Ab Initio Calculations for Rydberg States
Published Online: 15 SEP 2011
Copyright © 2011 John Wiley & Sons, Ltd. All rights reserved.
Handbook of High-resolution Spectroscopy
How to Cite
Jungen, M. 2011. Ab Initio Calculations for Rydberg States. Handbook of High-resolution Spectroscopy. .
- Published Online: 15 SEP 2011
This article deals with the phenomenon of atomic and molecular (electronic) Rydberg series and their quantum chemical treatment on various levels of sophistication, going from the simple frozen-core calculations to the use of highly correlated wave functions.
- quantum defect;
- the Edlen plot;
- series mixing;
- perturbations of Rydberg series;
- angular momentum analysis