1,2-Dioxatrisulfane (Thiaperoxide) Intermediates in Type I and II Photooxygenation Reactions
Published Online: 28 APR 2014
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Patai's Chemistry of Functional Groups
How to Cite
CLENNAN, E. L. 2014. 1,2-Dioxatrisulfane (Thiaperoxide) Intermediates in Type I and II Photooxygenation Reactions. Patai's Chemistry of Functional Groups. 1–34.
- Published Online: 28 APR 2014
This review focuses on a discussion of labile metastable sulfur-based peroxides (persulfoxides-R2S+OO−; 3-membered SOO ring thiadioxiranes-c-R2SO2; hydroperoxy sulfonium ylides-R(R′CH)S+OO−; and, peroxy sulfuranes-R2S(OR′)OOR′′) that have been observed or implicated in Type I and II photooxygenation reactions. Evidence for formation and computational structures of these novel intermediates is presented.
- hydroperoxy sulfonium ylide;
- peroxy sulfuranes;
- singlet oxygen