Chapter 14. Nitrosomethanides and their Acids: Synthesis, Structure and Bonding

  1. Professor Zvi Rappoport4 and
  2. Joel F. Liebman5
  1. Axel Schulz1,2,
  2. Harald Brand3 and
  3. Alexander Villinger1

Published Online: 19 DEC 2008

DOI: 10.1002/9780470741962.ch14

The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids

The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids

How to Cite

Schulz, A., Brand, H. and Villinger, A. (2008) Nitrosomethanides and their Acids: Synthesis, Structure and Bonding, in The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids (eds Z. Rappoport and J. F. Liebman), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470741962.ch14

Editor Information

  1. 4

    The Hebrew University, Jerusalem, Israel

  2. 5

    Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, 1000 Hilltop Circle, Baltimore, Maryland 21250, USA

Author Information

  1. 1

    Universität Rostock, Institut für Chemie, Abteilung Anorganische Chemie, Albert-Einstein-Straße 3a, 18059 Rostock, Germany

  2. 2

    Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany

  3. 3

    LMU Munich, Butenandt-Str. 5–13, 81377 München, Germany

Publication History

  1. Published Online: 19 DEC 2008
  2. Published Print: 19 DEC 2008

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Professor Saul Patai and
  2. Professor Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780470512616

Online ISBN: 9780470741962

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Keywords:

  • resonance stabilized methanides - new pseudohalide class;
  • nitrosomethanides and acids;
  • nitrosonitrocyanomethanides and nitrolic acids;
  • resonance stabilization;
  • dinitrosomethanide acids;
  • gas-phase acidities;
  • monomeric nitrosomethanide compound chemistry;
  • cyanoformaldoxime - synthesis and reaction;
  • gas-phase acidities and acid deprotonation reaction energetics

Summary

This chapter contains sections titled:

  • Introduction

  • Nitrosomethanides and their Acids

  • Nitrosocyanomethanides and their Acids

  • Nitrosonitromethanides and their Acids

  • Nitrosonitrocyanomethanides and Nitrolic Acids

  • Resonance Stabilization

  • Gas-Phase Acidities

  • Application-Summary-Outlook

  • References