Chapter 1. General Aspects of Organosuperbases

  1. Professor Tsutomu Ishikawa
  1. Professor Tsutomu Ishikawa

Published Online: 3 FEB 2009

DOI: 10.1002/9780470740859.ch1

Superbases for Organic Synthesis: Guanidines, Amidines, Phosphazenes and Related Organocatalysts

Superbases for Organic Synthesis: Guanidines, Amidines, Phosphazenes and Related Organocatalysts

How to Cite

Ishikawa, T. (2009) General Aspects of Organosuperbases, in Superbases for Organic Synthesis: Guanidines, Amidines, Phosphazenes and Related Organocatalysts (ed T. Ishikawa), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470740859.ch1

Editor Information

  1. Graduate School of Pharmaceutical Sciences, Chiba University, 1-33 Yayoi, Inage, Chiba 263-8522, Japan

Author Information

  1. Graduate School of Pharmaceutical Sciences, Chiba University, 1-33 Yayoi, Inage, Chiba 263-8522, Japan

Publication History

  1. Published Online: 3 FEB 2009
  2. Published Print: 28 JAN 2009

ISBN Information

Print ISBN: 9780470518007

Online ISBN: 9780470740859

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Keywords:

  • organosuperbases - general aspects;
  • amidinium and guanidinium ion conjugation;
  • stabilization effect through hydrogen bonding;
  • Verkade's base typical structure and trans-annular P–N formation;
  • hybrid organobases;
  • schematic equation for definition of superbases;
  • computational calculation of proton affinities;
  • recycling use ability in repeated reaction

Summary

This chapter contains sections titled:

  • References