Chapter 18. N-Heteroatom-Substituted Hydroxamic Esters

  1. Professor Zvi Rappoport2 and
  2. Joel F. Liebman3
  1. Stephen A. Glover

Published Online: 19 DEC 2008

DOI: 10.1002/9780470741962.ch18

The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids

The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids

How to Cite

Glover, S. A. (2008) N-Heteroatom-Substituted Hydroxamic Esters, in The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids (eds Z. Rappoport and J. F. Liebman), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470741962.ch18

Editor Information

  1. 2

    The Hebrew University, Jerusalem, Israel

  2. 3

    Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, 1000 Hilltop Circle, Baltimore, Maryland 21250, USA

Author Information

  1. Division of Chemistry, School of Science and Technology, University of New England, Armidale, NSW 2351, Australia

Publication History

  1. Published Online: 19 DEC 2008
  2. Published Print: 19 DEC 2008

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Professor Saul Patai and
  2. Professor Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780470512616

Online ISBN: 9780470741962

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Keywords:

  • N-heteroatom-substituted hydroxamic esters;
  • hydroxamic esters - amide functionality subset;
  • anomeric amides and conformational preference;
  • N-acyloxy-N-alkoxyamides properties;
  • amide carbonyl vibrational frequencies;
  • nitrenium ion resonance stabilization;
  • N-acyloxy-N-alkoxyureas and carbamates and benzamides;
  • amide carbonyl reaction;
  • N-acyloxy-N-alkoxyamides and HERON reactions

Summary

This chapter contains sections titled:

  • Introduction

  • Unusual Characteristics of N-Heteroatom-Substituted Hydroxamic Esters

  • N-Alkoxy-N-Haloamides

  • N-Acyloxy-N-Alkoxyamides

  • N,N-Dialkoxyamides

  • N-Alkoxy-N-Aminoamides

  • N-Alkoxy-N-Thioalkylamides

  • Acknowledgement

  • References