Chapter 12. Structural Effects on Reactivity and Properties of Oximes and Hydroxamic Acids

  1. Professor Zvi Rappoport2 and
  2. Joel F. Liebman3
  1. Marvin Charton

Published Online: 19 DEC 2008

DOI: 10.1002/9780470741962.ch12

The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids

The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids

How to Cite

Charton, M. (2008) Structural Effects on Reactivity and Properties of Oximes and Hydroxamic Acids, in The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids (eds Z. Rappoport and J. F. Liebman), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470741962.ch12

Editor Information

  1. 2

    The Hebrew University, Jerusalem, Israel

  2. 3

    Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, 1000 Hilltop Circle, Baltimore, Maryland 21250, USA

Author Information

  1. Chemistry Department, School of Liberal Arts and Sciences, Pratt Institute, Brooklyn, New York 11205, USA

Publication History

  1. Published Online: 19 DEC 2008
  2. Published Print: 19 DEC 2008

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Professor Saul Patai and
  2. Professor Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780470512616

Online ISBN: 9780470741962

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Keywords:

  • structural effect nature;
  • Structure–Property Quantitative Relationships (SPQR);
  • reactivity and properties - structural effects;
  • Yukawa–Tsuno (MYT) equation;
  • steric effect concept and substituent steric classification;
  • steric effects - multiparametric models;
  • intermolecular force (IMF) equation;
  • correlation analysis application and acidity

Summary

This chapter contains sections titled:

  • The Nature of Structural Effects

  • Electrical Effects

  • Steric Effects

  • Intermolecular Forces

  • Application Methods

  • Applications of Correlation Analysis to Acidity

  • Further Applications to Reactivities and Properties

  • Appendices

  • References