Chapter 16. The Chemistry of Magnesium Carbenoids

  1. Professor Zvi Rappoport2 and
  2. Ilan Marek3
  1. Tsuyoshi Satoh

Published Online: 17 APR 2008

DOI: 10.1002/9780470751879.ch16

The Chemistry of Organomagnesium Compounds

The Chemistry of Organomagnesium Compounds

How to Cite

Satoh, T. (2008) The Chemistry of Magnesium Carbenoids, in The Chemistry of Organomagnesium Compounds (eds Z. Rappoport and I. Marek), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470751879.ch16

Editor Information

  1. 2

    The Hebrew University, Jerusalem, Israel

  2. 3

    Technion-Israel Institute of Technology, Haifa, Israel

Author Information

  1. Department of Chemistry, Faculty of Science, Tokyo University of Science; Ichigayafunagawara-machi 12, Shinjuku-ku, Tokyo 162-0826, Japan

Publication History

  1. Published Online: 17 APR 2008
  2. Published Print: 29 FEB 2008

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Professor Saul Patai and
  2. Professor Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780470057193

Online ISBN: 9780470751879

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Keywords:

  • magnesium carbenoid generation;
  • magnesium carbenoid - reaction and synthetic use;
  • organic synthesis - carbene and carbenoid;
  • halogen–metal exchange;
  • magnesium cyclopropylidenes;
  • magnesium alkylidene carbenoids;
  • Simmons–Smith-type olefin cyclopropanation;
  • magnesium β-oxido carbenoids

Summary

This chapter contains sections titled:

  • Introduction

  • Generation of Magnesium Carbenoids

  • Reactions and Synthetic Uses of Magnesium Carbenoids

  • Magnesium Cyclopropylidenes

  • Magnesium Alkylidene Carbenoids

  • Magnesium β-Oxido Carbenoids

  • Other Magnesium Carbenoids

  • Conclusions and Perspective

  • References