Chapter 3. NMR of Organomagnesium Compounds

  1. Professor Zvi Rappoport2 and
  2. Ilan Marek3
  1. Peter J. Heard

Published Online: 17 APR 2008

DOI: 10.1002/9780470751879.ch3

The Chemistry of Organomagnesium Compounds

The Chemistry of Organomagnesium Compounds

How to Cite

Heard, P. J. (2008) NMR of Organomagnesium Compounds, in The Chemistry of Organomagnesium Compounds (eds Z. Rappoport and I. Marek), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470751879.ch3

Editor Information

  1. 2

    The Hebrew University, Jerusalem, Israel

  2. 3

    Technion-Israel Institute of Technology, Haifa, Israel

Author Information

  1. School of Science and Technology, North East Wales Institute, Mold Road, Wrexham LL112AW, UK

Publication History

  1. Published Online: 17 APR 2008
  2. Published Print: 29 FEB 2008

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Professor Saul Patai and
  2. Professor Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780470057193

Online ISBN: 9780470751879

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Keywords:

  • organomagnesium reagent solution concentration;
  • organomagnesium compound NMR;
  • alkyl and aryl compounds;
  • H NMR spectrum and MeMgBr display signal;
  • dynamic NMR studies and diorganomagnesium organic group exchange;
  • organomagnesium compound metal-bonded carbon atom;
  • aryl Grignards;
  • Schlenk equilibrium and Grignard compound reactivity;
  • allylic and vinylic compounds;
  • organomagnesium reagent co-ordination complex

Summary

This chapter contains sections titled:

  • Introduction

  • Concentration of Reagent Solutions

  • Alkyl and Aryl Compounds

  • Allylic and Vinylic Compounds

  • Alkoxide and Peroxide Compounds

  • Co-Ordination Complexes

  • 25Mg NMR Studies

  • References