Chapter 4. 1,2-Dicarbon Cumulenes

  1. Henri Ulrich

Published Online: 10 NOV 2009

DOI: 10.1002/9780470747957.ch4

Cumulenes in Click Reactions

Cumulenes in Click Reactions

How to Cite

Ulrich, H. (2009) 1,2-Dicarbon Cumulenes, in Cumulenes in Click Reactions, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470747957.ch4

Publication History

  1. Published Online: 10 NOV 2009
  2. Published Print: 13 NOV 2009

ISBN Information

Print ISBN: 9780470779323

Online ISBN: 9780470747957

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Keywords:

  • 1,2-Dicarbon cumulenes;
  • ketenes 2 - synthesized by dehydrochlorination of carboxylic acid chlorides;
  • intramolecular cyclization of imidoylketene;
  • flash vacuum thermolysis (FVT);
  • catalyzed thermal reaction of alkylarylketenes with cyclopentadiene;
  • switter ionic intermediates;
  • prostaglandin intermediates synthesis;
  • dimerization reactions

Summary

This chapter contains sections titled:

  • Ketenes, R2C[DOUBLE BOND]C[DOUBLE BOND]O

  • Thioketenes, R2C[DOUBLE BOND]C[DOUBLE BOND]S

  • Ketenimines, R2C[DOUBLE BOND]C[DOUBLE BOND]NR

  • 1-Silaallenes, R2C[DOUBLE BOND]C[DOUBLE BOND]Si

  • 1-Phosphaallenes, R2C[DOUBLE BOND]C[DOUBLE BOND]P

  • Other Metal Allenes

  • References