Chapter 11. Preparation and Reactivity of Magnesium Enolates

  1. Professor Zvi Rappoport2 and
  2. Ilan Marek3
  1. Claude Grison

Published Online: 17 APR 2008

DOI: 10.1002/9780470751879.ch11

The Chemistry of Organomagnesium Compounds

The Chemistry of Organomagnesium Compounds

How to Cite

Grison, C. (2008) Preparation and Reactivity of Magnesium Enolates, in The Chemistry of Organomagnesium Compounds (eds Z. Rappoport and I. Marek), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470751879.ch11

Editor Information

  1. 2

    The Hebrew University, Jerusalem, Israel

  2. 3

    Technion-Israel Institute of Technology, Haifa, Israel

Author Information

  1. UMR CNRS-Université, de Montpellier 2 5032, ENSCM, 8 rue de l'Ecole Normale, F-34296 Montpellier, France

Publication History

  1. Published Online: 17 APR 2008
  2. Published Print: 29 FEB 2008

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Professor Saul Patai and
  2. Professor Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780470057193

Online ISBN: 9780470751879

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Keywords:

  • enolate anions and magnesium enolates;
  • magnesium enolate and elemental magnesium;
  • metal–halogen interconversion;
  • magnesium enolates - preparation and reactivity;
  • sulfoxide ligand exchange reaction;
  • chiral acetate aldol stereochemistry;
  • electron-deficient carbon–carbon double bond;
  • tandem reaction and TrSbCl6-catalyzed Mukaiyama reaction;
  • thioamide enolates - interesting substrates

Summary

This chapter contains sections titled:

  • Introduction

  • Preparation of Magnesium Enolates

  • Reactivity of Enolates

  • References