound 35
Molecular Weight:412.345
Molecular Formula:C19H36FeN2O4
InChIKey:MKINTEUARJEITE-UHFFFAOYSA-N
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Compound 24b
Molecular Weight:506.243
Molecular Formula:C23H18FeN2O8
InChIKey:WAUYNHUATVVWGU-FYOXJOEUSA-N
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Compound 4
Molecular Weight:195.896
Molecular Formula:C5FeO5
InChIKey:FYOFOKCECDGJBF-UHFFFAOYSA-N
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Compound 47
Molecular Weight:339.124
Molecular Formula:C16H13FeNO4
InChIKey:KPRALTJWKLZZSM-MHRKHEJKSA-N
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Compound 109
Molecular Weight:470.6026
Molecular Formula:C30H34N2O3
InChIKey:QIWIBBYREGQTLI-UIUQJESISA-N
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Compound 23a
Molecular Weight:631.367
Molecular Formula:C31H28FeO9P
InChIKey:FHWJZGVLNGHFGX-ZPQYUHANSA-N
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Compound 60
Molecular Weight:232.014
Molecular Formula:C10H8FeO3
InChIKey:DDRCHXROTKBOTO-UHFFFAOYSA-N
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Compound 25
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 104c
Molecular Weight:204.245
Molecular Formula:C11H8O2S
InChIKey:FWKYTSHCIPIVQF-UHFFFAOYSA-N
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Compound 2
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 87
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 73
Molecular Weight:614.203
Molecular Formula:C32H22Fe2O6
InChIKey:PRWWSDFIXPCRQH-UHFFFAOYSA-N
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Compound 43
Molecular Weight:233.987
Molecular Formula:C9H6FeO4
InChIKey:NFNFQNKKHYYFRJ-UHFFFAOYSA-N
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Compound 100
Molecular Weight:475.295
Molecular Formula:C23H17FeNO5S
InChIKey:VYIYUTNXGBPZFV-LNDDYWTCSA-N
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Compound 66
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 23b
Molecular Weight:803.573
Molecular Formula:C43H41FeO8P2
InChIKey:VTTRZAJONOUSBZ-QKAXPGQZSA-N
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Compound 15
Molecular Weight:132.1162
Molecular Formula:C8H4O2
InChIKey:NFYYUUJYMWILSY-UHFFFAOYSA-N
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Compound 104
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 112
Molecular Weight:100.1158
Molecular Formula:C5H8O2
InChIKey:GAEKPEKOJKCEMS-SCSAIBSYSA-N
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Compound 46
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 63
Molecular Weight:526.98
Molecular Formula:C25H20FeO2Sn
InChIKey:SHFCQPVTZUQLHV-UHFFFAOYSA-N
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Compound 80
Molecular Weight:124.2233
Molecular Formula:C9H16
InChIKey:JLEYIXWABQURRS-UHFFFAOYSA-N
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Compound 9
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 98
Molecular Weight:487.349
Molecular Formula:C25H21FeNO4S
InChIKey:SQWQGEKTANIWFH-DAFSEJQISA-N
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Compound 27
Molecular Weight:319.137
Molecular Formula:C12H11FeN2O3S
InChIKey:GMSBKRGWBZVMQE-UHFFFAOYSA-M
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Compound 103
Molecular Weight:352.185
Molecular Formula:C17H12FeO3S
InChIKey:JZWBZGLFEBRJBW-UHFFFAOYSA-N
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Compound 116
Molecular Weight:601.496
Molecular Formula:C36H36FeNO2P
InChIKey:XWTFFTDXSCXJMR-UXDXUJKSSA-N
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Compound 5
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 17
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 42
Molecular Weight:409.5487
Molecular Formula:C20H31NO6Si
InChIKey:PVODISAUVIGWCW-CVEARBPZSA-N
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Compound 97
Molecular Weight:390.294
Molecular Formula:C18H16BrNO2S
InChIKey:NEPOAOHNLSXDBR-MOSHPQCFSA-N
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Compound 67
Molecular Weight:236.121
Molecular Formula:C9H12FeO2Si
InChIKey:MANWMKJYZWDYCS-UHFFFAOYSA-N
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Compound 38
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 64
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 135
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 31b
Molecular Weight:273.065
Molecular Formula:C12H11FeNO3
InChIKey:XXODGDYIQSIQHF-UHFFFAOYSA-N
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Compound 105a
Molecular Weight:202.2491
