Chapter 3. The Organic Thermochemistry of Hydroxylamines, Oximes, Hydroxamic Acids and their Derivatives

  1. Professor Zvi Rappoport2 and
  2. Joel F. Liebman3
  1. Suzanne W. Slayden1 and
  2. Joel F. Liebman3

Published Online: 19 DEC 2008

DOI: 10.1002/9780470741962.ch3

The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids

The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids

How to Cite

Slayden, S. W. and Liebman, J. F. (2008) The Organic Thermochemistry of Hydroxylamines, Oximes, Hydroxamic Acids and their Derivatives, in The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids (eds Z. Rappoport and J. F. Liebman), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470741962.ch3

Editor Information

  1. 2

    The Hebrew University, Jerusalem, Israel

  2. 3

    Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, 1000 Hilltop Circle, Baltimore, Maryland 21250, USA

Author Information

  1. 1

    Department of Chemistry, George Mason University, 4400 University Drive, Fairfax, Virginia 22030, USA

  2. 3

    Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, 1000 Hilltop Circle, Baltimore, Maryland 21250, USA

Publication History

  1. Published Online: 19 DEC 2008
  2. Published Print: 19 DEC 2008

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Professor Saul Patai and
  2. Professor Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780470512616

Online ISBN: 9780470741962

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Keywords:

  • hydroxylamines and N-substituted derivatives;
  • hydroxylamines, oximes, and hydroxamic acids - organic thermochemistry;
  • aliphatic hydroxylamine thermochemical data;
  • aryl hydroxylamines;
  • O-substituted hydroxylamine derivatives or alkoxylamines;
  • nitroxide radical dimers;
  • monooxime enthalpy of formation;
  • glyoxime and other dioximes;
  • oxime ethers

Summary

This chapter contains sections titled:

  • Introduction: Scope of the Chapter, Definitions of Key Terms and Sources of Data

  • Hydroxylamines and N-Substituted Derivatives

  • O-Substituted Hydroxylamine Derivatives (Alkoxylamines)

  • Monooximes

  • Glyoxime and other Dioximes

  • Quinone Oximes and Nitrosoarenols

  • Oxime Ethers

  • Hydroxamic Acids and their Derivatives

  • References and Notes