Chapter 50. Gibbs-Duhem Equation

  1. H. Donald Brooke Jenkins

Published Online: 7 APR 2008

DOI: 10.1002/9780470697733.ch50

Chemical Thermodynamics at a Glance

Chemical Thermodynamics at a Glance

How to Cite

Jenkins, H. D. B. (2008) Gibbs-Duhem Equation, in Chemical Thermodynamics at a Glance, Blackwell Publishing Ltd, Oxford, UK. doi: 10.1002/9780470697733.ch50

Author Information

  1. Professor of Chemistry, Department of Chemistry, University of Warwick, Coventry, UK

Publication History

  1. Published Online: 7 APR 2008
  2. Published Print: 1 JAN 2008

ISBN Information

Print ISBN: 9781405139977

Online ISBN: 9780470697733



  • Gibbs-Duhem equation;
  • Gibbs-Duhem-Margules equation;
  • free energy;
  • molar quantities;
  • entropy


This chapter contains section titled:

  • Gibbs-Duhem Equation

  • Derivation of Clausius-Clapeyrron Equation* Using the Gibbs-Duhem Equation. [* In the form of Equation (26.5), Frame 26]

  • Derivation of the Phase Rule using the Gibbs-Duhem Equation

  • Three-Phase Equilibria and the Gibbs-Duhem Equation

  • Application to Activities