Molecular Formula:C13H14O2
InChIKey:GYLNSWVQMRPVFQ-PWSUYJOCSA-N
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Compound 48
Molecular Weight:409.227
Molecular Formula:C20H28FeLiNO4
InChIKey:HJZIAHGLTIMBQT-IGMKIZKBSA-N
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Compound 50
Molecular Weight:467.293
Molecular Formula:C23H25FeNO6
InChIKey:OECXDPQXAOKESU-XSOAQHNLSA-N
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Compound 52d
Molecular Weight:372.312
Molecular Formula:C18H24FeO3Si
InChIKey:RSKUQCPSVNXUFV-UHFFFAOYSA-N
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Compound 34
Molecular Weight:621.423
Molecular Formula:C34H33FeNO3P2
InChIKey:IDCLLPHSCWCUQX-UHFFFAOYSA-N
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Compound 82
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 130
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 88
Molecular Weight:314.321
Molecular Formula:C12H17F3O4S
InChIKey:PVUSBBDKSMKNTG-UHFFFAOYSA-N
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Compound 91
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 70
Molecular Weight:264.2323
Molecular Formula:C16H8O4
InChIKey:BABBLZNSSDFZFH-BUHFOSPRSA-N
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Compound 89
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 32
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 105
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 131
Molecular Weight:156.2975
Molecular Formula:C8H16OSi
InChIKey:PMTXWMFGFKYIJE-VOTSOKGWSA-N
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Compound 102
Molecular Weight:519.391
Molecular Formula:C26H25FeNO5S
InChIKey:FIFYIFSNKDYZOM-UHFFFAOYSA-N
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Compound 33
Molecular Weight:223.006
Molecular Formula:C8H9FeNO3
InChIKey:VSRGKGTWPMBUPC-UHFFFAOYSA-N
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Compound 13
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 86
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 105c
Molecular Weight:206.261
Molecular Formula:C11H10O2S
InChIKey:CGIBCXVPVDWDAD-XVKPBYJWSA-N
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Compound 75
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 6
Molecular Weight:297.984
Molecular Formula:C9H6FeO8
InChIKey:MCYIYZKQCMSGKT-UHFFFAOYSA-N
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Compound 84
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 39
Molecular Weight:407.272
Molecular Formula:C16H21FeNO6Si
InChIKey:YRUWEYGETJRURV-UHFFFAOYSA-N
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Compound 93
Molecular Weight:336.12
Molecular Formula:C17H12FeO4
InChIKey:OOVJNHRQWAVVIP-UHFFFAOYSA-N
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Compound 30
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 51
Molecular Weight:199.948
Molecular Formula:C7H5FeNaO2
InChIKey:UBPRZDLAWPUWLA-UHFFFAOYSA-N
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Compound 78
Molecular Weight:246.04
Molecular Formula:C11H10FeO3
InChIKey:NSRYZVWUFTYHCL-UHFFFAOYSA-N
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Compound 26
Molecular Weight:424.294
Molecular Formula:C20H20FeN2O3S
InChIKey:JBAFMRVXKPHZMI-UHFFFAOYSA-M
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Compound 133
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 22
Molecular Weight:197.954
Molecular Formula:C6H6FeO4
InChIKey:MGMHKPUEVJFWSQ-UHFFFAOYSA-N
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Compound 21
Molecular Weight:325.82
Molecular Formula:C11H12BFeLiN2O5
InChIKey:SBJTZKSMKQPLLG-UHFFFAOYSA-N
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Compound 108
Molecular Weight:469.353
Molecular Formula:C27H27FeNO3
InChIKey:XXNWKWZJTREWSG-SESSBIMYSA-N
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Compound 31a
Molecular Weight:210.996
Molecular Formula:C7H9FeNO3
InChIKey:KLVBNPNRVHEBLP-UHFFFAOYSA-N
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Compound 120
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 123
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 74
Molecular Weight:204.2665
Molecular Formula:C16H12
InChIKey:VWDKVBGOVYWYFZ-UHFFFAOYSA-N
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Compound 20
Molecular Weight:308.068
Molecular Formula:C11H12FeN2O5
InChIKey:OVZNPSXMHGYEAA-UHFFFAOYSA-N
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Compound 7
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 19
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 115
Molecular Weight:175.227
Molecular Formula:C11H13NO
InChIKey:LTZANYLTVNPGTG-VIFPVBQESA-N
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Compound 28
Molecular Weight:555.405
Molecular Formula:C29H26FeNO3PS
InChIKey:KSENVLGPYIOCLA-UHFFFAOYSA-M
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Compound 45
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 65
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 132
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 81
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 69
Molecular Weight:203.022
Molecular Formula:C8H4Cl2O2
InChIKey:FYXKZNLBZKRYSS-UHFFFAOYSA-N
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Compound 71
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 94
Molecular Weight:325.3585
Molecular Formula:C19H19NO4
InChIKey:ZTKNWYCEAOFQKU-UHFFFAOYSA-N
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Compound 79
Molecular Weight:245.075
Molecular Formula:C12H13FeO2
InChIKey:QVWKMXUCKJGFSC-UHFFFAOYSA-N
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Compound 52
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 52b
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 58
Molecular Weight:250.029
Molecular Formula:C10H10FeO4
InChIKey:YNDHXGZKSNEPSE-UHFFFAOYSA-N
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Compound 136
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 76
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 52a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 92
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 24a
Molecular Weight:482.221
Molecular Formula:C21H18FeN2O8
InChIKey:DLWJPCPAFLGNMV-FYOXJOEUSA-N
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Compound 99
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 105b
Molecular Weight:190.1953
Molecular Formula:C11H10O3
InChIKey:KWHORJQIBWOVCB-XCBNKYQSSA-N
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Compound 117
Molecular Weight:189.2536
Molecular Formula:C12H15NO
InChIKey:OKVICDHXGCQBTC-ZJUUUORDSA-N
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Compound 106
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 68
Molecular Weight:316.069
Molecular Formula:C11H17FeO5P
InChIKey:RBJSNGHIWLPOJW-UHFFFAOYSA-N
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Compound 113
Molecular Weight:480.316
Molecular Formula:C28H25FeO2P
InChIKey:SFOIVCDLPNIUPF-GGMKUFPDSA-N
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Compound 72
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 104b
Molecular Weight:188.1794
Molecular Formula:C11H8O3
InChIKey:NZIDHWNIODMPSP-UHFFFAOYSA-N
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Compound 18
Molecular Weight:631.28
Molecular Formula:C27H30FeINO5
InChIKey:CPEFLAFXSVLHBJ-HNLDPSASSA-M
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Compound 107
Molecular Weight:308.11
Molecular Formula:C16H12FeO3
InChIKey:UDYRWMNUCPEMPG-UKTVGUFOSA-N
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Compound 8
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 11
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 95
Molecular Weight:251.119
Molecular Formula:C12H11BrO
InChIKey:UJSHTSTZXNGSOT-UHFFFAOYSA-N
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Compound 114
Molecular Weight:587.469
Molecular Formula:C35H34FeNO2P
InChIKey:CLMRZAXUECOSFC-WFLPUWFGSA-N
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Compound 83
Molecular Weight:146.1427
Molecular Formula:C9H6O2
InChIKey:ZYGHJZDHTFUPRJ-UHFFFAOYSA-N
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Compound 96
Molecular Weight:348.174
Molecular Formula:C19H16FeO3
InChIKey:RUNSDONCNKIUSR-UHFFFAOYSA-N
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Compound 29
Molecular Weight:237.975
Molecular Formula:C8H6FeO5
InChIKey:WYZSGFSQXVSPTM-UHFFFAOYSA-N
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Compound 121
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 124
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 104a
Molecular Weight:200.2332
Molecular Formula:C13H12O2
InChIKey:QLWJPYMUQTVYGG-UHFFFAOYSA-N
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Compound 10
Molecular Weight:503.656
Molecular Formula:C12Fe3O12
InChIKey:Not Available
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Compound 118
Molecular Weight:468.306
Molecular Formula:C27H25FeO2P
InChIKey:RTUOSOQJAHZXOI-UHFFFAOYSA-N
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